993-13-5Relevant articles and documents
Nichol et al.
, p. 1008,1010 (1967)
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Thompson
, p. 3292 (1952)
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A Peanut-Like Sb-Embedded Polyoxoniobate Cage for Hydrolytic Decomposition of Chemical Warfare Agent
Wu, Yan-Lan,Zhong, Zhuo-Hao,Wu, Ping-Xin,Sun, Yan-Qiong,Li, Xin-Xiong,Zheng, Shou-Tian
, p. 1505 - 1509 (2021)
A Sb-embedded polyoxoniobate has been originally synthesized under hydrothermal conditions. Particularly, the peanut-like [Sb2Nb24O72]18? cluster cage in 1 with C2h symmetry is composed of two 9-nuclear {SbNb9O33} motifs and one {Nb6O24} crown-shaped ring. The compound 1 present the novel structure of Sb-substituted sandwich-type polyoxoniobate with antimoniobate cluster cage. Decomposition catalytic studies indicate that compound 1 exhibits good hydrolytic activity and stability on the degradation of nerve agent simulant dimethylphosphonate (DMMP).
Mass Spectrometric Identification of Methylphosphonic Acid: The Hydrolysis Product of Isopropyl Methylphosphonofluoridate and Pinacolyl Methylphosphonofluoridate
Tripathi, Durgesh N.,Pandey, Karuna S.,Bhattacharya, Arabinda,Vaidyanathaswamy, Ramamoorthy
, p. 823 - 824 (1992)
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Synthesis of the Tripeptides Tyr-Thr-Lys Phosphorylated with Isopropyl Methyl- and (Deuteromethyl)phosphonochloridates as Reference Standards for the Analysis of Biomedical Samples
Rodin,Baygildiev,Krylov,Osipov,Krylov,Yashkir,Rybalchenko
, p. 2103 - 2107 (2019/11/29)
A procedure for the phosphorylation of the tripeptide Tyr-Thr-Lys with isopropyl methyl- or (deuteromethyl)phosphonochloridate is developed. The phosphorylated tripeptides are intended for use as reference standards in the analysis of blood samples of people suspected to have been exposed to acetylcholinesterase inhibitors. Conditions of hromatographic separation and purification of the synthesized compounds are determined and optimized, which ensures the preparation of high-purity phosphorylated tripeptides.
Investigating the breakdown of the nerve agent simulant methyl paraoxon and chemical warfare agents GB and VX using nitrogen containing bases
Wilson, Craig,Cooper, Nicholas J.,Briggs, Michael E.,Cooper, Andrew I.,Adams, Dave J.
supporting information, p. 9285 - 9291 (2019/01/03)
A range of nitrogen containing bases was tested for the hydrolysis of a nerve agent simulant, methyl paraoxon (MP), and the chemical warfare agents, GB and VX. The product distribution was found to be highly dependant on the basicity of the base and the quantity of water used for the hydrolysis. This study is important in the design of decontamination technology, which often involve mimics of CWAs.