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2045-00-3

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2045-00-3 Usage

Chemical Properties

grey-green to brown powder

Uses

o-Arsanilic Acid is an organoarsenic compound. o-Arsanilic Acid is a highly toxic contaminant and can be found in plants growing in contaminated soil.

Purification Methods

Crystallise it from water or ethanol/ether. POISONOUS. [Beilstein 16 I 463.]

Check Digit Verification of cas no

The CAS Registry Mumber 2045-00-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,0,4 and 5 respectively; the second part has 2 digits, 0 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 2045-00:
(6*2)+(5*0)+(4*4)+(3*5)+(2*0)+(1*0)=43
43 % 10 = 3
So 2045-00-3 is a valid CAS Registry Number.
InChI:InChI=1/C6H8AsNO3/c8-6-4-2-1-3-5(6)7(9,10)11/h1-4H,8H2,(H2,9,10,11)

2045-00-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name (2-aminophenyl)arsonic acid

1.2 Other means of identification

Product number -
Other names 2-Aminobenzenearsonic Acid

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:2045-00-3 SDS

2045-00-3Synthetic route

2-nitrophenylarsonic acid
5410-29-7

2-nitrophenylarsonic acid

sodium acetate
127-09-3

sodium acetate

o-arsanilic acid
2045-00-3

o-arsanilic acid

Conditions
ConditionsYield
With platinum Electrolysis;
2-nitrophenylarsonic acid
5410-29-7

2-nitrophenylarsonic acid

sodium acetate
127-09-3

sodium acetate

A

o-arsanilic acid
2045-00-3

o-arsanilic acid

B

(2,2'-hydrazo-diphenyl)-bis-arsonic acid

(2,2'-hydrazo-diphenyl)-bis-arsonic acid

Conditions
ConditionsYield
Reduktion an einer Platinkathode.Electrolysis;
2-nitrophenylarsonic acid
5410-29-7

2-nitrophenylarsonic acid

o-arsanilic acid
2045-00-3

o-arsanilic acid

Conditions
ConditionsYield
With iron(II) chloride in kalter alkalischer Loesung;
With water; iron; iron(II) chloride at 60 - 70℃;
With methanol; sodium amalgam at 55 - 60℃;
N,N'-bis-(2-arsono-phenyl)-oxalamide
861527-92-6

N,N'-bis-(2-arsono-phenyl)-oxalamide

o-arsanilic acid
2045-00-3

o-arsanilic acid

Conditions
ConditionsYield
With sulfuric acid
2-nitrophenylarsonic acid
5410-29-7

2-nitrophenylarsonic acid

iron (II)-chloride

iron (II)-chloride

o-arsanilic acid
2045-00-3

o-arsanilic acid

sodium-salt of/the/ 2-nitro-phenylarsonic acid

sodium-salt of/the/ 2-nitro-phenylarsonic acid

o-arsanilic acid
2045-00-3

o-arsanilic acid

Conditions
ConditionsYield
With ethanol; nickel at 50 - 90℃; under 69137.7 Torr; Hydrogenation;
o-chlorophenylarsonic acid
33781-24-7

o-chlorophenylarsonic acid

ammonium carbonate

ammonium carbonate

A

o-arsanilic acid
2045-00-3

o-arsanilic acid

B

(2,2'-imino-diphenyl)-bis-arsonic acid

(2,2'-imino-diphenyl)-bis-arsonic acid

Conditions
ConditionsYield
With pentan-1-ol; copper diacetate; potassium carbonate at 135℃;
sulfuric acid
7664-93-9

