Synthesis and Chemiluminescence of an α-Hydroperoxyacyl Cyanide

DOI: 10.1021/jo00254a056

Source and publish data:

Journal of Organic Chemistry p. 4635 - 4637 (1988)

Update date:2022-08-30

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Authors:

Jaroszewski, Jerzy W.

Ettlinger, Martin G.

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Article abstract of DOI:10.1021/jo00254a056

An isolable enol (3) reacts with triplet dioxygen to afford an α-hydroperoxyacyl cyanide (4); treatment of 4 with base provides evidence for the intermediacy of a 1,2-dioxetan-3-one (5).

Full text of DOI:10.1021/jo00254a056

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