Welcome to LookChem.com Sign In|Join Free

CAS

  • or

372-64-5

Post Buying Request

372-64-5 Suppliers

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier

372-64-5 Usage

Uses

Bis(trifluoromethyl)disulfide is used in preparation of trifluoromethylsulfinyl chloride.

Check Digit Verification of cas no

The CAS Registry Mumber 372-64-5 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 3,7 and 2 respectively; the second part has 2 digits, 6 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 372-64:
(5*3)+(4*7)+(3*2)+(2*6)+(1*4)=65
65 % 10 = 5
So 372-64-5 is a valid CAS Registry Number.
InChI:InChI=1/C2F6S2/c3-1(4,5)9-10-2(6,7)8

372-64-5Synthetic route

mercury bis(trifluoromethanethiolate)
21259-75-6

mercury bis(trifluoromethanethiolate)

A

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

B

trifluoromethylthio-mercury(II) chloride

trifluoromethylthio-mercury(II) chloride

C

bis(trifluoromethylthio)tellurium
83665-28-5

bis(trifluoromethylthio)tellurium

Conditions
ConditionsYield
With tellurium tetrachloride for 1h; Heating;A n/a
B n/a
C 83%
iodotrifluoromethane
2314-97-8

iodotrifluoromethane

sulfur
7704-34-9

sulfur

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

Conditions
ConditionsYield
390-420°C, atm. pessure in a continuous flow system;80.6%
390-420°C, atm. pessure in a continuous flow system;80.6%
>200°C, in autoclave;
>200°C, in autoclave;
O,O-diethyl S-trifluoromethyl phosphorothioate
79378-29-3

O,O-diethyl S-trifluoromethyl phosphorothioate

A

thiocarbonyl fluoride
420-32-6

thiocarbonyl fluoride

B

diethyl fluorophosphate
358-74-7

diethyl fluorophosphate

C

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

Conditions
ConditionsYield
With triethylamine In dichloromethane at 10℃; for 0.166667h;A n/a
B 76%
C n/a
mercury bis(trifluoromethanethiolate)
21259-75-6

mercury bis(trifluoromethanethiolate)

dimethylamino sulfonyl chloride
13360-57-1

dimethylamino sulfonyl chloride

A

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

B

N,N-Dimethyl-S-(trifluormethyl)thiosulfamidsaeure

N,N-Dimethyl-S-(trifluormethyl)thiosulfamidsaeure

Conditions
ConditionsYield
In acetonitrileA n/a
B 76%
hydrogen fluoride
7664-39-3

hydrogen fluoride

chlorothio-trichloro-methane
594-42-3

chlorothio-trichloro-methane

A

Trifluoromethylsulfenyl chloride
421-17-0

Trifluoromethylsulfenyl chloride

B

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

C

Trifluoro-methanethiosulfonic acid S-trifluoromethyl ester
358-15-6

Trifluoro-methanethiosulfonic acid S-trifluoromethyl ester

Conditions
ConditionsYield
180°C; chrom oxide fluoride catalyst;A 74%
B n/a
C n/a
dimethyl(bromo)arsine
676-71-1

dimethyl(bromo)arsine

Copper(I) trifluoromethanethiolate
3872-23-9

Copper(I) trifluoromethanethiolate

A

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

B

bis(trifluoromethyl)trisulfide
372-06-5

bis(trifluoromethyl)trisulfide

C

bis(trifluoromethyl)tetrasulfide
372-07-6

bis(trifluoromethyl)tetrasulfide

D

dimethyl(trifluoromethylthio)arsine
1959-80-4

dimethyl(trifluoromethylthio)arsine

Conditions
ConditionsYield
at 80 - 90℃; for 6h; Further byproducts given;A n/a
B n/a
C n/a
D 70%
Trifluoromethylsulfenyl chloride
421-17-0

