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10026-11-6

10026-11-6

Identification

Synonyms:Zirconiumchloride (ZrCl4) (8CI);Orgatix ZB 126;Tetrachlorozirconium;Zirconiumchloride;Zirconium chloride (Zr2Cl8);Zirconium tetrachloride;Zirconium(IV)chloride;

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Safety information and MSDS view more

  • Pictogram(s):CorrosiveC

  • Hazard Codes: C:Corrosive;

  • Signal Word:Danger

  • Hazard Statement:H290 May be corrosive to metalsH314 Causes severe skin burns and eye damage

  • First-aid measures: General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

  • Fire-fighting measures: Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.

  • Accidental release measures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

  • Handling and storage: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

  • Exposure controls/personal protection:Occupational Exposure limit valuesBiological limit values Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/face protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protection Wear dust mask when handling large quantities. Thermal hazards

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Relevant articles and documentsAll total 20 Articles be found

Synthesis of BaZrS3 in the presence of excess sulfur

Wang, Yarong,Sato, Nobuaki,Yamada, Kohta,Fujino, Takeo

, p. 214 - 223 (2000)

Synthetic reaction of barium zirconium sulfide, BaZrS3, was studied in a large excess amount of sulfur melt at temperatures of 623-723 K and in the presence of a small amount of excess sulfur at temperatures of 623-823 K, respectively. The results showed that BaZrS3 was formed with high yields by heating at temperatures ranging from 723 to 873 K, if a proper amount of excess sulfur and 10 mole% of BaCl2 were added in the starting materials. The compound could be obtained in almost a single phase with only 2-3 mole% ZrO2 impurity after the 8 min water treatment of the products obtained at 873 K. The modified method studied in this paper, i.e. reaction in the medium temperature range of 723-873 K, was shown to be applicable for synthesizing the mixed sulfides of some kinds including BaZrS3.

Zirconium tetrachloride revisited

Borjas Nevarez, Rosendo,Balasekaran, Samundeeswari Mariappan,Kim, Eunja,Weck, Philippe,Poineau, Frederic

, p. 307 - 311 (2018)

Zirconium tetrachloride, ZrCl 4, is a strategic material with wide-ranging applications. Until now, only one crystallographic study on ZrCl 4 has been reported [Krebs (1970). Z. Anorg. Allg. Chem. 378, 263-272] and that was more than 40 years ago. The compound used for the previous determination was prepared from ZrO 2 and Cl 2 -CCl 4, and single-crystal X-ray diffraction (SCXRD) studies on ZrCl 4 obtained from Zr metal have not yet been reported. In this context, we prepared ZrCl 4 from the reaction of Zr metal and Cl 2 gas in a sealed tube and investigated its structure at 100, 150, 200, 250, and 300 K. At 300 K, the SCXRD analysis indicates that ZrCl 4 crystallizes in the orthorhombic space group Pca2 1 [a = 6.262 (9), b = 7.402 (11), c = 12.039 (17) ?, and V = 558.0 (14) ? 3 ] and consists of infinite zigzag chains of edge-sharing ZrCl 6 octahedra. This chain motif is similar to that observed previously in ZrCl 4, but the structural parameters and space group differ. In the temperature range 100-300 K, no phase transformation was identified, while elongation of intra-chain Zr?Zr [3.950 (1) ? at 100 K and 3.968 (5) ? at 300 K] and inter-chain Cl?Cl [3.630 (3) ? at 100 K and 3.687 (9) ? at 300 K] distances occurred.

Ziebarth, Robin P.,Corbett, John D.

, p. 56 - 67 (1989)

Lister, M. W.,Sutton, L. E.

, p. 393 - 406 (1941)

Venable, F. P.

, p. 469 - 475 (1894)

Chemical vapor transport of layer structured crystal β-ZrNCl

Ohashi, M.,Yamanaka, S.,Hattori, M.

, p. 342 - 347 (1988)

A layer structured compounds β-ZrNCl is transported to a higher temperature zone with the aid of ammonium chloride as the transporting agent in the temperature range of 823-1173 K. The transport mechanism can be explained by the formation of a volatile compound (NH4)2ZrCl6. The measurements of the vapor pressure and the mass spectrum revealed that (NH4)2ZrCl6 decomposed congruently according to the equation presented. The enthalpy change for the decomposition was determined to be 533 kJ/mol. By combining the above two equations, a simplified transport equation is derived.

Razuvaev, G. A.,Vyshinskaya, L. I.,Vasil'eva, G. A.,Malysheva, A. V.,Mar'in, V. P.

, p. L285 - L288 (1980)

Thermodynamic properties of zirconium chlorides. I. The standard molar enthalpy of formation, the low-temperature heat capacity, the standard molar entropy, and the standard molar Gibbs energy of formation of zirconium trichloride

Efimov, M. E.,Prokopenko, I. V.,Tsirelnikov, V. I.,Troyanov, S. I.,Medvedev, V. A.,et al.

