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7601-90-3

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7601-90-3 Usage

Chemical Description

Different sources of media describe the Chemical Description of 7601-90-3 differently. You can refer to the following data:
1. Perchloric acid is a strong acid used to stop enzymatic reactions.
2. Perchloric acid is a strong acid that is used in the production of perchlorate salts.
3. Perchloric acid is a strong acid that can donate protons to other molecules.
4. Perchloric acid is a strong mineral acid, and phosphorus oxychloride is a colorless liquid used as a chlorinating agent.
5. Perchloric acid is a strong acid with the chemical formula HClO4.

Safety Profile

Poison by ingestion and subcutaneous routes. A severe irritant to the eyes, skin, and mucous membranes. A powerful oxidizer. A severe explosion hazard; the anhydrous form can explode spontaneously. Potentially explosive reaction with acetic anhydride + ac

Check Digit Verification of cas no

The CAS Registry Mumber 7601-90-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,6,0 and 1 respectively; the second part has 2 digits, 9 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 7601-90:
(6*7)+(5*6)+(4*0)+(3*1)+(2*9)+(1*0)=93
93 % 10 = 3
So 7601-90-3 is a valid CAS Registry Number.
InChI:InChI=1/2ClHO4.2H2O/c2*2-1(3,4)5;;/h2*(H,2,3,4,5);2*1H2

7601-90-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name perchloric acid

1.2 Other means of identification

Product number -
Other names acid by mass [Forbidden]

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Laboratory chemicals,Oxidizing/reducing agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:7601-90-3 SDS

7601-90-3Synthetic route

hydrogenchloride
7647-01-0

hydrogenchloride

barium(II) perchlorate

barium(II) perchlorate

perchloric acid
7601-90-3

perchloric acid

Conditions
ConditionsYield
In water98.75%
In not given80%
silver perchlorate

silver perchlorate

A

perchloric acid
7601-90-3

perchloric acid

B

silver
7440-22-4

silver

Conditions
ConditionsYield
In acetonitrile byproducts: H2; Electrolysis; electrolysis of AgClO4 in CH3CN, Pt anode, 200 mA, 5V;; cathodic deposition of Ag, current yield 70 %;;A >99
B 97%
In acetonitrile byproducts: H2; Electrolysis; electrolysis of AgClO4 in CH3CN, Pt anode, 200 mA, 5V;; cathodic deposition of Ag, current yield 70 %;;A >99
B 97%
In acetonitrile byproducts: H2; Electrolysis; electrolysis of AgClO4 in CH3CN, Pt anode, 30 mA, 4V;; cathodic deposition of Ag, current yield 94 %;;A >99
B 90%
In acetonitrile byproducts: H2; Electrolysis; electrolysis of AgClO4 in CH3CN, Pt anode, 30 mA, 4V;; cathodic deposition of Ag, current yield 94 %;;A >99
B 90%
hydrogenchloride
7647-01-0

hydrogenchloride

sodium perchlorate

sodium perchlorate

perchloric acid
7601-90-3

perchloric acid

Conditions
ConditionsYield
In not given concd. HCl is added to NaClO4; filtering; filtrate is heated to 135°C;; acid is free of Cl(1-);;95%
In water part of cyclic process;;
In water byproducts: NaCl; addn. of concd. HCl to NaClO4 under formation of NaCl; concg. soln. under removing of HCl excess;;
In not given byproducts: NaCl; aq. HClO4 is obtained;;
In water part of cyclic process;;
barium(II) perchlorate

barium(II) perchlorate

perchloric acid
7601-90-3

perchloric acid

Conditions
ConditionsYield
With hydrogenchloride In hydrogenchloride addition of 20% HCl-solution to solid waterfree Ba(ClO4)2 forms HClO4;;95%
With HCl In hydrogenchloride addition of 20% HCl-solution to solid waterfree Ba(ClO4)2 forms HClO4;;95%
With hydrogenchloride In hydrogenchloride addition of concd. HCl-solution to solid waterfree Ba(ClO4)2 forms HClO4;;90%
With HCl In hydrogenchloride addition of concd. HCl-solution to solid waterfree Ba(ClO4)2 forms HClO4;;90%
fluorosilicic acid

fluorosilicic acid

potassium perchlorate

potassium perchlorate

perchloric acid
7601-90-3

perchloric acid

Conditions
ConditionsYield
In water byproducts: K2SiF6; 30% aq. H2SiF6 is added to a boiling aq. soln. of KClO4; mixt. is boiled for 1 h;; K2SiF6 and KClO4 is filtered off; H2SiF6 and H2SO4 is removed by BaCl2; evapn.; diln.; purity of acid depends on purity of H2SiF6; chem. pure acid is obtained by distn. under reduced pressure;;80%
In water excess of H2SiF6 is removed by BaCl2 or Ba(OH)2; Fe is removed by K4Fe(CN)6; evapn. to remove other impurities; acid contains alkali and K;;
1-benzyl-5,7-dimethyl-4,6-dioxo-4,5,6,7-tetrahydropyrazolo<3,4-d>pyrimidine
106379-46-8

