Russian Chemical Bulletin p. 2079 - 2086 (1995)
Update date:2022-08-23
Topics:
Dunyakhin, V. A.
Kuricheva, O. V.
Timofeev, V. V.
Zhitnev, Yu. N.
Multiphoton dissociation (MPD) of hexafluoropropylene oxide (HFPO) under focused CO2-laser radiation was studied.A high-energy channel of HFPO decomposition was revealed.The dependences of the MPD yield and the ratio between various channels of HFPO decomposition on the laser radiation frequency in the range from 967.7 to 1090.0 cm-1, the incident radiation energy, and the initial pressure of HFPO were obtained.A considerable contribution of thermal decomposition of HFPO occurring outside of the irradiated zone to the total yield of its decomposition was established.An explanation for pressure dependence of the yield of HFPO decomposition was suggested. - Keywords: multiphoton dissociation; hexafluoropropylene oxide; carbenes; thermal decomposition; MPD spectrum.
View MoreShanghai Yingrui Biopharma Co., Ltd
Contact:021-3358 8661*8003
Address:shanghai
Chengdu D-Innovation Pharmaceutical Co., Ltd
Contact:86-28-85105536
Address:1001, B6, No.88 Keyuan South Road, Chengdu Hi-Tech Zone
RongCheng K&S Chemical Co.,Ltd
Contact:0631-7336369
Address:rongcheng ,shandong province china
Guangzhou Probig Fine Chemical Co., Ltd.
Contact:020-86297874
Address:No.2, 1/F, No.20, Hetai Road,Hebian Village, Baiyun District,Guangzhou,China
Contact:+86-533-3112891
Address:zibo
Doi:10.1002/ardp.19853180707
(1985)Doi:10.1021/ja01312a033
(1935)Doi:10.1002/anie.201404531
(2014)Doi:10.1021/acs.jafc.7b01499
(2018)Doi:10.1039/c6nj01893a
(2016)Doi:10.1039/c6cc05163d
(2016)