Trifluoromethylsulfenyl chloride

toluene
108-88-3

toluene

A

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

B

benzyl trifluoromethyl sulfide
351-60-0

benzyl trifluoromethyl sulfide

C

benzyl chloride
100-44-7

benzyl chloride

Conditions
ConditionsYield
byproducts: HCl; Irradiation (UV/VIS);A n/a
B 70%
C 3%
byproducts: HCl; Irradiation (UV/VIS);A n/a
B 70%
C 3%
for 0.283333h; Mechanism; Irradiation; effect of bis(heptafluoro-n-propyl) disulfide;
potassium fluoride

potassium fluoride

chlorothio-trichloro-methane
594-42-3

chlorothio-trichloro-methane

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

Conditions
ConditionsYield
With hydrogen bromide In further solvent(s) 160-175°C; solvent: tetramethylenesulfone;68%
With HBr In further solvent(s) 160-175°C; solvent: tetramethylenesulfone;68%
potassium fluoride

potassium fluoride

Bis(trichloromethyl)disulfane
15110-08-4

Bis(trichloromethyl)disulfane

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

Conditions
ConditionsYield
In further solvent(s) 150-160°C; solvent: tetramethylenesulfone;58%
In further solvent(s) 150-160°C; solvent: tetramethylenesulfone;58%
2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

1-phenyl-2-(phenyl-λ3-iodaneylidene)-2-((trifluoromethyl)sulfonyl)ethan-1-one
1443036-49-4

1-phenyl-2-(phenyl-λ3-iodaneylidene)-2-((trifluoromethyl)sulfonyl)ethan-1-one

A

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

B

2-phenyl-5-((trifluoromethyl)thio)-1H-pyrrole

2-phenyl-5-((trifluoromethyl)thio)-1H-pyrrole

Conditions
ConditionsYield
Stage #1: 1-phenyl-2-(phenyl-λ3-iodaneylidene)-2-((trifluoromethyl)sulfonyl)ethan-1-one With copper (II)-fluoride In 1-methyl-pyrrolidin-2-one at 20℃; for 0.333333h;
Stage #2: 2-phenyl-1H-pyrrole at 20℃; for 5h; regioselective reaction;
A 28%
B 58%
Trifluoromethylsulfenyl chloride
421-17-0

Trifluoromethylsulfenyl chloride

sodium acetate
127-09-3

sodium acetate

A

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

B

Trifluoro-methanethiosulfonic acid S-trifluoromethyl ester
358-15-6

Trifluoro-methanethiosulfonic acid S-trifluoromethyl ester

C

trifluoromethyl-sulfenyl acetate
42530-92-7

trifluoromethyl-sulfenyl acetate

D

acetic anhydride
108-24-7

acetic anhydride

Conditions
ConditionsYield
at 0℃; for 12h;A n/a
B n/a
C 52%
D n/a
tris(trifluoromethylmercapto)amine
4317-00-4

tris(trifluoromethylmercapto)amine

A

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

B

tetrakis (trifluormethylmarcapto)-hydrazine
80653-51-6

tetrakis (trifluormethylmarcapto)-hydrazine

Conditions
ConditionsYield
In trichlorofluoromethane at -73.1℃; for 6h; Irradiation;A n/a
B 50%
In trichlorofluoromethane at -73.1℃; for 6h; Product distribution; Irradiation; other temperature 298 deg K;A n/a
B 10 % Turnov.
methyldichloroarsane
593-89-5

methyldichloroarsane

mercury bis(trifluoromethanethiolate)
21259-75-6

mercury bis(trifluoromethanethiolate)

A

methyldifluoroarsine
420-24-6

methyldifluoroarsine

B

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

C

bis(trifluoromethyl)trithiocarbonate
461-08-5

bis(trifluoromethyl)trithiocarbonate

D

bis(trifluoromethylthio)methylarsine

bis(trifluoromethylthio)methylarsine

Conditions
ConditionsYield
at 95 - 100℃; for 4h;A n/a
B n/a
C n/a
D 48%
Trifluoromethylsulfenyl chloride
421-17-0

