Enantioselective synthesis of highly functionalised cyclohexanones starting from R-(-)-carvone

DOI: 10.1016/S0040-4039(98)01367-7

Source and publish data:

Tetrahedron Letters p. 6565 - 6568 (1998)

Update date:2022-08-04

Topics:

Authors:

Meulemans, Tommi M.

Stork, Gerrit A.

Jansen, Ben J.M.

De Groot, Aede

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Article abstract of DOI:10.1016/S0040-4039(98)01367-7

Copper (1) catalysed conjugate addition of methylmagnesium iodide to R- (-)-carvone and trapping the enolate as its trimethylsilyl enol ether, followed by a trityl perchlorate (TrClO₄) catalysed Mukaiyama-aldol reaction, is an efficient method

Full text of DOI:10.1016/S0040-4039(98)01367-7

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