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High quality Isobutylacetate supplier in China
Cas No: 110-19-0
No Data No Data Metric Ton/Day Simagchem Corporation Contact Supplier
Isobutyl acetate
Cas No: 110-19-0
USD $ 12.0-12.0 / Kilogram 1 Kilogram 1000 Metric Ton/Year Jinan Finer Chemical Co., Ltd Contact Supplier
Isobutyl Acetate CAS NO.110-19-0
Cas No: 110-19-0
USD $ 1.0-3.0 / Kilogram 1 Kilogram 10 Kilogram/Day Hebei yanxi chemical co.,LTD. Contact Supplier
Isobutyl acetate
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No Data 25 Kilogram 5000 Metric Ton/Month Hefei TNJ chemical industry co.,ltd Contact Supplier
Isobutyl acetate
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No Data 1 Kilogram 1 Metric Ton/Month Henan Allgreen Chemical Co.,Ltd Contact Supplier
Factory Supply Isobutylacetate
Cas No: 110-19-0
No Data 1 1 Ality Chemical Corporation Contact Supplier
Isobutyl acetate, iso-Butyl acetate, Natural isobutyl acetate
Cas No: 110-19-0
No Data 1 Metric Ton Metric Ton/Day Nanjing Yuance Industry&Trade Co., Ltd. Contact Supplier
Amadis Chemical offer CAS#110-19-0;CAT#A802160
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No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
Isobutyl acetate
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Isobutyl acetate
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110-19-0 Usage

Production Methods

Isobutyl acetate may be made from methyl isobutyl ketone. It may also be made by treating isobutanol with acetic acid in the presence of catalysts. The Tischenko reaction of acetaldehyde with isobutyraldehyde yields a mixture of isobutyl acetate with ethyl acetate and isobutyl isobutyrate.

Occurrence

Reported found in, apple, apricot, banana, currants, guava, grapes, melon, pear, blackcurrant, papaya, pineapple, strawberry, vinegar, wheat bread, Parmesan and Gruyere cheese, beef fat, beer, cognac, rum, cider, whiskies, sherry, grape wines, port, olive, cocoa, passion fruit, plum, starfruit, bantu beer, plum and grape brandy, mango, tamarind, apple brandy, figs, plum wine, litchi, sake, nectarine, naranjilla fruit, Cape gooseberry and Roman chamomile oil.

Production method

It can be obtained via the esterfication between iso-butanol and acetic anhydride in the presence of sulfuric acid. Mix the acetic anhydride and iso-butanol solution followed by adding drop wise of sulfuric acid. Heat for reflux of 5-6 h after a bit cooling, wash the refluxed liquid with water for 2-3 times. Use sodium carbonate for neutralizing with sodium carbonate, wash with water until neutralized, dry over calcium chloride with vacuum distillation in oil bath to derive the finished products.

Chemical Properties

It is a water-white liquid with soft fruit ester flavor. It is miscible with a variety of organic solvents such as alcohols, ethers and hydrocarbons.

Uses

Solvent; flavoring

Health Hazard

Isobutyl acetate is more toxic but less of anirritant than n-butyl acetate. The toxic symp toms include headache, drowsiness, irritationof upper respiratory tract, and anesthesia.A 4-hour exposure to 8000 ppm was lethalto rats. It produced mild to moderate irri tation on rabbits’ skin. The irritation ineyes was also mild to moderate. The LD50oral value in rabbit is within the range4800 mg/kg.

Chemical Properties

Isobutyl acetate, also known as 2-methylpropyl ethanoate (IUPAC name) or β-methylpropyl acetate, is a common solvent. It is produced from the esterifi cation of isobutanol with acetic acid. It is used as a solvent for lacquer and nitrocellulose. Like many esters, it has a fruity or fl oral smell at low concentrations and occurs naturally in raspberries, pears, and other plants. At higher concentrations, the odor can be unpleasant and may cause symptoms of CNS depression, such as nausea, dizziness, and headache

Physical properties

Colorless liquid with a fruity odor. Experimentally determined detection and recognition odor threshold concentrations were 1.7 mg/m3 (360 ppbv) and 2.4 mg/m3 (510 ppbv), respectively (Hellman and Small, 1974).

Chemical Properties

Butyl acetates are colorless or yellowish liquids with pleasant, fruity odors. There are 4 isomers.

