Cyclometallation of Azine Phosphines of Type Z,E-PPh2CH2(t-Bu)=N-N=CHR (R = an Aromatic or Heterocyclic Group) involving X-Y (X = C, N or O; Y = H, I or Br) Bond Fission by Platinum(II)

DOI: 10.1039/DT9950000641

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 641 - 648 (1995)

Update date:2022-08-04

Topics:

Authors:

Perera, Sarath D.

Shaw, Bernard L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9950000641

The phosphino hydrazone Z-PPh2CH2C(t-Bu)=NNH2 1 is shown to be a convenient 'reagent' for converting aryl or heterocyclic aldehydes into azines which can rhen be cycloplatinated readily with C-H, C-I, C-Br, N-H or O-H bond fission.Condensation of 1 with b

Full text of DOI:10.1039/DT9950000641

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:N-[1-[(Diphenylphosphanyl)-methyl]-2,2-dimethyl-prop-(Z)-ylidene]-N'-[1-(1H-pyrrol-2-yl)-meth-(E)-ylidene]-hydrazine

Cas No:157064-08-9

R&D Labs maybe for 157064-08-9

Dalian Join King Biochemical Tech. Co., Ltd.

Contact:0411 39216206

Address:814 First State Blvd
JiYi Chemical (Beijing) Co., Ltd.

Contact:+86-10-89385733

Address:Shilou Town of Fangshan District， Beijing
Jiangsu Zenji Pharmaceuticals LTD

Contact:+86-025-83172562; +1-224-888-1133(USA)

Address:No.5 Xinmofan Road
Wuhan Yitongtai Science and Technology Co.,Ltd.

Contact:+86-27-88933550

Address:27th Fl. Bldg. 1, Shuian International Mansion, Heping Ave, Wuhan, Hubei, China
Shanghai Send Pharmaceutical Technology Co., Ltd.

website:http://www.shsendpharma.com

Contact:021-58088081, +8613585868794

Address::Room A601, Building 1,NO. 800 Qingdai Road Pudong District Shanghai,China

Relevant to this article

Enantioselective Lewis base catalyzed phosphonyldifluoromethylation of allylic fluorides using a: C -silyl latent pronucleophile

Doi:10.1039/d0cc01815e
(2020)
Kinetic resolution of allyl fluorides by enantioselective allylic trifluoromethylation based on silicon-assisted c-F bond cleavage

Doi:10.1002/anie.201308071
(2014)
Base mediated synthesis of 2-aryl-2,3-dihydroquinazolin-4(1H)-ones from 2-aminobenzonitriles and aromatic aldehydes in water

Doi:10.1039/c3ob42434k
(2014)
N-Hydroxymethylnorcotinine, a new primary in vitro metabolite of cotinine

Doi:10.3109/00498259409043244
(1994)
Preparation of Dithioformato, Thioformamido and Formamido Derivatives of Iron(II)

Doi:10.1039/DT9940001769
(1994)
One Robust Microporous Tm^III-Organic Framework for Highly Catalytic Activity on Chemical CO₂Fixation and Knoevenagel Condensation

Doi:10.1021/acs.inorgchem.0c03134
(2021)

Article Doi