Tetrahedron p. 5379 - 5388 (1997)
Update date:2022-08-16
Topics:
Zoltewicz, John A.
Maier, Norbert M.
Lavieri, Sophie
Ghiviriga, Ion
Abboud, Khalil A.
Fabian, Walter M. F.
The title compounds, a mixture of anti and syn diastereomers, were prepared by Pd-catalyzed coupling of areneboronic acids with hetaryl halides. Energy barriers for the interconversion of the diastereomers obtained by kinetic and computational studies show a dependence on the location of the annular nitrogen atom, the ortho providing a smaller barrier than the meta nitrogen atom.
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