sulfuric acid

N,N'-bis-(2-arsono-phenyl)-oxalamide
861527-92-6

N,N'-bis-(2-arsono-phenyl)-oxalamide

o-arsanilic acid
2045-00-3

o-arsanilic acid

2-Nitrophenyldiazonium
25910-37-6

2-Nitrophenyldiazonium

o-arsanilic acid
2045-00-3

o-arsanilic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: alkali; sodium arsenite
2: NaOH-solution; ferrosulfate
View Scheme
Multi-step reaction with 2 steps
1: sodium arsenite
2: iron; iron (II)-chloride; water / 60 - 70 °C
View Scheme
Multi-step reaction with 2 steps
1: sodium arsenite
2: sodium amalgam (4 percent ); methanol / 55 - 60 °C
View Scheme
Multi-step reaction with 2 steps
1: sodium arsenite
2: iron (II)-chloride / in kalter alkalischer Loesung
View Scheme
o-arsanilic acid
2045-00-3

o-arsanilic acid

Methacryloyl chloride
920-46-7

Methacryloyl chloride

o-methacryloylaminophenylarsonic acid

o-methacryloylaminophenylarsonic acid

Conditions
ConditionsYield
In ethanol at 4℃; for 2h;90%
4-Chloro-2-methylthiopyrimidine
49844-90-8

4-Chloro-2-methylthiopyrimidine

o-arsanilic acid
2045-00-3

o-arsanilic acid

2-methylthio-4-(2'-aminophenylarsonic acid)aminopyrimidine

2-methylthio-4-(2'-aminophenylarsonic acid)aminopyrimidine

Conditions
ConditionsYield
With hydrogenchloride In isopropyl alcohol Heating;86%
With hydrogenchloride In isopropyl alcohol Heating;86.4%
for 24h; Heating;
o-arsanilic acid
2045-00-3

o-arsanilic acid

6,7-dimethoxy-4-chloroquinazoline
13790-39-1

6,7-dimethoxy-4-chloroquinazoline

4-(2'-phenylarsonic acid)amino-6,7-dimethoxyquinazoline

4-(2'-phenylarsonic acid)amino-6,7-dimethoxyquinazoline

Conditions
ConditionsYield
With hydrogenchloride In isopropyl alcohol Heating;83.2%
for 24h; Heating;
With hydrogenchloride In isopropyl alcohol Heating;
o-arsanilic acid
2045-00-3

o-arsanilic acid

6-chloropurine
87-42-3

6-chloropurine

6-(2'-phenylarsonic acid)aminopurine

6-(2'-phenylarsonic acid)aminopurine

Conditions
ConditionsYield
With hydrogenchloride In isopropyl alcohol Heating;73.4%
for 24h; Heating;
With hydrogenchloride In isopropyl alcohol Heating;
o-arsanilic acid
2045-00-3

o-arsanilic acid

acetylacetone
123-54-6

acetylacetone

(2-(2-(2,4-dioxopentan-3-ylidene)hydrazineyl) phenyl)arsonic acid
1288981-02-1

(2-(2-(2,4-dioxopentan-3-ylidene)hydrazineyl) phenyl)arsonic acid

Conditions
ConditionsYield
Stage #1: o-arsanilic acid With hydrogenchloride; sodium hydroxide; sodium nitrite In water at -0.16℃;
Stage #2: acetylacetone In water at -0.16℃; for 1h;
67%
o-arsanilic acid
2045-00-3

o-arsanilic acid

sodium monochloroacetic acid
3926-62-3

sodium monochloroacetic acid

2-(carboxymethylamino)phenylarsonic acid hydrochloride
1323372-55-9

2-(carboxymethylamino)phenylarsonic acid hydrochloride

Conditions
ConditionsYield
Stage #1: o-arsanilic acid; sodium monochloroacetic acid With potassium carbonate In water at 100℃; for 7h;
Stage #2: With hydrogenchloride In water pH=2 - 2.5;
60%
o-arsanilic acid
2045-00-3

o-arsanilic acid

salicylaldehyde
90-02-8

salicylaldehyde

(E)-(2-(2-hydroxybenzylidene)aminophenyl)arsonic acid

(E)-(2-(2-hydroxybenzylidene)aminophenyl)arsonic acid

Conditions
ConditionsYield
With hydrogenchloride In ethanol; water at 20℃; for 7h;34%
2,4-dinitrobromobenzene
584-48-5

