874-42-0Relevant articles and documents
MoO: x-pyridine organic-inorganic hybrid wires as a reusable and highly selective catalyst for the oxidation of alcohols: a comparison study between reaction-controlled phase-transfer catalysis and heterogeneous catalysis
Malakooti,Feghhi
, p. 3405 - 3413 (2017)
The different catalytic behaviors of Mo3O10(C5H6N)2·H2O wires (MoOx-pyridine) in the selective oxidation of alcohols by means of molecular oxygen (O2) and hydrogen per
New Stable Catalytic Electrodes Functionalized with TEMPO for the Waste-Free Oxidation of Alcohol
Karimi, Babak,Ghahremani, Mina,Ciriminna, Rosaria,Pagliaro, Mario
, p. 1298 - 1305 (2018)
We report the first catalytically active and stable sol-gel electrode functionalized with the TEMPO moiety for the highly selective oxidation of alcohols with an electric current only. The method shows broad applicability to different substrates, opening
New method for promoting photosensitive oxidation to remove 1, 2-mercaptoethanol acetal protecting group by utilizing visible light irradiation
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Paragraph 0014-0016, (2021/01/30)
The invention discloses a new method for removing a 1, 2-mercaptoethanol acetal protecting group, and belongs to the field of organic synthetic chemistry. The method comprises the following steps of:under a room-temperature open system, adding a substrate 2-substituted-1, 3-oxo-thio-cyclopentane and a catalytic amount of a photosensitizer Eosin Y into a proper amount of acetonitrile; and performing irradiating with a blue LED lamp for 3 hours while stirring to obtain the corresponding aldehyde compound with favorable yield. The method has the advantages of mild operation conditions, greenness, environmental protection, no harsh water and oxygen removal operation and device, realization of the reaction at room temperature, high substrate conversion rate, simple and easy post-treatment, andprovides a good method for removing the 1, 2-mercaptoethanol acetal protecting group at present.
Novel oxovanadium and dioxomolybdenum complexes of tridentate ONO-donor Schiff base ligand: Synthesis, characterization, crystal structures, Hirshfeld surface analysis, DFT computational studies and catalytic activity for the selective oxidation of benzyl
Amiri Rudbari, Hadi,Ashfaq, Muhammad,Behjatmanesh-Ardakani, Reza,Fallah-Mehrjardi, Mehdi,Forootan, Pooran,Kargar, Hadi,Nawaz Tahir, Muhammad,Shahzad Munawar, Khurram
, (2021/06/15)
Two new oxovanadium and dioxomolybdenum Schiff base complexes, [VvO(L)(OCH3)(CH3OH)] and [MoVIO2(L)(CH2CH3OH)], were synthesized by treating an ONO-donor type Schiff base ligand