Isolation of a Tetranuclear Iron Cluster Promoting CO2 Reduction and Intermediate to Iron Carbonyl Disproportionation

DOI: 10.1039/c39870000089

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 89 - 90 (1987)

Update date:2022-08-05

Topics:

Authors:

Fachinetti, Giuseppe

Fochi, Giovanni

Funaioli, Tiziana

Zanazzi, Pier Francesco

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39870000089

(py)Fe(CO)4 (py=pyridine) is formed on carbonylation of , and the 56 electron tetranuclear cluster <(py)2FeFe(CO)4>2, the crystal structure of which has been determined, is produced on dissolving (py)Fe(CO)4 in organic solvents; it behaves as a bifunctional molecule in reducing CO2 to CO, FeCO3 being formed during this reaction.

Full text of DOI:10.1039/c39870000089

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:{(C₅H₅N)2FeFe(CO)4}2

Cas No:107766-76-7

R&D Labs maybe for 107766-76-7

BrightGene Bio-Medical Technology Co., Ltd.

website:https://en.bright-gene.com/

Contact:+86-512-62551801

Address:Building C25 - C31, No. 218 Xinghu Road, Suzhou Industrial Park, Suzhou, Jiangsu, China.
Shanghai Profirst Co., Ltd.

Contact:+86-21-38122007

Address:2, Lane 1123, Kangqiao Road, Pudong New Area, Shanghai
Wuhan Yitongtai Science and Technology Co.,Ltd.

Contact:+86-27-88933550

Address:27th Fl. Bldg. 1, Shuian International Mansion, Heping Ave, Wuhan, Hubei, China
Oren Hydrocarbons (Qingdao) Co., Ltd.

Contact:+86-532-68607667-801

Address:Room 3 # 302, No.9 Qingyun Road, Qingdao, China
zonk drug r&d limited

Contact:+86-20-32051076

Address:1105,Building A, International Business Incubator,Science City

Relevant to this article

Tetraaryl-1,3-dioxolane-4,5-dimethanols as catalysts for the addition of trimethylsilyl cyanide to benzaldehyde and the oxirane ring

Doi:10.1007/s11172-007-0233-7
(2007)
Borane Anions with Bridging Cyanide Ligands; Preparation and Properties of Derivatives of ^- and ^-

Doi:10.1039/DT9860002645
(1986)
Selective thromboxane synthetase inhibitors and antihypertensive agents. New derivatives of 4-hydrazino-5H-pyridazino[4,5-b]indole, 4-hydrazinopyridazino[4,5-a]indole, and related compounds

Doi:10.1021/jm00389a012
(1987)
PALLADIUM-CATALYZED COUPLING OF ELECTROGENERATED ALLYLTIN REAGENTS

Doi:10.1016/S0040-4039(00)84981-3
(1986)
Facile synthesis and herbicidal activity of novel multisubstituted pyridine derivatives

Doi:10.1002/jhet.296
(2010)
Removal of metal-metal bonding in a dimetallic paddlewheel complex: Molecular and electronic structure of bis(phenyl) dirhodium(III) carboxamidate compounds

Doi:10.1021/om800631b
(2008)

Article Doi