2,4-dinitrobromobenzene

o-arsanilic acid
2045-00-3

o-arsanilic acid

[2-(2,4-dinitro-anilino)-phenyl]-arsonic acid
18016-88-1

[2-(2,4-dinitro-anilino)-phenyl]-arsonic acid

Conditions
ConditionsYield
With pentan-1-ol; copper; potassium carbonate
2-chloro-5-nitropyridine
4548-45-2

2-chloro-5-nitropyridine

o-arsanilic acid
2045-00-3

o-arsanilic acid

[2-(5-nitro-[2]pyridylamino)-phenyl]-arsonic acid

[2-(5-nitro-[2]pyridylamino)-phenyl]-arsonic acid

Conditions
ConditionsYield
With hydrogenchloride
Thioglycolamide
758-08-7

Thioglycolamide

o-arsanilic acid
2045-00-3

o-arsanilic acid

[(2-amino-phenyl)-arsanediyldimercapto]-di-acetic acid diamide

[(2-amino-phenyl)-arsanediyldimercapto]-di-acetic acid diamide

Conditions
ConditionsYield
With water
diethyl sulfate
64-67-5

diethyl sulfate

o-arsanilic acid
2045-00-3

o-arsanilic acid

(2-ethylamino-phenyl)-arsonic acid

(2-ethylamino-phenyl)-arsonic acid

Conditions
ConditionsYield
With sodium hydroxide
bromobenzene
108-86-1

bromobenzene

o-arsanilic acid
2045-00-3

o-arsanilic acid

(2-anilino-phenyl)-arsonic acid
872275-94-0

(2-anilino-phenyl)-arsonic acid

Conditions
ConditionsYield
With i-Amyl alcohol; copper; potassium carbonate at 130 - 140℃; Reagens 4:Kupfer(I)-jodid;
bromobenzene
108-86-1

bromobenzene

o-arsanilic acid
2045-00-3

o-arsanilic acid

(2-diphenylamino-phenyl)-arsonic acid

(2-diphenylamino-phenyl)-arsonic acid

Conditions
ConditionsYield
With i-Amyl alcohol; copper; potassium carbonate at 160 - 170℃; Reagens 4: Kupfer(I)-jodid;
1,3,5-trichloro-2,4,6-triazine
108-77-0

1,3,5-trichloro-2,4,6-triazine

o-arsanilic acid
2045-00-3

o-arsanilic acid

[2-(4,6-diamino-[1,3,5]triazin-2-ylamino)-phenyl]-arsonic acid

[2-(4,6-diamino-[1,3,5]triazin-2-ylamino)-phenyl]-arsonic acid

Conditions
ConditionsYield
With sodium hydroxide; acetone und Erhitzen des Reaktionsprodukts mit wss. NH3;
4-bromo-6-methoxy-2-methylquinoline
856095-00-6

4-bromo-6-methoxy-2-methylquinoline

o-arsanilic acid
2045-00-3

o-arsanilic acid

[2-(6-methoxy-2-methyl-[4]quinolylamino)-phenyl]-arsonic acid
872273-59-1

[2-(6-methoxy-2-methyl-[4]quinolylamino)-phenyl]-arsonic acid

Conditions
ConditionsYield
With pentan-1-ol; copper; potassium carbonate at 130 - 140℃; Reagens 4: Jod;
1-chloro-5-nitroisoquinoline
58142-97-5

1-chloro-5-nitroisoquinoline

o-arsanilic acid
2045-00-3

o-arsanilic acid

[2-(5-nitro-[1]isoquinolylamino)-phenyl]-arsonic acid

[2-(5-nitro-[1]isoquinolylamino)-phenyl]-arsonic acid

Conditions
ConditionsYield
With sodium hydroxide
4-bromo-phenol
106-41-2

4-bromo-phenol

o-arsanilic acid
2045-00-3

o-arsanilic acid

[2-(4-hydroxy-anilino)-phenyl]-arsonic acid

[2-(4-hydroxy-anilino)-phenyl]-arsonic acid

Conditions
ConditionsYield
With pentan-1-ol; copper; potassium carbonate
CYANAMID
420-04-2