, p. 353 - 358 (1987)

The enthalpies of the reaaction of ZrCl3(cr) and of ZrCl4(cr) with 3 mol * dm-3 HCl solution were measured in a 0.1 dm3 reaction vessel of the isoperibol calorimeter LKB-8700.The enthalpy change of the resulting reaction: ZrCl3(cr) + HCl(sln, 17.06H2O) = ZrCl4(cr) + 0.5H2(g), was found to be ΔrHm0(298.15 K) = -(62.6+/-2.7) kJ * mol-1 which leads to ΔfHm0(ZrCl3, cr, 298.15 K) = -(753.9+/-3.0) kJ * mol-1.Heat-capacity measurements between 7 and 312 K were performed on a pure sample of ZrCl3(cr).The following standard molar thermodynamic quantities are reported at T0 = 298.15 K: the heat capacity: Cp,m0(T0) = (92.871+/-0.089) J * K-1 * mol-1; the entropy: Sm0(T0) = (137.50+/-0.28) J * K-1 * mol-1; the enthalpy increment: m0(T0)-Hm0(0)> = (19239+/-29) J * mol-1; and the Gibbs energy of formation: ΔfGm0(T0) = -(685.0+/-1.5) kJ * mol-1.

Titanium, zirconium, and hafnium metal atom reactions with CF4, CCl4, and CF2Cl2: A matrix isolation spectroscopic and DFT investigation of triplet XC÷MX3 complexes

Lyon, Jonathan T.,Andrews, Lester

, p. 2519 - 2527 (2008/10/09)

Laser-ablated group 4 transition metal atoms react with CF4 to form triplet state electron-deficient FC÷MFa methylidyne complexes, which are identified by their infrared spectra and comparison to density functional vibrational frequency calculations of stable possible products. Of particular interest in these complexes are the strong C-X bonds and carbon-metal n bonding. The two unpaired electrons on carbon are drawn to the electron-deficient transition metal center, forming a partially filled triple bond, which is approximately equal in length to a classical C=M double bond. Reactions with carbon tetrachloride form the analogous ClC÷MCl3 complexes, whereas reactions with CF2Cl2 form a mixture of FC÷MFCl2 and ClC÷MF2Cl species. The FC÷MFCl2 complexes involving more α-Cl transfer are favored in the reaction of excited metal atoms during sample deposition, but UV irradiation photoisomerizes FC÷MFCl2 to the lower energy ClC÷MF2Cl complexes with more α-F transfer to the metal center.

Process route upstream and downstream products

Process route

dimethylsilyl-bis-(4,5,6,7,8,9,10,11,12,13-decahydrocyclo pentacyclododecen-2-yl)zirconiumdichloride

dimethylsilyl-bis-(4,5,6,7,8,9,10,11,12,13-decahydrocyclo pentacyclododecen-2-yl)zirconiumdichloride

zirconium(IV) chloride
10026-11-6

zirconium(IV) chloride

Conditions
Conditions Yield
23%
23%
zirconium(IV) chloride
10026-11-6

zirconium(IV) chloride

Conditions
Conditions Yield
tetrachloro-2,2'-bipyridylzirconium
17099-99-9

tetrachloro-2,2'-bipyridylzirconium

[2,2]bipyridinyl
366-18-7

[2,2]bipyridinyl

zirconium(IV) chloride
10026-11-6

zirconium(IV) chloride

Conditions
Conditions Yield
In neat (no solvent); heating under N2 above 400 °C;
zirconium
7440-67-7