1-benzyl-5,7-dimethyl-4,6-dioxo-4,5,6,7-tetrahydropyrazolo<3,4-d>pyrimidine

A

perchloric acid
7601-90-3

perchloric acid

B

5,7-dimethylpyrazolo<3,4-d>pyrimidine-4,6(5H,7H)-dione
4680-51-7

5,7-dimethylpyrazolo<3,4-d>pyrimidine-4,6(5H,7H)-dione

Conditions
ConditionsYield
With palladium on activated charcoal; ethanol Hydrogenation;
water
7732-18-5

water

fluoren-9-one; perchlorate

fluoren-9-one; perchlorate

A

perchloric acid
7601-90-3

perchloric acid

B

9-fluorenone
486-25-9

9-fluorenone

ethanol
64-17-5

ethanol

triphenylmethyl perchlorate

triphenylmethyl perchlorate

A

perchloric acid
7601-90-3

perchloric acid

B

Triphenylmethylethylether
968-39-8

Triphenylmethylethylether

methanol
67-56-1

methanol

triphenylmethyl perchlorate

triphenylmethyl perchlorate

A

perchloric acid
7601-90-3

perchloric acid

B

methoxytriphenylmethane
596-31-6

methoxytriphenylmethane

chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

water
7732-18-5

water

A

hydrogenchloride
7647-01-0

hydrogenchloride

B

perchloric acid
7601-90-3

perchloric acid

Conditions
ConditionsYield
In water reaction of ClO2 and O3; addn. of water;;
water
7732-18-5

water

chlorine
7782-50-5

chlorine

A

perchloric acid
7601-90-3

perchloric acid

B

chloride
16887-00-6

chloride

Conditions
ConditionsYield
With moisture In water reaction of O3 and Cl2 in presence of moisture; addn. of water;;
water
7732-18-5

water

chlorine
7782-50-5

chlorine

perchloric acid
7601-90-3

perchloric acid

Conditions
ConditionsYield
In neat (no solvent) Irradiation (UV/VIS); at 1800 - 4000 Å; condensation in liquid O2;;
In neat (no solvent) Irradiation (UV/VIS); at 1800 - 4000 Å; condensation in liquid O2;;
hypochloric acid
14989-30-1

hypochloric acid

perchloric acid
7601-90-3

perchloric acid

Conditions
ConditionsYield
In water ozonized air is passed through an aq. soln. of HClO;;
sulfuric acid
7664-93-9

sulfuric acid

potassium perchlorate

potassium perchlorate

water
7732-18-5

water

perchloric acid
7601-90-3

perchloric acid

Conditions
ConditionsYield
In not given distg. at a pressure below 100 Torr; steam is added to prevent formation of solid HClO4*H2O;; obtained HClO4 is 88 to 98% in H2O;;
In not given distg. at a pressure below 100 Torr; steam is added to prevent formation of solid HClO4*H2O;; acid contains 20 to 25% H2SO4;;
sodium chlorate

sodium chlorate

water
7732-18-5

water

A

perchloric acid
7601-90-3

perchloric acid

B

sodium hydroxide
1310-73-2

sodium hydroxide

Conditions
ConditionsYield
In water Electrolysis; vacuum distillation under concg. of 2 n HClO4 soln.;;
In water Electrolysis; vacuum distillation under concg. of 2 n HClO4 soln.;;
hydrogenchloride
7647-01-0

hydrogenchloride

water
7732-18-5

water

perchloric acid
7601-90-3

perchloric acid

Conditions
ConditionsYield
In water Electrolysis; anodic oxidation;;
In water Electrolysis; anodic oxidation;;
water
7732-18-5

water

chlorine
7782-50-5

chlorine

perchloric acid
7601-90-3

perchloric acid

Conditions
ConditionsYield
In water Electrolysis; O2 and H2 are evolved on electrodes; after some time a vol. ratio O2:H2=1:2 has established; oxygen reacts with free chlorine to form perchlorate;;
In water Electrolysis;
In water Electrolysis; O2 and H2 are evolved on electrodes; after some time a vol. ratio O2:H2=1:2 has established; oxygen reacts with free chlorine to form perchlorate;;
dichlorine hexoxide

dichlorine hexoxide

water
7732-18-5

water

A

perchloric acid
7601-90-3

perchloric acid

B

chloric acid
7790-93-4

chloric acid

Conditions
ConditionsYield
In gas common condensing of educts;;
perchloric acid monohydrate
13444-99-0, 501680-61-1

perchloric acid monohydrate

perchloric acid
7601-90-3

perchloric acid

Conditions
ConditionsYield
In not given repeated freezing out;;
In neat (no solvent) decompn. at 110°C into anhyd. HClO4 and a less volatile aq. acid;;
In neat (no solvent) decompn. at 110°C into anhyd. HClO4 and a less volatile aq. acid;;
chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

