
Tetrahedron p. 15711 - 15716 (1997)
Update date:2022-08-04
Topics:
Rezgui
El Gaied
Regiospecific replacement of acetoxy group in 2-(acetoxymethyl)-2-cyclohexenone 1 by stabilizedd carbanions, leads to S(N) 2-type products 2a-g, 5 and 6. Bicyclic dienones 4 are prepared in 'one pot' from the reaction of 2 with K2CO3 in refluxing absolute ethanol.
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