Monomeric base-stabilized phosphino- and arsinoalanes

DOI: 10.1021/om00025a008

Source and publish data:

Organometallics p. 17 - 18 (1993)

Update date:2022-08-04

Topics:

Authors:

Atwood, David A.

Contreras, Leopoldo

Cowley, Alan H.

Jones, Richard A.

Mardones, Miguel A.

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Article abstract of DOI:10.1021/om00025a008

The first base-stabilized phosphino- and arsinoalane monomers, H₂AlEMes₂·NMe₃(Mes = mesityl; 1, E = P; 2, E = As) have been prepared. Thermolysis at 95°C converts 1 to the trimer [H₂AlPMes₂]₃ (3); further heating at 125°C results in the formation of Mes₂PH and aluminum metal.

Full text of DOI:10.1021/om00025a008

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