The Extremely Rapid Acid-catalysed Additions of Acetylenes to and the Synthesis of

DOI: 10.1039/c39860001629

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1629 - 1630 (1986)

Update date:2022-08-02

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Authors:

Higgins, Simon J.

Shaw, Bernard L.

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Article abstract of DOI:10.1039/c39860001629

The addition of acetylenes such as HCCH, HCCPh, or MeOOCCCCOOMe to to give 'dimetallated olefins' is catalysed by traces of acid or methanol but inhibited by a base: the 'dimetallated olefin' complex makes an interesting comparison with the vinylidene complex .

Full text of DOI:10.1039/c39860001629

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