Trifluoromethylsulfenyl chloride

Isobutane
75-28-5

Isobutane

A

CF3SCH2C(CH3)3

CF3SCH2C(CH3)3

B

tertiary butyl chloride
507-20-0

tertiary butyl chloride

C

2-methyl-2-[(trifluoromethyl)thio]propane
2708-84-1

2-methyl-2-[(trifluoromethyl)thio]propane

D

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

E

isobutyryl chloride
513-36-0

isobutyryl chloride

Conditions
ConditionsYield
byproducts: HCl; Irradiation (UV/VIS);A 12%
B 33%
C 24%
D 47%
E 1%
byproducts: HCl; Irradiation (UV/VIS);A 12%
B 33%
C 24%
D 47%
E 1%
Trifluoromethylsulfenyl chloride
421-17-0

Trifluoromethylsulfenyl chloride

n-butane
106-97-8

n-butane

A

s-butyl chloride
78-86-4, 53178-20-4

s-butyl chloride

B

n-Butyl chloride
109-69-3

n-Butyl chloride

C

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

D

Trifluormethyl-sek.-butyl-sulfid
6214-34-2

Trifluormethyl-sek.-butyl-sulfid

E

1-[(trifluoromethyl)thio]butane
7412-26-2

1-[(trifluoromethyl)thio]butane

Conditions
ConditionsYield
byproducts: HCl; Irradiation (UV/VIS);A 12%
B 1%
C 28%
D 46%
E 13%
byproducts: HCl; Irradiation (UV/VIS);A 12%
B 1%
C 28%
D 46%
E 13%
Trifluoromethylsulfenyl chloride
421-17-0

Trifluoromethylsulfenyl chloride

cyclohexane
110-82-7

cyclohexane

A

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

B

cyclohexyl(trifluoromethyl)sulfane
6476-52-4

cyclohexyl(trifluoromethyl)sulfane

C

cyclohexyl chloride
542-18-7

cyclohexyl chloride

Conditions
ConditionsYield
byproducts: HCl; Irradiation (UV/VIS);A 35%
B 45%
C 28%
byproducts: HCl; Irradiation (UV/VIS);A 35%
B 45%
C 28%
for 0.2h; Mechanism; Irradiation; effect of bis(heptafluoro-n-propyl) disulfide;
Trifluoromethylsulfenyl chloride
421-17-0

Trifluoromethylsulfenyl chloride

dihydrogen peroxide
7722-84-1

dihydrogen peroxide

A

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

B

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

C

trifluoromethane sulfonyl chloride
421-83-0

trifluoromethane sulfonyl chloride

Conditions
ConditionsYield
35% H2O2 soln.;A 35%
B 7%
C 40%
35% H2O2 soln.;A 35%
B 7%
C 40%
Trifluoromethylsulfenyl chloride
421-17-0

Trifluoromethylsulfenyl chloride

A

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

B

tetrakis(trifluoromethylthiazyl)
99028-27-0

tetrakis(trifluoromethylthiazyl)

Conditions
ConditionsYield
With trimethylsilylazide In trichlorofluoromethane at -30℃; for 24h;A n/a
B 37%
furan
110-00-9

furan

Trifluoromethylsulfenyl chloride
421-17-0

Trifluoromethylsulfenyl chloride

A

2-Trifluormethylmercapto-furan
58679-57-5

2-Trifluormethylmercapto-furan

B

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

Conditions
ConditionsYield
With pyridine at 20℃; for 12h; other sulfenyl chloride;A 35%
B n/a
With pyridine at 20℃; for 12h;A 35%
B n/a
F2S2O6
13955-08-3

F2S2O6

trifluoromethylsulfide
1493-15-8

trifluoromethylsulfide

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

Conditions
ConditionsYield
-183 to 25°C;30%
-183 to 25°C;30%
bis(fluorosulfuryl) peroxide
13709-32-5

bis(fluorosulfuryl) peroxide

trifluoromethylsulfide
1493-15-8

trifluoromethylsulfide

A

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

B

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

C

sulfur dioxide
7446-09-5

sulfur dioxide

D

sulfur
7704-34-9

sulfur

Conditions
ConditionsYield
CF3SH:S2O6F2 molar ratio 1:1, from -183 to +25°C;A n/a
B 30%
C n/a
D n/a
ethylarsenic dichloride
598-14-1