A

hydrogenchloride
7647-01-0

hydrogenchloride

B

perchloric acid
7601-90-3

perchloric acid

C

chloric acid
7790-93-4

chloric acid

Conditions
ConditionsYield
In water Irradiation (UV/VIS); decompn. in sunlight;;
In water Irradiation (UV/VIS); reaction in sunlight;;
In water Irradiation (UV/VIS); reaction in sunlight;;
chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

perchloric acid
7601-90-3

perchloric acid

Conditions
ConditionsYield
In not given Irradiation (UV/VIS); at 20°C;;
In not given Irradiation (UV/VIS);
With PbO2 hydrate In not given
iron(III) perchlorate

iron(III) perchlorate

perchloric acid
7601-90-3

perchloric acid

Conditions
ConditionsYield
In water byproducts: Fe(OH)3, H2O; thermal decompn.;;
dichlorine hexaoxide

dichlorine hexaoxide

hydrogen fluoride
7664-39-3

hydrogen fluoride

A

perchloric acid
7601-90-3

perchloric acid

B

chloryl fluoride
13637-83-7

chloryl fluoride

Conditions
ConditionsYield
Pt apparatus, 6°C, equilibrium reaction;
Pt apparatus, 6°C, equilibrium reaction;
potassium chlorate
3811-04-9

potassium chlorate

sulfuric acid
7664-93-9

sulfuric acid

potassium chloride

potassium chloride

perchloric acid
7601-90-3

perchloric acid

Conditions
ConditionsYield
In water heating;;0%
silicon monoxide

silicon monoxide

hydrogen fluoride
7664-39-3

hydrogen fluoride

silver perchlorate

silver perchlorate

A

perchloric acid
7601-90-3

perchloric acid

B

fluorosilicic acid

fluorosilicic acid

C

silver
7440-22-4

silver

Conditions
ConditionsYield
In hydrogen fluoride byproducts: H2O; aq. HF;
sulfuric acid
7664-93-9

sulfuric acid

barium(II) perchlorate

barium(II) perchlorate

perchloric acid
7601-90-3

perchloric acid

Conditions
ConditionsYield
In not given aq. acid is obtaind; HCl is removed by heating to 135°C;;
In water aluminium shot is added; heating to 110°C for 10h; Cl(1-) is removed by Ag2O; distg. with H2SO4; anhyd. acid is obtained;;
calcium perchlorate

calcium perchlorate

perchloric acid
7601-90-3

perchloric acid

Conditions
ConditionsYield
In water byproducts: Ca(OH)2, H2O; thermal decompn.;;
chloride
16887-00-6

chloride

perchloric acid
7601-90-3

perchloric acid

Conditions
ConditionsYield
In not given Electrolysis; in accumulator;;

A

perchloric acid
7601-90-3

perchloric acid

B

chloric acid
7790-93-4

chloric acid

Conditions
ConditionsYield
With water In not given Electrolysis;
With H2O In not given Electrolysis;
perchloric acid
7601-90-3

perchloric acid

pentetrazole
54-95-5

pentetrazole

1-ferrocenylmethanol
1273-86-5

1-ferrocenylmethanol

3(4)-(ferrocenylmethylene)-1,5-pentamethylenetetrazolium perchlorate

3(4)-(ferrocenylmethylene)-1,5-pentamethylenetetrazolium perchlorate

Conditions
ConditionsYield
In dichloromethane; water aq. HClO4 was added to mixt. of corazol and Fe-complex in CH2Cl2, 12 min, Et2O was added; filtered, washed with ether, dried; elem. anal.;100%
perchloric acid
7601-90-3

perchloric acid

oxygen
80937-33-3

oxygen

dihydrogen peroxide
7722-84-1

dihydrogen peroxide

Conditions
ConditionsYield
With C57H42CoFe3N4 at 20℃; Catalytic behavior; Reagent/catalyst; Electrochemical reaction;100%
With catalyst: Ba/carbon In perchloric acid aq. HClO4; Electrochem. Process; electroreduced on Ba/carbon in 0.1 M HClO4 (1 bar, 21+/-0.5°C, 1.2 V vs. RHE);
With catalyst: Ce/carbon In perchloric acid aq. HClO4; Electrochem. Process; electroreduced on Ce/carbon in 0.1 M HClO4 (1 bar, 21+/-0.5°C, 1.2 V vs. RHE);
perchloric acid
7601-90-3