Limited use

FEMA (mg/kg): soft drinks: 11; cold drink: 16; Confectionery: 36; Bakery: 35; pudding class: 170; gum: 860; coating: 5.5. Take appropriate amount as limit (FDA§172.515,2000).

Environmental fate

Chemical/Physical. Slowly hydrolyzes in water forming 2-methylpropanol and acetic acid. At an influent concentration of 1,000 mg/L, treatment with GAC resulted in an effluent concentration of 180 mg/L. The adsorbability of the carbon used was 164 mg/g carbon (Guisti et al., 1974).

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Uses

Isobutyl acetate is used as a solvent and as aflavoring agent.

Chemical Reactivity

Reactivity with Water No reaction; Reactivity with Common Materials: Softens and dissolves many types of plastics; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

Shipping

UN1123 Butyl acetates, Hazard Class: 3; Labels: 3—Flammable liquid.

Description

Isobutyl acetate has a fruity (currant-pear), floral (hyacinth-rose) odor and a characteristic ether-like, slightly bitter flavor. May be prepared by direct esterification of isobutyl alcohol with acetic acid.

General Description

A clear colorless liquid with a fruity odor. Flash point 64°F. Less dense than water (6.2 lb / gal) and insoluble in water. Vapors are heavier than air .

Taste threshold values

Taste characteristics at 30 ppm: sweet fruity with a banana tutti-frutti note.

Uses

Isobutyl Acetate can be used as organic solvent, the solvent of nitrocellulose and lacquer, extraction agent, dehydrating agents. It can also be applied to collodion, nitrocellulose, varnishes, leather, pharmaceuticals, plastics and perfume industry.

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

Content Analysis

It can be determined according to the method 1 in ester assay (OT-18). The amount of the sample for taking is 1g. The equivalency factor (e) for the calculation can be taken as 58.08. Alternatively, people can apply non-polar column method via gas chromatography (GT-10-4) for the determination. The above information is edited by the chemicalbook of Dai Xiongfeng.

Incompatibilities

All butyl acetates are incompatible with nitrates, strong oxidizers; strong alkalies; strong acids. Butyl acetates may form explosive mixture with air; reacts with water, on standing, to form acetic acid and n-butyl alcohol. Violent reaction with strong oxidizers and potassium-tert-butoxide. Dissolves rubber, many plastics, resins and some coatings. May accumulate static electrical charges, and may cause ignition of its vapors

Toxicity

LD50: 13400 mg/kg (rat, oral). GRAS (FEMA).

description

Isobutyl acetate, also known as n-propyl acetate, is the esterfication product between acetic acid and 2-butanol. It is a water-white liquid with flavor of soft fruit ester. It is slightly soluble in water, miscible with ethanol, ethyl ether as well as many other kinds of organic solvent including alcohol, ether and hydrocarbon. It can be mainly used as the diluent of nitro-lacquer and perchlorethylene paint and the solvents of nitrocellulose and lacquer as well as the substitution solvent of butyl acetate and methyl isobutyl ketone. It can also be used as a component of the flavoring agent. It can also be used as the diluent of plastic printing paste and the extraction agent in the pharmaceutical industry. Sec-butyl acetate has excellent capability of dissolving many substances. It can be industrially applied as the solvent for manufacturing of nitrocellulose paint, acrylic paint, polyurethane paint, etc., these paints can also be used as an aircraft wing paint, artificial leather coatings and automotive coatings. Its dissolving capability is similar as n-butyl acetate and isobutyl acetate. In the coating formulation, it can be widely adopted for substitution of n-butyl acetate and isobutyl acetate. In metallic paints, people can apply butyl acetate to dissolve the cellulose acetate butyrate to obtain 15% to 20% solution. The above information is edited by the chemicalbook of Dai Xiongfeng.

Potential Exposure

n-Butyl acetate is an important solvent in the production of lacquers, leather and airplane dopes, and perfumes. It is used as a solvent and gasoline additive. sec-Butyl acetate is used as a widely used solvent for nitrocellulose, nail enamels and many different purposes. tert-Butyl acetate is common industrial solvent used in the making of lacquers, artificial leather, airplane dope, perfume; and as a food additive. Isobutyl acetate is used as a solvent and in perfumes and artificial flavoring materials

Chemical Properties

Isobutyl acetate is a colorless liquid with a fruit flavor. Isobutyl acetate is moisture sensitive, incompatible with ignition sources, moisture, excess heat, strong oxidizing agents, and strong bases; on decomposition, it releases carbon monoxide and carbon dioxide. It is used for nitrification fiber and paint solvents, chemical reagents, and modulation spices

Air & Water Reactions

Highly flammable. Insoluble in water.