ethylarsenic dichloride

Copper(I) trifluoromethanethiolate
3872-23-9

Copper(I) trifluoromethanethiolate

A

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

B

trifluoromethylmercaptothiocarbonyl fluoride
371-73-3

trifluoromethylmercaptothiocarbonyl fluoride

C

bis(trifluoromethyl)trisulfide
372-06-5

bis(trifluoromethyl)trisulfide

D

ethyl bis(trifluoromethylthio)arsine

ethyl bis(trifluoromethylthio)arsine

Conditions
ConditionsYield
at 85 - 95℃; for 6h; Further byproducts given;A n/a
B n/a
C n/a
D 25%
CF2HC(O)OSCF3

CF2HC(O)OSCF3

A

difluoromethyl-trifluoromethyl sulfide
371-72-2

difluoromethyl-trifluoromethyl sulfide

B

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

Conditions
ConditionsYield
Irradiation (UV/VIS); in Pyrex bulb;A n/a
B 25%
Irradiation (UV/VIS); in Pyrex bulb;A n/a
B 25%
trichloromethanesulfenyl bromide
993-35-1

trichloromethanesulfenyl bromide

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

Conditions
ConditionsYield
With sulfolane; potassium fluoride at 175℃; Inert atmosphere;15%
Trifluoromethylsulfenyl chloride
421-17-0

Trifluoromethylsulfenyl chloride

A

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

B

hexachloro-3-cyclopentenylidenaminotrifluormethylsulfide
114541-92-3

hexachloro-3-cyclopentenylidenaminotrifluormethylsulfide

Conditions
ConditionsYield
With trimethylsilylazide; hexachlorocyclopentadiene In toluene at 110℃; under 0.01 Torr; for 3h;A n/a
B 6.2%
Trifluoromethylsulfenyl chloride
421-17-0

Trifluoromethylsulfenyl chloride

trimethylsilylazide
4648-54-8

trimethylsilylazide

hexachlorocyclopentadiene
77-47-4

hexachlorocyclopentadiene

A

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

B

hexachloro-3-cyclopentenylidenaminotrifluormethylsulfide
114541-92-3

hexachloro-3-cyclopentenylidenaminotrifluormethylsulfide

Conditions
ConditionsYield
In toluene at 110℃; under 0.01 Torr; for 3h;A n/a
B 6.2%
carbon disulfide
75-15-0

carbon disulfide

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

Conditions
ConditionsYield
With iodine pentafluoride at 195℃;
With mercury(II) fluoride at 500℃;
iodotrifluoromethane
2314-97-8

iodotrifluoromethane

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

Conditions
ConditionsYield
With sulfur at 310℃;
tetrafluoro-1,3-dithiaetane
1717-50-6

tetrafluoro-1,3-dithiaetane

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

Conditions
ConditionsYield
With sulfur tetrafluoride at 250℃;
Trifluoromethylsulfenyl chloride
421-17-0

Trifluoromethylsulfenyl chloride

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

Conditions
ConditionsYield
iron pentacarbonyl In tetrahydrofuran at -80℃;
With perfluoropropylene for 72h; Irradiation;
With trifluoro-methoxy-ethene for 0.166667h; Irradiation; Further byproducts given;
propene
187737-37-7

propene

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

1,2-Bis-trifluoromethylsulfanyl-propane
34994-61-1

1,2-Bis-trifluoromethylsulfanyl-propane

Conditions
ConditionsYield
Irradiation (UV/VIS); 20 h;100%
Irradiation (UV/VIS); 20 h;100%
Irradiation;
ethene
74-85-1

ethene

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

1,2-Bis-trifluormethyl-mercapto-ethan
674-64-6

1,2-Bis-trifluormethyl-mercapto-ethan

Conditions
ConditionsYield
Irradiation (UV/VIS); 44 h;100%
Irradiation (UV/VIS); 44 h;100%
Irradiation;
Tetrakis(dimethylamino)ethylen
996-70-3

Tetrakis(dimethylamino)ethylen

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

tetrakis(dimethylamino)ethanebis(ylium) bis(trifluoro-methanethiolate)

tetrakis(dimethylamino)ethanebis(ylium) bis(trifluoro-methanethiolate)

