Silyloxy-cope rearrangement of chiral aldol adducts

DOI: 10.1016/0040-4039(96)00904-5

Source and publish data:

Tetrahedron Letters p. 4471 - 4474 (1996)

Update date:2022-07-29

Topics:

Authors:

Black, W. Cameron

Giroux, Andre

Greidanus, Grace

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(96)00904-5

The silyloxy-Cope rearrangement of a chiral 1,5-diene generated from aldol condensation proceeds in high yield and selectivity under mild thermal conditions to generate a new stereocenter five atoms removed from the chiral auxiliary.

Full text of DOI:10.1016/0040-4039(96)00904-5

Products guided by the article

Product name:(S)-4-Benzyl-3-[(E)-(2S,3R)-3-(tert-butyl-dimethyl-silanyloxy)-5-phenyl-2-vinyl-pent-4-enoyl]-oxazolidin-2-one

Cas No:180976-44-7

R&D Labs maybe for 180976-44-7

Nantong LiKai Chemical Co.,Ltd

Contact:+86-513-89068669

Address:Jincheng Science Park
HangZhou HuaYe Chemical Technology Co.,Ltd

Contact:+86-13505815007

Address:hangzhou
Advanced Biotech

Contact:+1-973-357-0577

Address:10 Taft Rd.
chengdu firsterchem Pharmaceutical Co., Ltd.

Contact:028-66825849

Address:chengdu
Jiangsu Willing Bio-Tech Co ltd

website:http://www.willingbio.com/

Contact:+86 18796909136--

Address:No 18 Guoqiao Road

Relevant to this article

Bioactive hydroxyethylene dipeptide isosteres with hydrophobic (P₃- P₁)-moieties. A novel strategy towards small non-peptide renin inhibitors

Doi:10.1016/S0960-894X(96)00279-X
(1996)
A bis(cyclopalladated) tetranuclear derivative of methyl ferrocenyl ketone azine: [{Pd[(η⁵-C₅H₅)Fe(η⁵-C ₅H₃)CMe=N]Cl(PPh₃)}₂]

Doi:10.1039/DT9960003195
(1996)
Synthesis and structural study of some N-acyl-4-allylsemicarbazides and the product of their cyclization with a potential antimicrobial activity

Doi:10.1016/j.molstruc.2020.128552
(2020)
Synthesis and properties of diuridine phosphate analogues containing thio and amino modifications

Doi:10.1021/jo960795l
(1996)
Aerobic catalytic epoxidation of unfunctionalized olefins using a new (salen)manganese (III) complex bearing a sesquiterpene salicylaldehyde derivative

Doi:10.1016/0040-4020(96)00697-7
(1996)
Thermal cleavage of oxazolidine-4,5-diones to imines: A short synthesis of 3,4-dihydro-3,3-dimethyl-7-trifluoromethylisoquinoline-2-oxide

Doi:10.1080/00397919608003751
(1996)

Article Doi