Cyclometallation of Azine Phosphines of Type Z,E-PPh2CH2(t-Bu)=N-N=CHR (R = an Aromatic or Heterocyclic Group) involving X-Y (X = C, N or O; Y = H, I or Br) Bond Fission by Platinum(II)

DOI: 10.1039/DT9950000641

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 641 - 648 (1995)

Update date:2022-08-04

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Authors:

Perera, Sarath D.

Shaw, Bernard L.

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Article abstract of DOI:10.1039/DT9950000641

The phosphino hydrazone Z-PPh2CH2C(t-Bu)=NNH2 1 is shown to be a convenient 'reagent' for converting aryl or heterocyclic aldehydes into azines which can rhen be cycloplatinated readily with C-H, C-I, C-Br, N-H or O-H bond fission.Condensation of 1 with b

Full text of DOI:10.1039/DT9950000641

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