Conditions
ConditionsYield
In 1,2-dimethoxyethane at -20℃; for 0.166667h; Reduction;98.3%
Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

benzyl tetraethylphosphorodiamidite
66954-57-2

benzyl tetraethylphosphorodiamidite

A

benzyl trifluoromethyl sulfide
351-60-0

benzyl trifluoromethyl sulfide

B

bis(diethylamido)-S-trifluoromethylphosphorothioate

bis(diethylamido)-S-trifluoromethylphosphorothioate

Conditions
ConditionsYield
In pentane at -50℃; for 0.0833333h;A 95%
B n/a
chlorine trifluoride
7790-91-2

chlorine trifluoride

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

trifluoro(trifluoromethyl)sulfur(IV)
374-10-7

trifluoro(trifluoromethyl)sulfur(IV)

Conditions
ConditionsYield
In dichloromethane -78°C;95%
In dichloromethane -78°C;95%
In Dichlorodifluoromethane excess ClF3, -196 to -78°C;
In Dichlorodifluoromethane excess ClF3, -196 to -78°C;
perfluoropropylene
116-15-4

perfluoropropylene

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

A

2,5-bis(trifluoromethylmercapto)-4-trifluoromethyl-nonafluoropentane
646-86-6

2,5-bis(trifluoromethylmercapto)-4-trifluoromethyl-nonafluoropentane

B

1,2-bis(trifluoromethylsulfanyl)hexafluoropropane
679-31-2

1,2-bis(trifluoromethylsulfanyl)hexafluoropropane

Conditions
ConditionsYield
Irradiation (UV/VIS); 184 h;A 90.5%
B 9.5%
Irradiation (UV/VIS); 184 h;A 90.5%
B 9.5%
Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

C12H27N2O3P

C12H27N2O3P

A

Ethyl <(trifluoromethyl)thio>acetate
65540-51-4

Ethyl <(trifluoromethyl)thio>acetate

B

bis(diethylamido)-S-trifluoromethylphosphorothioate

bis(diethylamido)-S-trifluoromethylphosphorothioate

Conditions
ConditionsYield
In pentane at -50℃; for 0.0833333h;A 90%
B n/a
Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

C13H29N2O3P

C13H29N2O3P

A

Ethyl 2-<(trifluoromethyl)thio>propanoate
84132-15-0

Ethyl 2-<(trifluoromethyl)thio>propanoate

B

bis(diethylamido)-S-trifluoromethylphosphorothioate

bis(diethylamido)-S-trifluoromethylphosphorothioate

Conditions
ConditionsYield
In pentane at -50℃; for 0.0833333h;A 90%
B n/a
Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

Tetrakis(trifluoromethyl)cyclotetraphosphane
393-02-2

Tetrakis(trifluoromethyl)cyclotetraphosphane

A

Trifluormethyl-(bis-methylmercapto)-phosphin
1898-62-0

Trifluormethyl-(bis-methylmercapto)-phosphin

B

pentakis-trifluoromethyl-cyclopentaphosphane
745-23-3, 54548-49-1

pentakis-trifluoromethyl-cyclopentaphosphane

Conditions
ConditionsYield
143°C, 1 h;A 90%
B n/a
143°C, 1 h;A 90%
B n/a
20°C, 12 h;
20°C, 12 h;
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

Pd(SCF3)2{P(C6H5)3}2
50298-23-2, 50298-22-1

Pd(SCF3)2{P(C6H5)3}2

Pd(SCF3)2{P(C6H5)3}2
50298-23-2, 50298-22-1

Pd(SCF3)2{P(C6H5)3}2

Conditions
ConditionsYield
In pentane Irradiation (UV/VIS); with low-pressure mercury lamp, 25°C, 30 min;A 10%
B 90%
In pentane Irradiation (UV/VIS); with low-pressure mercury lamp, 25°C, 30 min;A 10%
B 90%
Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

fluorine
7782-41-4

fluorine

trifluoro(trifluoromethyl)sulfur(IV)
374-10-7

trifluoro(trifluoromethyl)sulfur(IV)