perchloric acid

[CoIII(1,4,8,12-tetramethyl-1,4,8,12-tetraazacyclopentadecane)(O2)]+

[CoIII(1,4,8,12-tetramethyl-1,4,8,12-tetraazacyclopentadecane)(O2)]+

acetonitrile
75-05-8

acetonitrile

[CoIII(1,4,8,12-tetramethyl-1,4,8,12-tetraazacyclopentadecane)(O2H)(CH3CN)]2+

[CoIII(1,4,8,12-tetramethyl-1,4,8,12-tetraazacyclopentadecane)(O2H)(CH3CN)]2+

Conditions
ConditionsYield
at 0℃;100%
2,6-Diacetylpyridine
1129-30-2

2,6-Diacetylpyridine

perchloric acid
7601-90-3

perchloric acid

palladium diacetate
3375-31-3

palladium diacetate

[Pd(O1,N1,C1-pyridine-2-acetyl-6-(C(O)CH2))(acetonitrile)]ClO4
1372169-85-1

[Pd(O1,N1,C1-pyridine-2-acetyl-6-(C(O)CH2))(acetonitrile)]ClO4

Conditions
ConditionsYield
Stage #1: 2,6-Diacetylpyridine; perchloric acid In diethyl ether; water for 2h; Inert atmosphere;
Stage #2: palladium diacetate In diethyl ether; water; acetonitrile for 2h; Inert atmosphere;
100%
perchloric acid
7601-90-3

perchloric acid

N,N'-dimethyl-N,N'-ethylenebis(2-aminomethyl-4-bromo-6-formylphenolato)copper(II)
181575-42-8

N,N'-dimethyl-N,N'-ethylenebis(2-aminomethyl-4-bromo-6-formylphenolato)copper(II)

ethylenediamine
107-15-3

ethylenediamine

(Cu(H(CH2N(CH3)CH2C6H2OBrCHNCH2)2))2(2+)*2ClO4(1-)=((Cu(H(CH2N(CH3)CH2C6H2OBrCHNCH2)2))2)(ClO4)2

(Cu(H(CH2N(CH3)CH2C6H2OBrCHNCH2)2))2(2+)*2ClO4(1-)=((Cu(H(CH2N(CH3)CH2C6H2OBrCHNCH2)2))2)(ClO4)2

Conditions
ConditionsYield
In water; N,N-dimethyl-formamide to soln. ethylenediamine in DMF Cu complex was added and stirred at roomtemp. for 2 h, suspn. was acidified with aq. HClO4; ppt. was collected, washed with Et2O and dried in vacuo; elem. anal.;99%
perchloric acid
7601-90-3

perchloric acid

[Cr2(tris(2-pyridylmethyl)amine)2(μ-O)(μ-C2H5NO)](ClO4)4

[Cr2(tris(2-pyridylmethyl)amine)2(μ-O)(μ-C2H5NO)](ClO4)4

[Cr2(tris(2-pyridylmethyl)amine)2(μ-OH)(μ-C2H5NO)](ClO4)5

[Cr2(tris(2-pyridylmethyl)amine)2(μ-OH)(μ-C2H5NO)](ClO4)5

Conditions
ConditionsYield
In acetonitrile addn. of one drop concd. HClO4 to soln. of Cr-complex; pptn. on ether addn., washing (ether), drying in air; elem. anal.;99%
hydrogenchloride
7647-01-0

hydrogenchloride

perchloric acid
7601-90-3

perchloric acid

α-antiβ-[Co(3,6,9-triazaundecane-1,11-diamine)OH2]Cl3 * H2O

α-antiβ-[Co(3,6,9-triazaundecane-1,11-diamine)OH2]Cl3 * H2O

α-antiβ-[Co(3,6,9-triazaundecane-1,11-diamine)OH2]Cl2 * ClO4 * 0.5H2O

α-antiβ-[Co(3,6,9-triazaundecane-1,11-diamine)OH2]Cl2 * ClO4 * 0.5H2O

Conditions
ConditionsYield
In water crystn. on cooling, collection, washing (EtOH, ether), drying (air);99%
perchloric acid
7601-90-3

perchloric acid

[CH2(CH2NHCH2CH2NHCH2)2NC3N3(NH2)2Cu(OClO3)2]*H2O
449146-32-1

[CH2(CH2NHCH2CH2NHCH2)2NC3N3(NH2)2Cu(OClO3)2]*H2O

Cu(CH2(CH2NHCH2CH2NHCH2)2NC3N3H(NH2)2)(ClO4)2(1+)*ClO4(1-)*H2O=[CH2(CH2NHCH2CH2NHCH2)2NC3N3H(NH2)2Cu(OClO3)2]ClO4*H2O
449728-76-1

