Journal of Organic Chemistry p. 862 - 876 (1987)
Update date:2022-08-03
Topics: Total synthesis Methyl ester Chemical Synthesis Experimental
Ghosh, Soumitra S.
Martin, John C.
Fried, Josef
A total synthesis of the disulfide analogue 2 of 13,14-dehydro-PGH2 methyl ester is described.A key intermediate is the mesylate of the 3-phenyl-2,4-dithia<3.2.1>bicyclooctane derivative 37b, which undergoes alkynylation via an episulfonium intermediate t
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(1987)