Conditions
ConditionsYield
fluorination with F2/He (flow rate 1 mL/min F2 and 60 mL min He) in continuous flow reactor at -120°C (38 h);90%
fluorination with F2/He (flow rate 1 mL/min F2 and 60 mL min He) in continuous flow reactor at -120°C (38 h);90%
with N2 dild. F2 used;
with N2 dild. F2 used;
{C6H5NiCO}2

{C6H5NiCO}2

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

(C6H5NiSCF3)2

(C6H5NiSCF3)2

Conditions
ConditionsYield
In pentane Irradiation (UV/VIS); medium-pressure mercury lamp, 25 h;90%
In pentane Irradiation (UV/VIS); medium-pressure mercury lamp, 25 h;90%
dimanganese decacarbonyl
10170-69-1

dimanganese decacarbonyl

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

A

Mn2(CO)8(SCF3)2
21239-57-6

Mn2(CO)8(SCF3)2

B

CF3SMn(CO)5
50979-57-2

CF3SMn(CO)5

Conditions
ConditionsYield
In pentane Irradiation (UV/VIS); medium-pressure mercury lamp, -10°C, 24 h;A 90%
B n/a
In pentane Irradiation (UV/VIS); medium-pressure mercury lamp, -10°C, 24 h;A 90%
B n/a
Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

bis-(trifluoromethyl)sulfide
371-78-8

bis-(trifluoromethyl)sulfide

Conditions
ConditionsYield
heating at 425-435°C, 3-4 d;88%
Irradiation (UV/VIS); in quartztube, 13 d;39%
Irradiation (UV/VIS); in quartztube, 13 d;39%
Irradiation.UV-Licht;
Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

(Rp)-t-butyl(phenyl)phosphine oxide
82945-11-7, 6057-79-0, 57956-51-1

(Rp)-t-butyl(phenyl)phosphine oxide

(-)-S-t-butyl(phenyl)-S-trifluoromethyl phosphinothioate
128175-77-9

(-)-S-t-butyl(phenyl)-S-trifluoromethyl phosphinothioate

Conditions
ConditionsYield
In dichloromethane at 20℃; for 6h;88%
hydrido(tricarbonyl)(cyclopentadienyl)molybdenum
12176-06-6

hydrido(tricarbonyl)(cyclopentadienyl)molybdenum

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

[(η(5)-C5H5)Mo(CO)3SCF3]

[(η(5)-C5H5)Mo(CO)3SCF3]

Conditions
ConditionsYield
In benzene byproducts: HSCF3; (N2 or in vacuum with Schlenk-technique); react. at 25°C for 2 d; chromy. on SiO2-column with benzene/cyclohexane;87.3%
Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

tert-Butylphenylphosphine oxide
98976-30-8, 57956-51-1, 6057-79-0, 82945-11-7

tert-Butylphenylphosphine oxide

t-butyl(phenyl) S-trifluoromethyl phosphinothioate

t-butyl(phenyl) S-trifluoromethyl phosphinothioate

Conditions
ConditionsYield
In dichloromethane -85 to -80 deg C, 30 min, then 15-20 deg C, 5 h;85%
Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

2-diethylamino-1,3,2-dioxaphosphorinane
38432-39-2

2-diethylamino-1,3,2-dioxaphosphorinane

O-(3-S-trifluoromethyl)propyl S-trifluoromethyl N,N-diethylamidophosphorothioate

O-(3-S-trifluoromethyl)propyl S-trifluoromethyl N,N-diethylamidophosphorothioate

Conditions
ConditionsYield
In dichloromethane -85 to -80 deg C, 30 min, then 15-20 deg C, 5 h;85%
Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

3,4,5-trimethoxy-2-(trimethylsilyl)phenyl trifluoromethanesulfonate

3,4,5-trimethoxy-2-(trimethylsilyl)phenyl trifluoromethanesulfonate

3,4,5-trimethoxy-1,2-bis(trifluoromethylthio)benzene

3,4,5-trimethoxy-1,2-bis(trifluoromethylthio)benzene

Conditions
ConditionsYield
With cesium fluoride In 1,2-dimethoxyethane at 85℃; for 24h; Inert atmosphere; Sealed tube;84%
Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

