Unexpected reactions of pentafluorophenyl boron compounds with η-cyclopentadienyl(benzamidinato)zirconium derivatives

DOI: 10.1039/DT9960000939

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 939 - 946 (1996)

Update date:2022-09-26

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Authors:

Gomez, Rafael

Green, Malcolm L. H.

Haggitt, Jane L.

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Article abstract of DOI:10.1039/DT9960000939

The compounds [Zr(η-C₅R₅){ζ-CPh(NSiMe₃) ₂}R′₂] (R = H, R′ = Me or CH₂Ph; R = Me, R′ = Me) reacted with [Ph₃C][B(C₆F₅)₄] giving [{Zr(η-C_{5
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Full text of DOI:10.1039/DT9960000939

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Product name:Zr(CH₂C₆H₅)(C₅H₅)(C(C₆H₅)(NSi(CH₃)3)2)⁽¹⁺⁾*B(CH₂C₆H₅)(C₆F₅)3^(1-)=[Zr(CH₂C₆H₅)(C₅H₅)(C₁₃H₂₃N₂Si₂)]B(CH₂C₆H₅)(C₆F₅)3

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