The First Preparation of Disilene via Reductive Dehalogenation of 1,2-Dichlorodisilane. The Formation of an Unusual Air-Oxidation Product, 1-Oxa-2-silacyclopent-3-ene Derivative

DOI: 10.1246/cl.1988.1343

Source and publish data:

Chemistry Letters p. 1343 - 1346 (1988)

Update date:2022-08-04

Topics:

Authors:

Watanabe, Hamao

Takeuchi, Ken

Nakajima, Kenji

Nagai, Yoichiro

Goto, Midori

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Article abstract of DOI:10.1246/cl.1988.1343

The most air-stable disilene, tetrakis(2,4,6-triisopropylphenyl)disilene, again was obtained by the reaction of 1,2-dichloro-1,1,2,2-tetrakis(2,4,6-triisopropylphenyl)disilane with lithium naphthalenide.The disilene afforded its air-oxidation product havi

Full text of DOI:10.1246/cl.1988.1343

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