Chemistry of Acetoacetanilide and Derivatives with Zero- and Di-valent Platinum and Palladium complexes; Crystal Structure of the Four-membered Ring Palladalactam Complex (bipy = 2,2'-bipyridyl)

DOI: 10.1039/DT9940003085

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3085 - 3090 (1994)

Update date:2022-08-05

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Authors:

Henderson, William

Fawcett, John

Kemmitt, Raymond D. W.

Proctor, Clive

Russell, David R.

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Article abstract of DOI:10.1039/DT9940003085

Reaction of the complexes cis- with acetoacetanilide, o- or p-acetoacetanisidide mediated by silver(I) oxide gave, under mild conditions, high yields of the metallalactam complexes (R = Ph, C6H4OMe-o or p).The complexes have been fully characterised by multinuclear NMR spectroscopy, fast atom bombardment mass spectrometry, and by a single-crystal X-ray diffraction study carried out on the 2,2'-bipyridyl palladium derivative .The complex contains a slightly puckered palladalactam ring system (fold angle 17.5 deg).Reaction of acetoacetanilide with the zerovalent platinum complex in air gives exclusively the peroxometallacyclic complex , while reaction with gave a mixture of the peroxometallacycle plus the platinalactam complex .

Full text of DOI:10.1039/DT9940003085

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