TANDEM ADDITION-REARRANGEMENT OF NITRILE ANIONS TO BENZYNE. A CONVENIENT SYNTHESIS OF 3-CYANO-2-ALKYL BENZOIC ACIDS AND BENZALDEHYDES.

DOI: 10.1016/S0040-4039(01)81332-0

Source and publish data:

Tetrahedron Letters p. 2941 - 2944 (1984)

Update date:2022-09-26

Topics:

Authors:

Meyers, A. I.

Pansegrau, Paul D.

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Article abstract of DOI:10.1016/S0040-4039(01)81332-0

Benzynes derived from aryloxazolines react with lithio-alkyl nitriles to give addition followed by cyclization to benzocyclobutanone imines which fragment to the title products.

Full text of DOI:10.1016/S0040-4039(01)81332-0

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