
Peptoid-synthesis-inspired modular assembly of azaxylylene precursors and their cyclizations. [a] Acetal hydrolysis step is required only in the a (i.e. benzaldehyde) series. [b] major diastereomer is shown, the minor hydroxy epimer (not shown) is deno
Condensation of benzil, benzaldehyde, ammonium acetate and n-Pr amine using recycled catalysts.
Scheme of preparation of ligand L.
Potential energy profiles for the addition of benzaldehyde to (TmS)3Si+ and me3Si+.