Cu(CH2(CH2NHCH2CH2NHCH2)2NC3N3H(NH2)2)(ClO4)2(1+)*ClO4(1-)*H2O=[CH2(CH2NHCH2CH2NHCH2)2NC3N3H(NH2)2Cu(OClO3)2]ClO4*H2O

Conditions
ConditionsYield
In perchloric acid aq. HClO4; 0.1 M HClO4; recrystn., elem. anal.;99%
perchloric acid
7601-90-3

perchloric acid

trans-[Mo(O)2(1,2-bis(diphenylphosphino)ethane)2] * 2 CH3OH

trans-[Mo(O)2(1,2-bis(diphenylphosphino)ethane)2] * 2 CH3OH

trans-[Mo(O)(OH)(1,2-bis(diphenylphosphino)ethane)2](ClO4)

trans-[Mo(O)(OH)(1,2-bis(diphenylphosphino)ethane)2](ClO4)

Conditions
ConditionsYield
In methanol slow addn. of excess 1 M HClO4 to Mo-complex; crystn.; elem. anal.;99%
perchloric acid
7601-90-3

perchloric acid

1-methyl-5-phenyltetrazole
20743-50-4

1-methyl-5-phenyltetrazole

1-ferrocenylmethanol
1273-86-5

1-ferrocenylmethanol

C5H5FeC5H4CH2N4CCH3C6H5(1+)*ClO4(1-)=C5H5FeC5H4CH2N4CCH3C6H5ClO4

C5H5FeC5H4CH2N4CCH3C6H5(1+)*ClO4(1-)=C5H5FeC5H4CH2N4CCH3C6H5ClO4

Conditions
ConditionsYield
In dichloromethane; water aq. HClO4 was added to mixt. of corazol and Fe-complex in CH2Cl2, 15 min, Et2O was added; filtered, washed with ether, dried; elem. anal.;99%
perchloric acid
7601-90-3

perchloric acid

1-ferrocenylmethanol
1273-86-5

1-ferrocenylmethanol

1,5-diphenyltetrazole
7477-73-8

1,5-diphenyltetrazole

C5H5FeC5H4CH2N4C(C6H5)2(1+)*ClO4(1-)=C5H5FeC5H4CH2N4C(C6H5)2ClO4

C5H5FeC5H4CH2N4C(C6H5)2(1+)*ClO4(1-)=C5H5FeC5H4CH2N4C(C6H5)2ClO4

Conditions
ConditionsYield
In dichloromethane; water aq. HClO4 was added to mixt. of corazol and Fe-complex in CH2Cl2, 20 min, Et2O was added; filtered, washed with ether, dried; elem. anal.;99%
perchloric acid
7601-90-3

perchloric acid

Mn4O4(O2P(C6H4OCH3)2)6

Mn4O4(O2P(C6H4OCH3)2)6

Mn4O4(O2P(C6H4OCH3)2)6(1+)*ClO4(1-)=(Mn4O4(O2P(C6H4OCH3)2)6)ClO4

Mn4O4(O2P(C6H4OCH3)2)6(1+)*ClO4(1-)=(Mn4O4(O2P(C6H4OCH3)2)6)ClO4

Conditions
ConditionsYield
With air In not given Mn complex oxidized by air in presence of HClO4;99%
copper (II) carbonate hydroxide

copper (II) carbonate hydroxide

perchloric acid
7601-90-3

perchloric acid

1,10-Phenanthroline
66-71-7

1,10-Phenanthroline

{Cu(H2O)phan2}(ClO4)2

{Cu(H2O)phan2}(ClO4)2

Conditions
ConditionsYield
Stage #1: copper (II) carbonate hydroxide; perchloric acid In isopropyl alcohol for 0.166667h; Heating;
Stage #2: 1,10-Phenanthroline In isopropyl alcohol at 20℃;
99%
perchloric acid
7601-90-3

perchloric acid

chloro(2,3,7,8,12,13,17,18-octaethylporphyrinato-N,N',N'',N''')iron(III) complex
28755-93-3

chloro(2,3,7,8,12,13,17,18-octaethylporphyrinato-N,N',N'',N''')iron(III) complex

bis(methanol-O)(2,3,7,8,12,13,17,18-octaethylporphyrinato-N,N',N'',N''')iron(III) perchlorate bis(methanol) solvate

bis(methanol-O)(2,3,7,8,12,13,17,18-octaethylporphyrinato-N,N',N'',N''')iron(III) perchlorate bis(methanol) solvate