Preparation

By direct esterification of isobutyl alcohol with acetic acid.

Aroma threshold values

Detection: 65 to 880 ppb

Uses

Isobutyl Acetate is a flavoring agent that is a clear colorless liquid with a fruity odor resembling banana when diluted. it is soluble in alcohol, propylene glycol, most fixed oils, and mineral oil, and slightly soluble in water. it is obtained by synthesis.

Reactivity Profile

Isobutyl acetate reacts exothermically with acids to give alcohols and other acids. May react sufficiently exothermically with strong oxidizing acids to ignite the reaction products. Reactions with bases also generate heat. Combination with strong reducing agents (alkali metals and hydrides) generates flammable hydrogen.

Definition

ChEBI: The acetate ester of isobutanol.

Health Hazard

Vapors may irritate upper respiratory tract and cause nausea, vomiting, dizziness and loss of consciousness. Liquid irritates eyes and may irritate skin.

Source

A product of whiskey fermentation (quoted, Verschueren, 1983). Isobutyl acetate was identified as a volatile constituent released by fresh coffee beans (Coffea canephora variety Robusta) at different stages of ripeness (Mathieu et al., 1998).

Hazard

Flammable, dangerous fire risk.
InChI:InChI=1/C6H12O2/c1-5(2)4-8-6(3)7/h5H,4H2,1-3H3

110-19-0 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Alfa Aesar (A14892)  Isobutyl acetate, 98%    110-19-0 250ml 161.0CNY Detail
Alfa Aesar (A14892)  Isobutyl acetate, 98%    110-19-0 500ml 179.0CNY Detail
Alfa Aesar (A14892)  Isobutyl acetate, 98%    110-19-0 2500ml 649.0CNY Detail
USP (1347802)  Isobutylacetate  United States Pharmacopeia (USP) Reference Standard 110-19-0 1347802-3X1.2ML 4,662.45CNY Detail
Sigma-Aldrich (94823)  Isobutylacetate  analytical standard 110-19-0 94823-1ML-F 415.35CNY Detail
Sigma-Aldrich (94823)  Isobutylacetate  analytical standard 110-19-0 94823-5ML-F 1,375.92CNY Detail

110-19-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name isobutyl acetate

1.2 Other means of identification

Product number -
Other names Isobutyl Acetate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Fragrances
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:110-19-0 SDS

110-19-0Synthetic route

Reaxys ID: 11464140

Reaxys ID: 11464140

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

Conditions
ConditionsYield
With hydrogen at 40℃; under 7500.75 Torr;99%
With hydrogen at 40℃; under 7500.75 Torr;96.9%
vinyl acetate
108-05-4

vinyl acetate

2-methyl-propan-1-ol
78-83-1

2-methyl-propan-1-ol

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

Conditions
ConditionsYield
With pseudomonas fuorescens lipase immobilized on multiwall carbon nano-tubes at 50℃; for 4.5h; Green chemistry;99%
With Mycobacterium smegmatis acyl transferase In aq. phosphate buffer pH=7.5; Enzymatic reaction;
With acyltransferase from Mycobacterium smegmatis In aq. phosphate buffer pH=7.5; Enzymatic reaction;
Reaxys ID: 11465423

Reaxys ID: 11465423

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

Conditions
ConditionsYield
ruthenium on γ-alumina at 95.5℃;98.6%
2-methyl-propan-1-ol
78-83-1

2-methyl-propan-1-ol

acetic acid
64-19-7

acetic acid

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

Conditions
ConditionsYield
copper methanesulfonate In cyclohexane at 85 - 90℃; for 2.5h;95%
With sodium hydrogen sulfate for 1h; Esterification; Heating;92.5%
With 1-butyl-2-methylbenzimidazolium tetrafluoroborate at 120℃; for 2h;89%
2-methyl-propan-1-ol
78-83-1

