Hydrosilylation of olefins with monosilane in the presence of lithium aluminum hydride

DOI: 10.1246/cl.1996.1013

Source and publish data:

Chemistry Letters p. 1013 - 1014 (1996)

Update date:2022-08-28

Topics:

Authors:

Kobayashi, Mineo

Itoh, Masayoshi

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Article abstract of DOI:10.1246/cl.1996.1013

Hydrosilylation reactions of 1-hexene and ethylene with SiH₄ occurs in the presence of LiAlH₄ as a catalyst. Hexylsilane and dihexylsilane were produced from 1-hexene and SiH₄. Ethylsilane was produced from ethylene and SiH₄. The reaction mechanism involving SiH₄ and the alkyl anion, which is formed by the interaction between LiAlH₄ and the olefin, has been proposed.

Full text of DOI:10.1246/cl.1996.1013

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