CYANAMID

o-arsanilic acid
2045-00-3

o-arsanilic acid

(2-guanidino-phenyl)-arsonic acid

(2-guanidino-phenyl)-arsonic acid

Conditions
ConditionsYield
With hydrogenchloride
(2-chloroacetyl)urea
4791-21-3

(2-chloroacetyl)urea

o-arsanilic acid
2045-00-3

o-arsanilic acid

[2-(allophanoylmethyl-amino)-phenyl]-arsonic acid

[2-(allophanoylmethyl-amino)-phenyl]-arsonic acid

Conditions
ConditionsYield
With sodium hydroxide
1-(chloroacetyl)-3-methylurea
4791-22-4

1-(chloroacetyl)-3-methylurea

o-arsanilic acid
2045-00-3

o-arsanilic acid

(2-{[(4-methyl-allophanoyl)-methyl]-amino}-phenyl)-arsonic acid

(2-{[(4-methyl-allophanoyl)-methyl]-amino}-phenyl)-arsonic acid

Conditions
ConditionsYield
With sodium hydroxide
para-bromotoluene
106-38-7

para-bromotoluene

o-arsanilic acid
2045-00-3

o-arsanilic acid

(2-p-toluidino-phenyl)-arsonic acid
860236-55-1

(2-p-toluidino-phenyl)-arsonic acid

Conditions
ConditionsYield
With i-Amyl alcohol; copper; potassium carbonate
1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

o-arsanilic acid
2045-00-3

o-arsanilic acid

[2-(4-bromo-anilino)-phenyl]-arsonic acid

[2-(4-bromo-anilino)-phenyl]-arsonic acid

Conditions
ConditionsYield
at 130 - 140℃;
With i-Amyl alcohol; copper; potassium carbonate at 130 - 140℃; Reagens 4: Kupfer(I)-jodid;
1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

o-arsanilic acid
2045-00-3

o-arsanilic acid

{2-[bis-(4-bromo-phenyl)-amino]-phenyl}-arsonic acid

{2-[bis-(4-bromo-phenyl)-amino]-phenyl}-arsonic acid

Conditions
ConditionsYield
at 150 - 160℃;
With i-Amyl alcohol; copper; potassium carbonate at 150 - 160℃; Reagens 4: Kupfer(I)-jodid;
m-bromobenzoic acid
585-76-2

m-bromobenzoic acid

o-arsanilic acid
2045-00-3

o-arsanilic acid

3-(2-arsono-anilino)-benzoic acid
872276-17-0

3-(2-arsono-anilino)-benzoic acid

Conditions
ConditionsYield
/BRN= 3395862/;
m-bromobenzoic acid
585-76-2

m-bromobenzoic acid

o-arsanilic acid
2045-00-3

o-arsanilic acid

4-(2-arsono-anilino)-benzoic acid

4-(2-arsono-anilino)-benzoic acid

Conditions
ConditionsYield
With i-Amyl alcohol; copper; potassium carbonate at 145 - 155℃; Reagens 4: Kupfer(I)-jodid;
3-Bromonitrobenzene
585-79-5

3-Bromonitrobenzene

o-arsanilic acid
2045-00-3

o-arsanilic acid

[2-(3-nitro-anilino)-phenyl]-arsonic acid
873983-25-6

[2-(3-nitro-anilino)-phenyl]-arsonic acid

Conditions
ConditionsYield
With i-Amyl alcohol; copper; potassium carbonate at 145 - 150℃; Reagens 4: Kupfer(I)-jodid;
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

o-arsanilic acid
2045-00-3

o-arsanilic acid

[2-(2-nitro-anilino)-phenyl]-arsonic acid
876497-37-9

[2-(2-nitro-anilino)-phenyl]-arsonic acid

Conditions
ConditionsYield
With i-Amyl alcohol; copper; potassium carbonate at 110℃; Reagens 4: Kupfer(I)-jodid;
N-(2-hydroxyphenyl)-2-chloroacetamide
10147-68-9