2-methyl-propan-1-ol

(S)-N-acetylphenylalanine
3618-96-0

(S)-N-acetylphenylalanine

A

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

B

methyl (2S)-2-amino-3-phenylpropanoate hydrochloride
7524-50-7

methyl (2S)-2-amino-3-phenylpropanoate hydrochloride

Conditions
ConditionsYield
Stage #1: (S)-N-acetylphenylalanine With triphenyl phosphite; chlorine; triethylamine In tetrahydrofuran at -30℃;
Stage #2: 2-methyl-propan-1-ol In tetrahydrofuran at -30 - 20℃;
Stage #3: With water
A n/a
B 95%
2-methyl-propan-1-ol
78-83-1

2-methyl-propan-1-ol

acetic anhydride
108-24-7

acetic anhydride

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

Conditions
ConditionsYield
With N-methylmorpholinium propanesulfonic acid ammonium hydrogensulfate at 25℃; for 0.0833333h; Inert atmosphere; neat (no solvent); chemoselective reaction;94%
ruthenium trichloride In acetonitrile at 20℃; for 0.416667h;91%
With cadmium(II) oxide at 80℃; for 0.333333h; Neat (no solvent); Microwave irradiation;85%
Allyl acetate
591-87-7

Allyl acetate

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

Conditions
ConditionsYield
ruthenium on γ-alumina at 102℃;93%
2-methyl-propan-1-ol
78-83-1

2-methyl-propan-1-ol

benzylidene 1,1-diacetate
581-55-5

benzylidene 1,1-diacetate

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

Conditions
ConditionsYield
With C. antarctica B immobilized lipase In toluene at 60℃; for 7h; Enzymatic reaction;87%
benzyl iso-butyl ether
940-49-8

benzyl iso-butyl ether

acetyl chloride
75-36-5

acetyl chloride

A

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

B

benzyl chloride
100-44-7

benzyl chloride

C

dimethylglyoxal
431-03-8

dimethylglyoxal

Conditions
ConditionsYield
CoCl2 In acetonitrile Ambient temperature; Yields of byproduct given;A 85%
B 15%
C n/a
isobutyl vinyl ether
109-53-5

isobutyl vinyl ether

acetyl chloride
75-36-5

acetyl chloride

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

Conditions
ConditionsYield
CoCl2 In acetonitrile Ambient temperature;77%
cobalt(II) chloride In acetonitrile at 0℃; for 1h;77%
2-methyl-propan-1-ol
78-83-1

2-methyl-propan-1-ol

acetyl chloride
75-36-5

acetyl chloride

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

Conditions
ConditionsYield
With potassium hydroxide; sodium hydroxide; tetrabutyl-ammonium chloride at 0℃; for 0.125h;72%
With zinc(II) chloride at 30℃; for 1.08333h; Neat (no solvent);63%
With diethyl ether
With coal fly ash supported phosphomolybdic acid at 110℃; Temperature; Microwave irradiation; Green chemistry;
acetamide
60-35-5

acetamide

2-methyl-propan-1-ol
78-83-1

2-methyl-propan-1-ol

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

Conditions
ConditionsYield
With silicon tetrafluoride
Ketene
463-51-4

Ketene

2-methyl-propan-1-ol
78-83-1

2-methyl-propan-1-ol

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

Conditions
ConditionsYield
With sulfuric acid
With boron trifluoride
tetrachloromethane
56-23-5

tetrachloromethane

N-isobutyl-N-nitroso-acetamide
15289-94-8

N-isobutyl-N-nitroso-acetamide

A

acetic acid tert-butyl ester
540-88-5

acetic acid tert-butyl ester

B

sec-Butyl acetate
105-46-4

sec-Butyl acetate

C

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

Conditions
ConditionsYield
at 77℃;
2-methyl-propan-1-ol
78-83-1

2-methyl-propan-1-ol

sodium acetate
127-09-3

sodium acetate

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

Conditions
ConditionsYield
With sulfuric acid
α-isobutyloxy-isobutyraldehyde isobutyl semiacetal

α-isobutyloxy-isobutyraldehyde isobutyl semiacetal

A

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

B

2-hydroxy-2-methylpropanal
20818-81-9

2-hydroxy-2-methylpropanal

Conditions
ConditionsYield
With acetic acid
acetaldehyde
75-07-0

acetaldehyde

isobutyraldehyde
78-84-2

isobutyraldehyde

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

Conditions
ConditionsYield
With aluminum ethoxide
isobutyl formate
542-55-2

isobutyl formate

acetic acid
64-19-7

acetic acid

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

Conditions
ConditionsYield
With sulfuric acid; benzene at 77℃; unter Abdestillieren des Azeotrops Ameisensaeure-Benzol;
α-isobutyloxy-isobutyraldehyde isobutyl semiacetal

