A Convenient Synthesis of N-Substituted Formamidines by Desulfurization of the Corresponding Thioureas

DOI: 10.1246/bcsj.59.3317

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3317 - 3319 (1986)

Update date:2022-08-04

Topics:

Authors:

Kashima, Choji

Shimizu, Masao

Eto, Takeshi

Omote, Yoshimori

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.59.3317

N,N'-Di- and N,N,N'-trisubstituted thioureas were easily desulfurized by Raney nickel to yield the corresponding formamidines, while N-monosubstituted thioureas gave N,N'-disubstituted formamidines.

Full text of DOI:10.1246/bcsj.59.3317

Products guided by the article

Product name:N-methyl-N'-(p-methylphenyl)formamidine

Cas No:72397-78-5

R&D Labs maybe for 72397-78-5

Qingdao Kingway Pharmtech Co., Ltd.

Contact:86-532-87118899

Address:No. 88, Middle Haixi Road, Jiaonan City, Qingdao, China
Shijiazhuang Haotian Chemical Co., Ltd.

Contact:86-311-85044374

Address:293 Donggang Road
Anqing World Chemical Co., Ltd.

Contact:+86-556-5800026

Address:Daguan Economic Development Zone of circular economy industrial park Anqing City Anhui province
Changzhou Foreign Trade Corp

Contact:+86-519-86623222

Address:29F/D, 99 Yanling West Road, Changzhou, Jiangsu, China
Nanjing Legend Pharmaceutical & Chemical Co., Ltd.

Contact:+86-25-83767696

Address:14-7 Zhongshan Lu Guluo District, Nanjing

Relevant to this article

ASYMMETRIC TOTAL SYNTHESIS OF NATURAL (-)- AND UNNATURAL (+)-STEGANACIN DETERMINATION OF THE ABSOLUTE CONFIGURATION OF NATURAL ANTITUMOR STEGANACIN

Doi:10.1016/S0040-4020(01)82416-9
(1984)
Sodium Diisopropylamide in Tetrahydrofuran: Selectivities, Rates, and Mechanisms of Arene Metalations

Doi:10.1021/jacs.7b08734
(2017)
Doi:10.1002/macp.1979.021801201
(1979)
Synthesis of 5-<(Methylthio)methyl>-2'-deoxyuridine, the Corresponding Sulfoxide and Sulfone, and Their 5'-Phosphates: Antiviral Effects and Thymidylate Synthetase Inhibition

Doi:10.1021/jm00177a008
(1980)
Differential Effects of Structural Modifications on the Competition of Chalcones for the PIB Amyloid Imaging Ligand-Binding Site in Alzheimer's Disease Brain and Synthetic Aβ Fibrils

Doi:10.1021/acschemneuro.5b00266
(2016)
Triarylamine-based porous coordination polymers performing both hydrogen atom transfer and photoredox catalysis for regioselective α-amino C(sp³)-H arylation

Doi:10.1039/d1sc00828e
(2021)

Article Doi