Synthetic Communications p. 942 - 948 (2016)
Update date:2022-08-05
Topics:
Raja, Ranganathan
Murugan, Dinesh
Sivasubramaniyan, Archana
George, Jaabil
Perumal, Sakthivel
Alagusundaram, Ponnuswamy
Jayakumar, Mohan Raj
Saminathan, Murugavel
Two different heterocycles, thiazole-2-imines and imidazole-2-thiones, have been conveniently synthesized by just altering the sequential order (1+2+3 or 1+3+2) when combining the same components [aryl amine (1), aryl isothiocyanate (2), and phenacyl bromide (3)] in one-pot, three-component protocols. The third possible sequential order of combination (2+3+1) chemoselectively affords thiazole-2-imine. The finding is a stepping stone in the synthetic applicability of sequential one-pot, three-component protocols.
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