Tetrahedron Letters p. 7375 - 7378 (1993)
Update date:2022-09-26
Topics:
Arrington, Mark P.
Bennani, Youssef L.
Goebel, Thomas
Walsh, Patrick
Zhao, Shu-Hai
Sharpless, K. Barry
Modification on the quinuclidine and quinoline moieties of the bis cichona-alkaloid phthalazine ligands resulted in improved enantioselectivities in the osmium tetroxide catalyzed dihydroxylation of olefins.For the first time 1-decene, a common model for terminal aliphatic olefins, afforded enantioselectivities of over ninety percent.
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