The chloramination of some substituted arsines

Article abstract of DOI:10.1021/ic50045a035

The reactions of triphenylarsine and diphenylchloroarsine with chloramine and with mixtures of chloramine and ammonia have been carried out and a variety of aminoarsonium chlorides and cyclic arsenonitriles prepared. Similar compounds have been derived by the ammonolysis of di- and trichlorophenylarsanes. It has been shown that chloramination, like chlorination, of phenylarsines results, under some conditions, in the fission of some of the arsenic-phenyl bonds and the elimination of chlorobenzene.