N-(2-hydroxyphenyl)-2-chloroacetamide

o-arsanilic acid
2045-00-3

o-arsanilic acid

(2-{[(2-hydroxy-phenylcarbamoyl)-methyl]-amino}-phenyl)-arsonic acid

(2-{[(2-hydroxy-phenylcarbamoyl)-methyl]-amino}-phenyl)-arsonic acid

Conditions
ConditionsYield
With sodium hydroxide
2-bromo-3-nitrotoluene
41085-43-2

2-bromo-3-nitrotoluene

o-arsanilic acid
2045-00-3

o-arsanilic acid

[2-(2-methyl-6-nitro-anilino)-phenyl]-arsonic acid
823810-41-9

[2-(2-methyl-6-nitro-anilino)-phenyl]-arsonic acid

Conditions
ConditionsYield
With i-Amyl alcohol; copper; potassium carbonate
4-bromo-2-nitrotoluene
60956-26-5

4-bromo-2-nitrotoluene

o-arsanilic acid
2045-00-3

o-arsanilic acid

[2-(4-methyl-3-nitro-anilino)-phenyl]-arsonic acid

[2-(4-methyl-3-nitro-anilino)-phenyl]-arsonic acid

Conditions
ConditionsYield
With i-Amyl alcohol; copper; potassium carbonate

2045-00-3Relevant articles and documents

Interaction of phenylarsonic acid derivatives with Group IIA metal ions

Sharma,Sud,Pannu

, p. 169 - 170 (2007/10/03)

The proton-ligand stability constants and stability constants of complexes of Group IIA metal ions with o-amino- and o-hydroxyphenylarsonic acids have been determined potentiometrically at 30° at ionic strengths of 0.05, 0.10, 0.20 M and also at 20° and 40° at an ionic strength of 0.05 M. The stability order for 1:1 complexes is CaII II II. In case of MgII and BeII complexes, precipitation occurred early during titration. The thermodynamic parameters have been evaluated.

Asymmetric dioxazine compounds and method for dyeing or printing fiber materials using the same

-

, (2008/06/13)

An asymmetric dioxazine compound represented by the following formula (I) in the free acid form: STR1 wherein A1 and A2 independently of one another are each sulfo, halo, alkyl or alkoxy, W is an unsubstituted or substituted aliphatic or aromatic bridging group, X1 and X2 independently of one another are each hydrogen, halo, alkyl, alkoxy or phenoxy, R1 and R2 independently of one another are each hydrogen or unsubstituted or substituted alkyl, R3 and R4 independently of one another are each hydrogen, halo, alkyl, alkoxy or unsubstituted or substituted amino, Z is a fiber-reactive group, m and n independently of one another are each 0 or 1, provided that m≠n, and l is 1 or 2. This compound is suitable for dyeing and printing cellulose fiber, natural and synthetic polyamide fibers, polyrethane fiber, leather and the like and mixed yarns thereof, to obtain dyed or printed products of a color fast to light, wetness and chlorine with superior build-up and level dyeing properties.

Bisazo brown reactive dye

-

, (2008/06/13)

A brown reactive dye represented by a free acid of the formula, STR1 wherein R is a hydrogen atom or a C1 to C4 alkyl group, X is --SO2 CH2 CH2 Cl, --SO2 CH=CH2, --SO2 CH2 CH2 OSO3 H or --SO2 CH2 CH2 OPO3 H2, rings A, B and C are each a benzene or naphthalene ring which may have other substituent, m is 0 to 3 and n is 0 to 1. This dye is suitable for dyeing cellulose fibers brown to afford dyeings superior in fastnesses, acid stability, build-up property and level dyeing property.

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