α-isobutyloxy-isobutyraldehyde isobutyl semiacetal

acetic acid
64-19-7

acetic acid

A

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

B

2-hydroxy-2-methylpropanal
20818-81-9

2-hydroxy-2-methylpropanal

ethyl isobutyl ether
627-02-1

ethyl isobutyl ether

acetyl chloride
75-36-5

acetyl chloride

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

Conditions
ConditionsYield
With zinc(II) chloride at 25℃;
4-methyl-2-pentanone
108-10-1

4-methyl-2-pentanone

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

Conditions
ConditionsYield
With disodium hydrogenphosphate; dichloromethane; trifluoroacetyl peroxide
With Sn-palygorskite; dihydrogen peroxide In 1,4-dioxane at 90℃; for 24h; Baeyer-Villiger oxidation;
With dihydrogen peroxide; tin; magnesium silicate aluminate In 1,4-dioxane at 90℃; for 24h; Bayer-Villiger oxidation;
deuteroacetic acid
758-12-3

deuteroacetic acid

C31H30N(1+)*BF4(1-)
90886-05-8

C31H30N(1+)*BF4(1-)

A

acetic acid tert-butyl ester
540-88-5

acetic acid tert-butyl ester

B

sec-Butyl acetate
105-46-4

sec-Butyl acetate

C

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

D

isobutene
115-11-7

isobutene

Conditions
ConditionsYield
at 150℃; Yield given. Further byproducts given. Yields of byproduct given;
tetradeuterioacetic acid
1186-52-3

tetradeuterioacetic acid

C31H30N(1+)*BF4(1-)
90886-05-8

C31H30N(1+)*BF4(1-)

A

acetic acid tert-butyl ester
540-88-5

acetic acid tert-butyl ester

B

sec-Butyl acetate
105-46-4

sec-Butyl acetate

C

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

D

isobutene
115-11-7

isobutene

Conditions
ConditionsYield
at 150℃; Yield given. Further byproducts given. Yields of byproduct given;
acetic acid
64-19-7

acetic acid

C31H30N(1+)*BF4(1-)
90886-05-8

C31H30N(1+)*BF4(1-)

A

2,4,4-trimethyl-1-pentene
107-39-1

2,4,4-trimethyl-1-pentene

B

acetic acid tert-butyl ester
540-88-5

acetic acid tert-butyl ester

C

sec-Butyl acetate
105-46-4

sec-Butyl acetate

D

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

E

isobutene
115-11-7

isobutene

Conditions
ConditionsYield
at 150℃; Rate constant; Thermodynamic data; ΔH(excit.), ΔS(excit.);
acetic acid
64-19-7

acetic acid

C31H30N(1+)*BF4(1-)
90886-05-8

C31H30N(1+)*BF4(1-)

A

acetic acid tert-butyl ester
540-88-5

acetic acid tert-butyl ester

B

sec-Butyl acetate
105-46-4

sec-Butyl acetate

C

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

D

isobutene
115-11-7

isobutene

Conditions
ConditionsYield
at 150℃; Yield given. Further byproducts given. Yields of byproduct given;
2-methyl-propan-1-ol
78-83-1

2-methyl-propan-1-ol

ethyl acetate
141-78-6

ethyl acetate

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

Conditions
ConditionsYield
K2CO3 + 5percent Carbowax 6000 at 170℃;46 % Chromat.
With Mycobacterium smegmatis acyl transferase In aq. phosphate buffer at 21℃; for 0.5h; pH=7.5; Inert atmosphere; Enzymatic reaction;
1,1-bis(isobutyloxy)-ethane
5669-09-0