2-(diethylamino)-4-methyl-1,3,2-dioxaphospholane
3440-92-4

2-(diethylamino)-4-methyl-1,3,2-dioxaphospholane

O-(1-methyl, 2-S-trifluoromethyl)ethyl S-trifluoromethyl N,N-diethylamidophosphorothioate

O-(1-methyl, 2-S-trifluoromethyl)ethyl S-trifluoromethyl N,N-diethylamidophosphorothioate

Conditions
ConditionsYield
In dichloromethane -85 to -80 deg C, 30 min, then 15-20 deg C, 5 h;83%
Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

C24H33F3O5SSi

C24H33F3O5SSi

C22H24F6O2S2

C22H24F6O2S2

Conditions
ConditionsYield
With cesium fluoride In 1,2-dimethoxyethane at 110℃; for 48h; Inert atmosphere; Sealed tube;83%
Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

(6-iodo-2,3,4-trimethoxyphenyl)dimethylsilane

(6-iodo-2,3,4-trimethoxyphenyl)dimethylsilane

A

C10H10F3IO3S

C10H10F3IO3S

B

3,4,5-trimethoxy-1,2-bis(trifluoromethylthio)benzene

3,4,5-trimethoxy-1,2-bis(trifluoromethylthio)benzene

Conditions
ConditionsYield
With cesium fluoride In 1,2-dimethoxyethane at 110℃; for 37h; Inert atmosphere; Sealed tube;A n/a
B 82%
Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

2-diethylamino-1,3,2-dioxaphospholane
3741-34-2

2-diethylamino-1,3,2-dioxaphospholane

O-2-(S-trifluoromethyl)ethyl S-trifluoromethyl N,N-diethylamidophosphorothioate

O-2-(S-trifluoromethyl)ethyl S-trifluoromethyl N,N-diethylamidophosphorothioate

Conditions
ConditionsYield
In dichloromethane -85 to -80 deg C, 30 min, then 15-20 deg C, 5 h;81%
Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

4-methoxy-N-(8-quinolinyl)benzamide
33757-50-5

4-methoxy-N-(8-quinolinyl)benzamide

N-(2,6-di(trifluoromethylthio)-4-methoxybenzoyl)-8-aminoquinoline
1404616-69-8

N-(2,6-di(trifluoromethylthio)-4-methoxybenzoyl)-8-aminoquinoline

Conditions
ConditionsYield
With copper diacetate In dimethyl sulfoxide at 100℃; for 5.75h;81%
Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

4-methoxy-aniline
104-94-9

4-methoxy-aniline

4-methoxyphenyl trifluoromethylsulfide
78914-94-0

4-methoxyphenyl trifluoromethylsulfide

Conditions
ConditionsYield
Stage #1: 4-methoxy-aniline With tetrafluoroboric acid; tert.-butylnitrite In water; acetic acid at 20℃; for 0.0833333h; Green chemistry;
Stage #2: Bis(trifluoromethyl)disulfid With sodium acetate In dimethyl sulfoxide at 20℃; for 8h; Inert atmosphere; Green chemistry;
81%
Stage #1: 4-methoxy-aniline With tetrafluoroboric acid; sodium nitrite In water at 0℃; for 0.666667h;
Stage #2: Bis(trifluoromethyl)disulfid With tris(bipyridine)ruthenium(II) dichloride hexahydrate In dimethyl sulfoxide at 20℃; for 1h; Reagent/catalyst; Inert atmosphere; Irradiation;
131.2 mg
Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

