The Preparation and Crystal Structure of a Salt with the 4(NO3)> Monoanion

DOI: 10.1039/c39950000627

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 627 - 628 (1995)

Update date:2022-08-03

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Authors:

Arrowsmith, Stephen

Dove, Michael F. A.

Logan, Norman

Antipin, Michael Y.

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Article abstract of DOI:10.1039/c39950000627

Acetonitrile is oxidised to acetate by vanadium(V) oxide trinitrate in the presence of tetraphenylarsonium chloride and the crystal structure of the main reaction product, (C6H5)4As 1, is solved; the anion consists of a tetravanadium(V) crown containing a guest nitrate group in a μ₄ mode.

Full text of DOI:10.1039/c39950000627

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Product name:As(C₆H₅)4⁽¹⁺⁾*[VO₂(O₂CCH₃)]4NO₃^(1-)=(C₆H₅)4As[VO₂(O₂CCH₃)]4NO₃

Cas No:162828-88-8

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