Conditions
ConditionsYield
In methanol treating with 5% HClO4 for 2 d, stay for 2 d to crystn.;98%
perchloric acid
7601-90-3

perchloric acid

di-μ-chloro-bis[chloro(η5-pentamethylcyclopentadienyl)cobalt]
82595-77-5

di-μ-chloro-bis[chloro(η5-pentamethylcyclopentadienyl)cobalt]

Triaqua(pentamethylcyclopentadienyl)cobalt-diperchlorat

Triaqua(pentamethylcyclopentadienyl)cobalt-diperchlorat

Conditions
ConditionsYield
evapn. at 0 °C in high vac.;98%
perchloric acid
7601-90-3

perchloric acid

ferrocenyl(2,4,6-trimethoxyphenyl)methanol
223139-66-0

ferrocenyl(2,4,6-trimethoxyphenyl)methanol

Ferrocenyl(2,4,6-trimethoxyphenyl)carbenium perchlorate
223139-82-0

Ferrocenyl(2,4,6-trimethoxyphenyl)carbenium perchlorate

Conditions
ConditionsYield
In perchloric acid; ethanol aq. HClO4; stirring Fe-complex suspn. (in EtOH) with 1.1 equiv. of 60% aq. HClO4 (0°C, 15 min); crystn. (-30°C);98%
In perchloric acid; diethyl ether aq. HClO4; stirring Fe-complex with slight excess of 60% HClO4 (0°C, 15 min); elem. anal.;94%
In methanol; perchloric acid aq. HClO4; stirring Fe-complex suspn. (in MeOH) with 1.1 equiv. of 60% aq. HClO4 (0°C, 15 min); crystn. (-30°C);86%
perchloric acid
7601-90-3

perchloric acid

trans-[PtCl{(E)-HNC(Me)OMe}2(PPh3)]Cl*2H2O

trans-[PtCl{(E)-HNC(Me)OMe}2(PPh3)]Cl*2H2O

trans-[PtCl{(E)-HN=C(Me)OMe}2(PPh3)](ClO4)

trans-[PtCl{(E)-HN=C(Me)OMe}2(PPh3)](ClO4)

Conditions
ConditionsYield
In water pH=3;98%
perchloric acid
7601-90-3

perchloric acid

C48H54N3O6P3Pd3

C48H54N3O6P3Pd3

acetonitrile
75-05-8

acetonitrile

C48H54N6P3Pd3(3+)*3ClO4(1-)

C48H54N6P3Pd3(3+)*3ClO4(1-)

Conditions
ConditionsYield
Stage #1: perchloric acid; C48H54N3O6P3Pd3 In tetrahydrofuran; water at 20℃; for 12h; Inert atmosphere;
Stage #2: acetonitrile Inert atmosphere;
98%
copper (II) carbonate hydroxide

copper (II) carbonate hydroxide

perchloric acid
7601-90-3

perchloric acid

1,10-Phenanthroline
66-71-7

1,10-Phenanthroline

Cu(1,10-phenanthroline)(OH2)2(OClO3)2

Cu(1,10-phenanthroline)(OH2)2(OClO3)2

Conditions
ConditionsYield
Stage #1: copper (II) carbonate hydroxide; perchloric acid In isopropyl alcohol for 0.166667h; Heating;
Stage #2: 1,10-Phenanthroline In isopropyl alcohol at 20℃; for 3h;
98%
perchloric acid
7601-90-3

perchloric acid

bis[3-(dimethylamino)propyl]tin dichloride
133957-42-3

bis[3-(dimethylamino)propyl]tin dichloride

C10H26Cl3N2O4Sn(1+)*ClO4(1-)

C10H26Cl3N2O4Sn(1+)*ClO4(1-)

Conditions
ConditionsYield
In water for 5h;98%
perchloric acid
7601-90-3

perchloric acid

bis(3-(dimethylamino)propyl)difluorodistannane dihydrate

bis(3-(dimethylamino)propyl)difluorodistannane dihydrate

C10H26F2N2Sn(2+)*2ClO4(1-)

C10H26F2N2Sn(2+)*2ClO4(1-)

Conditions
ConditionsYield
In water for 1h;98%
methanol
67-56-1

methanol

perchloric acid
7601-90-3

perchloric acid

[ReH2(nitrosyl)(triphenylphosphine)3]
58694-74-9

[ReH2(nitrosyl)(triphenylphosphine)3]

