Silyloxy-cope rearrangement of chiral aldol adducts

DOI: 10.1016/0040-4039(96)00904-5

Source and publish data:

Tetrahedron Letters p. 4471 - 4474 (1996)

Update date:2022-07-29

Topics:

Authors:

Black, W. Cameron

Giroux, Andre

Greidanus, Grace

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Article abstract of DOI:10.1016/0040-4039(96)00904-5

The silyloxy-Cope rearrangement of a chiral 1,5-diene generated from aldol condensation proceeds in high yield and selectivity under mild thermal conditions to generate a new stereocenter five atoms removed from the chiral auxiliary.

Full text of DOI:10.1016/0040-4039(96)00904-5

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