1,1-bis(isobutyloxy)-ethane

acetic acid
64-19-7

acetic acid

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

Conditions
ConditionsYield
With water; N-chlorobenzamide at 313℃; Kinetics; Further Variations:; pH-values; Reagents; Temperatures; Oxidation;
aluminum ethoxide
555-75-9

aluminum ethoxide

acetaldehyde
75-07-0

acetaldehyde

isobutyraldehyde
78-84-2

isobutyraldehyde

A

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

B

ethyl acetate
141-78-6

ethyl acetate

C

Ethyl isobutyrate
97-62-1

Ethyl isobutyrate

D

isobutyl isobutyrate

isobutyl isobutyrate

Conditions
ConditionsYield
analog reagiert statt bei Einw.von Aluminiumaethylat mit Isovaleraldehyd, mit Benzaldehyd sowie mit Zimtaldehyd;
propene
187737-37-7

propene

carbon monoxide

carbon monoxide

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

Conditions
ConditionsYield
With hydrogen; cobalt(II) acetate at 175 - 250℃; under 514855 Torr; und Essigsaeure;
2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

isophytol
505-32-8

isophytol

Trimethylhydroquinone
700-13-0

Trimethylhydroquinone

Tocopherol
59-02-9

Tocopherol

Conditions
ConditionsYield
With hydrogenchloride; Zinc chloride In water; toluene99.6%
With hydrogenchloride; Zinc chloride In water; toluene98.6%
2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

ethanol
64-17-5

ethanol

Conditions
ConditionsYield
With C17H16BrMnNO3P; potassium tert-butylate; hydrogen In 1,4-dioxane at 100℃; under 37503.8 Torr; for 16h; Autoclave;99%
2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

isobutyl p-methoxycinnamate
136748-36-2

isobutyl p-methoxycinnamate

Conditions
ConditionsYield
With pyridine; titanium tetrachloride In 5,5-dimethyl-1,3-cyclohexadiene at -10 - 10℃; for 12h;98%
Geraniol
106-24-1

Geraniol

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

3,7-dimethyl-2E,6-octadien-1-yl acetate
105-87-3

3,7-dimethyl-2E,6-octadien-1-yl acetate

Conditions
ConditionsYield
With caesium carbonate at 125℃; for 30h;96%
2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

2-phenylethanol
60-12-8

2-phenylethanol

acetic acid phenethyl ester
103-45-7

acetic acid phenethyl ester

Conditions
ConditionsYield
With caesium carbonate at 125℃; for 19h;93%
2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

(SS)-2-methyl-N-(2,2,2-trifluoroethylidene)-propane-2-sulfinamide

(SS)-2-methyl-N-(2,2,2-trifluoroethylidene)-propane-2-sulfinamide

(S)-isobutyl 4,4,4-trifluoro-3-((S)-2-methylpropan-2-ylsulfinamido)butanoate

(S)-isobutyl 4,4,4-trifluoro-3-((S)-2-methylpropan-2-ylsulfinamido)butanoate

Conditions
ConditionsYield
Stage #1: 2-methylpropyl acetate With lithium diisopropyl amide In tetrahydrofuran; toluene at -78℃; for 1h; Inert atmosphere;
Stage #2: (SS)-2-methyl-N-(2,2,2-trifluoroethylidene)-propane-2-sulfinamide In tetrahydrofuran; toluene at -78 - 20℃; for 2h; Inert atmosphere; diastereoselective reaction;
86%
iodobenzene
591-50-4

iodobenzene

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

benzamide
55-21-0

benzamide

A

N-phenyl benzoyl amide
93-98-1

N-phenyl benzoyl amide

B

isobutyl benzoate
120-50-3

isobutyl benzoate

Conditions
ConditionsYield
With potassium phosphate; copper(l) iodide; N-(2-fluorophenyl)picolinamide at 150℃; for 24h; Green chemistry;A 85%
B 15%
2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

benzyl alcohol
100-51-6

benzyl alcohol

2-methylpropyl 3-phenypropionate
28048-94-4

2-methylpropyl 3-phenypropionate

Conditions
ConditionsYield
With C15H17ClIrNOP; potassium tert-butylate In toluene at 60℃; for 12h; Schlenk technique; Inert atmosphere; Glovebox;84%
2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

para-iodoanisole
696-62-8

para-iodoanisole

benzamide
55-21-0

benzamide

A

isobutyl benzoate
120-50-3

isobutyl benzoate

B

N-(p-methoxyphenyl)benzamide
7472-54-0

N-(p-methoxyphenyl)benzamide

Conditions
ConditionsYield
With potassium phosphate; copper(l) iodide; N-(2-fluorophenyl)picolinamide at 150℃; for 24h; Catalytic behavior; Reagent/catalyst; Green chemistry;A 22%
B 83%
iodobenzene
591-50-4