{ReH(CH3OH)(NO)(P(C6H5)3)3}(1+)*ClO4(1-)={ReH(CH3OH)(NO)(P(C6H5)3)3}ClO4

{ReH(CH3OH)(NO)(P(C6H5)3)3}(1+)*ClO4(1-)={ReH(CH3OH)(NO)(P(C6H5)3)3}ClO4

Conditions
ConditionsYield
In dichloromethane Re-compd. and HClO4 suspended in MeOH at 0°C, addn. of CH2Cl2 until reaction had begun, addn. of diethyl ether, stirred for 5 min at 0°C; filtered (vac., N2), washed (diethyl ether);97%
perchloric acid
7601-90-3

perchloric acid

ferrocenyl(2,6-dimethoxyphenyl)methanol
223139-72-8

ferrocenyl(2,6-dimethoxyphenyl)methanol

Ferrocenyl(2,6-dimethoxyphenyl)carbenium perchlorate
223139-96-6

Ferrocenyl(2,6-dimethoxyphenyl)carbenium perchlorate

Conditions
ConditionsYield
In perchloric acid; diethyl ether aq. HClO4; stirring Fe-complex with slight excess of 60% HClO4 (0°C, 15 min); elem. anal.;97%
perchloric acid
7601-90-3

perchloric acid

silver(l) oxide
20667-12-3

silver(l) oxide

[Ag(cyanogunidine)2]ClO4
573987-19-6

[Ag(cyanogunidine)2]ClO4

Conditions
ConditionsYield
In water Ag2O was dissolved in aq. HClO4 in a polypropylene beaker, 4 equiv. of N-compd. was added in H2O; standing for 20 min at room temp., crystals were filtered, washed with small vol. of ice-cold H2O, dried in a desiccator; filtrate waskept at 0 °C for 24 h, further amt. of compd. could be isolated, elem. anal.;97%
perchloric acid
7601-90-3

perchloric acid

1-phenyl-1,2-butanedione
3457-55-4

1-phenyl-1,2-butanedione

2-amino-5-trifluoromethyl-1,3,4-thiadiazole
10444-89-0

2-amino-5-trifluoromethyl-1,3,4-thiadiazole

A

C5HN3SCH3CF3C6H5(1+)*ClO4(1-)

C5HN3SCH3CF3C6H5(1+)*ClO4(1-)

B

7-methyl-5-phenyl-2-trifluoromethyl-[1,3,4]thiadiazolo[3,2-a]pyrimidinylium; perchlorate

7-methyl-5-phenyl-2-trifluoromethyl-[1,3,4]thiadiazolo[3,2-a]pyrimidinylium; perchlorate

Conditions
ConditionsYield
In ethanol in boiling ethanol ( 0.2 h ), with 20 % 1-phenylbutane-1,2-dione excess;A 4%
B 96%
In ethanol in boiling ethanol ( 0.2 h ), with 20 % 1-phenylbutane-1,2-dione excess;A 4%
B 96%
formaldehyd
50-00-0

formaldehyd

formic acid
64-18-6

formic acid

perchloric acid
7601-90-3

perchloric acid

(1,8-diammonio-3,6,10,13,16,19-hexaazabicyclo[6.6.6]icosane) copper(II) nitrate

(1,8-diammonio-3,6,10,13,16,19-hexaazabicyclo[6.6.6]icosane) copper(II) nitrate

(1,8-bis(dimethylammonio)-3,6,10,13,16,19-hexaazabicyclo[6.6.6]icosane) copper(II) perchlorate trihydrate

(1,8-bis(dimethylammonio)-3,6,10,13,16,19-hexaazabicyclo[6.6.6]icosane) copper(II) perchlorate trihydrate

Conditions
ConditionsYield
In formic acid aq. formic acid; refluxing soln. of Cu-complex and HCHO (48 h), evapn. (reduced pressure), dissolving in hot H2O, pptn. on HClO4 addn.; filtration, washing (EtOH, Et2O), drying (vac. desiccator); elem. anal.;96%
perchloric acid
7601-90-3

perchloric acid

10-methyl-9, 10-dihydro-9-acridinone
719-54-0

10-methyl-9, 10-dihydro-9-acridinone

2,4,6-trimethylphenyl bromide
576-83-0

2,4,6-trimethylphenyl bromide

9-(2-mesityl)-10-methylacridinium perchlorate

9-(2-mesityl)-10-methylacridinium perchlorate

Conditions
ConditionsYield
Stage #1: 2,4,6-trimethylphenyl bromide With tert.-butyl lithium In diethyl ether; pentane at -78℃; for 0.5h; Cooling with acetone-dry ice;
Stage #2: 10-methyl-9, 10-dihydro-9-acridinone In diethyl ether; pentane at -78 - 25℃; for 72h; Cooling with acetone-dry ice;
Stage #3: perchloric acid In ethyl acetate
96%
perchloric acid
7601-90-3

perchloric acid

C13H11N2O2S(1-)*Cu(2+)*NO3(1-)

