Angewandte Chemie - International Edition p. 5701 - 5705 (2012)
Update date:2022-07-29
Topics:
Pankajakshan, Sreekumar
Xu, Yun-He
Cheng, Jun Kee
Low, Man Ting
Loh, Teck-Peng
Z only: An atom-economical synthetic route towards arylated Z-enamides through double C-H functionalization is described. The Z/E selectivity of the palladium-catalyzed monoarylation is absolute (step A in scheme), and the molecular complexity of the products can be further endowed by a sequential second arylation, which requires the use of trifluoracetic acid (TFA; step B). Copyright
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Doi:10.1021/ic301374z
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