zirconium

chlorine
7782-50-5

chlorine

zirconium(IV) chloride
10026-11-6

zirconium(IV) chloride

Conditions
Conditions Yield
With char coal; In neat (no solvent); briquetting with a tenfold excess of char coal; heating the dry briquets at 600-650°C in stream of dry Cl2;; condensation of ZrCl4 in spherical condenser;;
chlorinating metallic Zr with dry chlorine at 453-693 K;; sublimation in a stream of dry hydrogen; elem. anal.;;
With pyrographite; In neat (no solvent); calcinating of a mixture of Zr and C under Cl2;;
In neat (no solvent); at 200 - 400°C;;
In neat (no solvent); byproducts: FeCl3; heating pure Zr powder in dry stream of Cl2 (free of O2) in apparatus filled with Cl2 gas (free of air);; separation from FeCl3 by fractionated destillation;;
In neat (no solvent); byproducts: ZrOCl2; heating pure Zr powder in dry stream of Cl2 (free of O2) in apparatus filled with Cl2 gas (free of air);; sublimation;;
In neat (no solvent); chlorination of metallic Zr between 653 and 693 K; sublimed (dry H2; then in vac.); elem. anal.;
In neat (no solvent); combustion of Zr powder with Cl2 on slight warming;;
In neat (no solvent); heating 2 hours in stream of Cl2 (free of O2); addn. of coal to residue of ZrO2, further chlorination for 4 hours;; sublimation;;
In neat (no solvent); heating Zr (containg Ti and Si) in dry stream of Cl2;; sublimation of ZrCl4, residue of impurities;;
In neat (no solvent); moderate heating of Zr in a stream of Cl2;;
In not given; reactive Zr (from reduced ore or residues) fine distributed;;
In neat (no solvent); byproducts: FeCl3; heating pure Zr powder in dry stream of Cl2 (free of O2) in apparatus filled with Cl2 gas (free of air);; separation from FeCl3 by fractionated destillation;;
In neat (no solvent); heating 2 hours in stream of Cl2 (free of O2); addn. of coal to residue of ZrO2, further chlorination for 4 hours;; sublimation;;
In neat (no solvent); at 200 - 400°C;;
With C; In neat (no solvent); calcinating of a mixture of Zr and C under Cl2;;
In neat (no solvent); byproducts: ZrOCl2; heating pure Zr powder in dry stream of Cl2 (free of O2) in apparatus filled with Cl2 gas (free of air);; sublimation;;
In neat (no solvent); heating of Zr in Cl2 flow (650-690 K); sublimation (H2 flow); elem. anal.;
In neat (no solvent); react. of Zr sponge with Cl2 at 330°C; purifn. by fractional distn.; elem. anal.;
673 K;
zirconium; chlorine; at 299.84 ℃; for 6h; Schlenk technique; Inert atmosphere; Sealed tube;
at 154.84 ℃; for 96h; Inert atmosphere; Schlenk technique; Sealed tube;
thionyl chloride
7719-09-7

thionyl chloride

zirconium(IV) oxide
7440-67-7

zirconium(IV) oxide

zirconium(IV) chloride
10026-11-6

zirconium(IV) chloride

Conditions
Conditions Yield
In neat (no solvent); heating of calcinated ZrO2 at 200-250°C with 5-6fold amount of SOCl2;;
In neat (no solvent); heating at 400°C;;
>99
In neat (no solvent); heating below 400°C and then increasing temp.;;
In neat (no solvent); heating in a tube below 400°C with 5-6 fold amount of SOCl2, then increasing temperature; removal of SOCl2 from ZrCl4*SOCl2 on heating;; sublimation in a stream of H2 to remove Fe impurities;;
In neat (no solvent); heating at 400°C;;
>99
In neat (no solvent); heating of calcinated ZrO2 at 200-250°C with 5-6fold amount of SOCl2;;
In neat (no solvent, gas phase); thermal-sublimation column, Ar as carrier gas for SOCl2, heating (850°C, 20 min); drying the products over P2O5, elem. anal., product ratio depending on deposition temp.;
phosgene
75-44-5

phosgene

zirconium silicate

zirconium silicate

zirconium(IV) chloride
10026-11-6

zirconium(IV) chloride

Conditions
Conditions Yield
In neat (no solvent); byproducts: SiO2; reaction at 1300°C;;
phosgene
75-44-5

phosgene

baddeleyite

baddeleyite

zirconium(IV) chloride
10026-11-6

zirconium(IV) chloride

Conditions
Conditions Yield
In neat (no solvent); heating baddeleyite in a rotary furnace to 500-600°C, countercurrent of COCl2;; extraction by heating with lime;;
phosgene
75-44-5

phosgene

zirconium(IV) oxide
7440-67-7

zirconium(IV) oxide

zirconium(IV) chloride
10026-11-6

zirconium(IV) chloride

Conditions
Conditions Yield
In neat (no solvent); heating;;
In neat (no solvent); heating at 400°C in a very slow stream of COCl2;;
In neat (no solvent); heating at 600-700°C;; sublimation in a stream of N2;;
In neat (no solvent); passing stream of COCl2 over ZrO2 at 650 °C;;
In neat (no solvent); heating at 400°C in a very slow stream of COCl2;;
In neat (no solvent); heating;;
boron trichloride
10294-34-5

boron trichloride

zirconium(IV) oxide
7440-67-7

zirconium(IV) oxide

zirconium(IV) chloride
10026-11-6

zirconium(IV) chloride

Conditions
Conditions Yield
In neat (no solvent); byproducts: H3BO3; on heating;;
In neat (no solvent); heating 2 hours in vac. at 200°C; back reaction at higher temperatures;;
In neat (no solvent); heating in an evacuated tube at 200°C;;
In neat (no solvent); heating 2 hours in vac. at 200°C; back reaction at higher temperatures;;
zirconium(IV) sulfate

zirconium(IV) sulfate

barium(II) chloride

barium(II) chloride

zirconium(IV) chloride
10026-11-6

zirconium(IV) chloride

Conditions
Conditions Yield
In neat (no solvent); heating at 300°C;;

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