C13H11N2O2S(1-)*Cu(2+)*NO3(1-)

acetonitrile
75-05-8

acetonitrile

C13H11N2O2S(1-)*Cu(2+)*C2H3N*ClO4(1-)

C13H11N2O2S(1-)*Cu(2+)*C2H3N*ClO4(1-)

Conditions
ConditionsYield
Stage #1: perchloric acid; C13H11N2O2S(1-)*Cu(2+)*NO3(1-) In methanol; water for 4h;
Stage #2: acetonitrile In methanol; dichloromethane
96%

7601-90-3Relevant articles and documents

Mathers

, p. 66 - 66 (1910)

Effect of rGO-Fe2O3 nanocomposites fabricated in different solvents on the thermal decomposition properties of ammonium perchlorate

Zhang, Ming,Zhao, Fengqi,Yang, Yanjing,Zhang, Jiankan,Li, Na,Gao, Hongxu

, p. 7010 - 7019 (2018)

rGO-Fe2O3 composites were prepared using different solvents (distilled water, ethanol, N-methylpyrrolidone, ethyl acetate, n-butyl alcohol and N,N-dimethylformamide) via a simple solvothermal method and characterized by SEM, TEM, XRD

Goddard, D. R.,Hughes, E. D.,Ingold, C. K.

, p. 480 - 480 (1946)

Willard

, p. 1480 - 1480 (1912)

Trowbridge, J. C.,Westrum, E. F.

, p. 42 - 49 (1964)

The effect of specific surface area of TiO2 on the thermal decomposition of ammonium perchlorate

Fujimura, Kaori,Miyake, Atsumi

, p. 27 - 31 (2010)

The thermal decomposition of ammonium perchlorate (AP) is considered to be the first step in the combustion of AP-based composite propellants. In this report, the effect of the specific surface area of titanium oxide (TiO 2) catalysts on the thermal decomposition characteristics of AP was examined with a series of thermal analysis experiments. It was clear that the thermal decomposition temperature of AP decreased when the specific surface area of TiO2 increased. It was also possible that TiO2 influences the frequency factor of AP decomposition because there was no observable effect on the activation energy. Akademiai Kiado, Budapest, Hungary 2009.

Supercritical solvothermal synthesis and formation mechanism of V2O3 microspheres with excellent catalytic activity on the thermal decomposition of ammonium perchlorate

Yang, Liuqing,Li, Xiaofang,Zhang, Xiongzhi,Huang, Chi

, p. 1394 - 1402 (2019)

V2O3 with the structure of microspheres has been successfully synthesized by a facile supercritical solvothermal method. The samples have a rhombohedral structure and the morphology of microspheres. The formation mechanism is proposed on the basis of the discussion on the self-assembly process of uniform microsphere structure. Furthermore, the catalytic activity of as-obtained V2O3 microspheres was investigated through the thermal decomposition of ammonium perchlorate (AP). The thermal decomposition temperature was reduced by 46 °C in the presence of 2 wt% of V2O3 microspheres, indicating that V2O3 with microspheres structure has excellent catalytic property. In addition, the possible catalytic mechanism of the microspheres for the thermal decomposition of AP is simply discussed. This study provides a simple way to control the morphology of V2O3 nanostructure, which also exhibits the potential application in modern science and technology.

Facile fabrication of porous La doped ZnO granular nanocrystallites and their catalytic evaluation towards thermal decomposition of ammonium perchlorate

Jagtap,Kshirsagar,Khire,Pardeshi

, p. 194 - 204 (2019/05/17)

The present article expresses synthesis, characterization and catalytic activity of pure and La doped ZnO (La-ZnO)towards thermal decomposition of Ammonium Perchlorate (AP). The catalytic materials (La-ZnO)with 0–1.00% of doped La were synthesized by simple co-precipitation method and thoroughly characterized by several spectroscopic techniques like FT-IR, XRD, UV–Visible, PL, SEM-EDS and BET analysis. The XRD pattern of synthesized materials displayed wurtzite ZnO structure. The SEM images of the materials showed granular morphology where gradual increase in particle size and crystallite size was observed to be increased with increase in doped La concentration. The BET surface area of the materials was 28.203 to 15.830 m2/g and exhibited mesoporous nature. In catalytic studies for thermal decomposition of AP, the pure ZnO catalyst offered single stage decomposition of AP along with lowering high-thermal decomposition (HTD)temperature of AP by 105 OC. However, La doped ZnO showed slightly lower activity due to promotion of NO formation in oxidation of ammonia generated on initial decomposition of AP and decrease in BET surface area.