iodobenzene

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

3-trifluoromethylbenzamide
1801-10-1

3-trifluoromethylbenzamide

A

C12H13F3O2

C12H13F3O2

B

N-phenyl-3-(trifluoromethyl)benzamide
106376-18-5

N-phenyl-3-(trifluoromethyl)benzamide

Conditions
ConditionsYield
With potassium phosphate; copper(l) iodide; N-(2-fluorophenyl)picolinamide at 150℃; for 24h; Green chemistry;A 19%
B 81%
2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

benzyl alcohol
100-51-6

benzyl alcohol

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
With caesium carbonate at 125℃; for 16h;76%
2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

ethyl 3,4-dimethoxy-α-(3,4-dimethoxybenzyl)cinnamate

ethyl 3,4-dimethoxy-α-(3,4-dimethoxybenzyl)cinnamate

6-ethoxycarbonyl-5-((2-methylpropoxy)carbonylmethyl)-2,3,9,10-tetramethoxy-5H-dibenzo[a,c]cycloheptene
1267491-56-4

6-ethoxycarbonyl-5-((2-methylpropoxy)carbonylmethyl)-2,3,9,10-tetramethoxy-5H-dibenzo[a,c]cycloheptene

Conditions
ConditionsYield
Stage #1: ethyl 3,4-dimethoxy-α-(3,4-dimethoxybenzyl)cinnamate With molybdenum(V) chloride; titanium tetrachloride In dichloromethane at 0 - 20℃; Inert atmosphere;
Stage #2: 2-methylpropyl acetate With triethylamine In dichloromethane at 20℃; Cooling with ice;
72%
2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

para-iodoanisole
696-62-8

para-iodoanisole

3-trifluoromethylbenzamide
1801-10-1

3-trifluoromethylbenzamide

A

N-(4-methoxyphenyl)-3-(trifluoromethyl)benzamide

N-(4-methoxyphenyl)-3-(trifluoromethyl)benzamide

B

C12H13F3O2

C12H13F3O2

Conditions
ConditionsYield
With potassium phosphate; copper(l) iodide; N-(2-fluorophenyl)picolinamide at 150℃; for 24h; Green chemistry;A 66%
B 18%
octanol
111-87-5

octanol

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

n-octyl acetate
112-14-1

n-octyl acetate

Conditions
ConditionsYield
With caesium carbonate at 125℃; for 29h;63%
2-acetoxyethane phosphonic acid diethyl ester

2-acetoxyethane phosphonic acid diethyl ester

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

2-hydroxyethanephosphonic acid diethyl ester
39997-40-5

2-hydroxyethanephosphonic acid diethyl ester

Conditions
ConditionsYield
With hydrogenchloride In 2-methyl-propan-1-ol62%
2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

3-Phenylpropenol
104-54-1

3-Phenylpropenol

cinnamyl acetate
103-54-8

cinnamyl acetate

Conditions
ConditionsYield
With caesium carbonate at 125℃; for 25h;62%
iodobenzene
591-50-4

iodobenzene

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

nicotinamide
98-92-0

nicotinamide

A

Iso-butyl nicotinate
31678-58-7

Iso-butyl nicotinate

B

N-phenylnicotinamide
1752-96-1

N-phenylnicotinamide

Conditions
ConditionsYield
With potassium phosphate; copper(l) iodide; N-(2-fluorophenyl)picolinamide at 150℃; for 24h; Green chemistry;A 6%
B 61%
2-Phenoxyethanol
122-99-6

2-Phenoxyethanol

2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

2-phenoxyethyl acetate
6192-44-5

2-phenoxyethyl acetate

Conditions
ConditionsYield
With caesium carbonate at 125℃; for 19h;59%
2-methylpropyl acetate
110-19-0

2-methylpropyl acetate

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

benzamide
55-21-0

benzamide

A

isobutyl benzoate
120-50-3

isobutyl benzoate

B

N-(4-acetylphenyl)benzamide
5411-13-2

N-(4-acetylphenyl)benzamide

Conditions
ConditionsYield
With potassium phosphate; copper(l) iodide; N-(2-fluorophenyl)picolinamide at 150℃; for 24h; Green chemistry;A 9%
B 59%

110-19-0Downstream Products

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