Isolation of a Tetranuclear Iron Cluster Promoting CO2 Reduction and Intermediate to Iron Carbonyl Disproportionation

DOI: 10.1039/c39870000089

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 89 - 90 (1987)

Update date:2022-08-05

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Authors:

Fachinetti, Giuseppe

Fochi, Giovanni

Funaioli, Tiziana

Zanazzi, Pier Francesco

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Article abstract of DOI:10.1039/c39870000089

(py)Fe(CO)4 (py=pyridine) is formed on carbonylation of , and the 56 electron tetranuclear cluster <(py)2FeFe(CO)4>2, the crystal structure of which has been determined, is produced on dissolving (py)Fe(CO)4 in organic solvents; it behaves as a bifunctional molecule in reducing CO2 to CO, FeCO3 being formed during this reaction.

Full text of DOI:10.1039/c39870000089

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