New route to (-)-frontalin and (-)-malyngolide via epoxyketone rearrangement

DOI: 10.1016/S0040-4020(01)96151-4

Source and publish data:

Tetrahedron p. 6967 - 6974 (1991)

Update date:2022-09-26

Topics:

Authors:

Asaoka, Morio

Hayashibe, Satoshi

Sonoda, Syuzo

Takei, Hisashi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)96151-4

Synthesis of the title compounds by utilizing BF₃·Et₂O catalyzed ring contraction of 2,3-epoxycyclohexanones leading to 2-alkyl-2-formylcyclopentanones is described.

Full text of DOI:10.1016/S0040-4020(01)96151-4

Products guided by the article

Product name:(-)-(2S,4S)-2-benzoyloxymethyl-2-methyl-4-(trimethylsilyl)cyclopentanone

Cas No:137809-75-7

R&D Labs maybe for 137809-75-7

Shanghai Gsyn Chemical Co.,Ltd.

Contact:86-021-67158290

Address:86-021-67158291
RongCheng Tianyu Technology Co.,Ltd.

Contact:86-631-7519595

Address:220Ping Donghai Road RongChengCity,ShangDong Province China
Zhejiang Chemline International Co., Ltd.

Contact:+86-571-88062298

Address:Hengdian Industry Area, Dongyang, Zhejiang, China
Tianjin Bright Future Technology Co., Ltd

Contact:0086-22-58016666

Address:NO.136 DongTeng Lake Street Tianjin Economic and Technology Development Area,Tainjin,China
Nanjing Habo Medical Technology Co., Ltd.

Contact:025－85769882

Address:No.108. Ganjiabian east. Qixia District .Nanjing

Relevant to this article

A novel, general, totally stereoselective one-pot synthesis of cis-3-substituted 4-formylazetidin-2-ones

Doi:10.1016/S0040-4039(00)74892-1
(1991)
N-Alkyl derivatives of diosgenyl 2-amino-2-deoxy-β-D-glucopyranoside; synthesis and antimicrobial activity

Doi:10.3762/bjoc.11.97
(2015)
Synthesis, structure, and properties of extended π-conjugated systems bearing sterically crowded triarylphosphines

Doi:10.1016/j.jorganchem.2011.07.013
(2011)
Nanorods versus nanovesicles from amphiphilic dendrofullerenes

Doi:10.1021/ja206769a
(2011)
Synthesis of PDE IV inhibitors. First asymmetric synthesis of two of GlaxoSmithKline's highly potent Rolipram analogues

Doi:10.1039/c3ob41646a
(2013)
Copper-mediated C-H activation/C-S cross-coupling of heterocycles with thiols

Doi:10.1021/jo2017444
(2011)

Article Doi