1-(trimethylsilyl)-5,6,7,8-tetrahydronaphthalen-2-yl trifluoromethanesulfonate

1-(trimethylsilyl)-5,6,7,8-tetrahydronaphthalen-2-yl trifluoromethanesulfonate

1,2-bis((trifluoromethyl)thio)-5,6,7,8-tetrahydronaphthalene

1,2-bis((trifluoromethyl)thio)-5,6,7,8-tetrahydronaphthalene

Conditions
ConditionsYield
With cesium fluoride In 1,2-dimethoxyethane at 110℃; for 46h; Inert atmosphere; Sealed tube;81%
Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

phosphorous acid trimethyl ester
121-45-9

phosphorous acid trimethyl ester

A

methyl trifluoromethyl sulphide
421-16-9

methyl trifluoromethyl sulphide

B

O,O-dimethyl-S-trifluoromethyl phosphorthioate
30295-39-7

O,O-dimethyl-S-trifluoromethyl phosphorthioate

Conditions
ConditionsYield
In dichloromethane 1) -75 deg C, 2) 20 deg C, 50 min;A n/a
B 80%
In dichloromethane -75 to 20°C;A n/a
B 80%
In dichloromethane -75 to 20°C;A n/a
B 80%
(bis(triphenylphosphoranylidene)ammonium){CpMo(CO)3}

(bis(triphenylphosphoranylidene)ammonium){CpMo(CO)3}

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

[(η(5)-C5H5)Mo(CO)3SCF3]

[(η(5)-C5H5)Mo(CO)3SCF3]

Conditions
ConditionsYield
In dichloromethane a soln. of Mo-complex and CF3SSCF3 was stirred under N2 at room temp. for 2 h (IR monitoring); solvent was removed by evapn. under a stream of N2, product purified by chromy. on Al2O3 and crystn.;80%

372-64-5Relevant articles and documents

Dear,Gilbert

, p. 310 (1972)

Haas,Peach

, p. 299,302 (1965)

Boron Trifluoride-Mediated Trifluoromethylthiolation of N-Acyliminiums

Maury, Julien,Force, Guillaume,Darses, Benjamin,Leb?uf, David

, p. 2752 - 2756 (2018)

Herein, we describe a hitherto unprecedented trifluoromethylthiolation of N-acyliminiums promoted by boron trifluoride etherate to enable a convenient access to various α-amino trifluoromethylthiolate derivatives in good yields. The reaction proceeds under mild conditions, relying on copper(I) trifluoromethylthiolate as a nucleophilic partner. (Figure presented.).

-

Henn,Sundermeyer,Witz,Pritzkow

, p. 225 - 238 (1989)

2-Chloro-1,1,2,3,3,4,4,-heptafluoro-1,3-dithietane (7b), 2,4-dichloro-1,1,2,3,3,4-hexafluoro-1,3-dithietane (7c), 2-chloro-1,1,2,4,4-pentafluoro-3,3-dioxo-1,3-dithietane (9b), 2,4-dichloro-1,1,2,4-tetrafluoro-3,3-dioxo-1,3-dithietane (9c), and 1,1,2,2,4,4

Catalyst-Free Decarbonylative Trifluoromethylthiolation Enabled by Electron Donor-Acceptor Complex Photoactivation

Lipp, Alexander,Badir, Shorouk O.,Dykstra, Ryan,Gutierrez, Osvaldo,Molander, Gary A.

supporting information, p. 3507 - 3520 (2021/06/11)

A catalyst- and additive-free decarbonylative trifluoromethylthiolation of aldehyde feedstocks has been developed. This operationally simple, scalable, and open-to-air transformation is driven by the selective photoexcitation of electron donor-acceptor (EDA) complexes, stemming from the association of 1,4-dihydropyridines (donor) with N-(trifluoromethylthio)phthalimide (acceptor), to trigger intermolecular single-electron transfer events under ambient- and visible light-promoted conditions. Extension to other electron acceptors enables the synthesis of thiocyanates and thioesters, as well as the difunctionalization of [1.1.1]propellane. The mechanistic intricacies of this photochemical paradigm are elucidated through a combination of experimental efforts and high-level quantum mechanical calculations [dispersion-corrected (U)DFT, DLPNO-CCSD(T), and TD-DFT]. This comprehensive study highlights the necessity for EDA complexation for efficient alkyl radical generation. Computation of subsequent ground state pathways reveals that SH2 addition of the alkyl radical to the intermediate radical EDA complex is extremely exergonic and results in a charge transfer event from the dihydropyridine donor to the N-(trifluoromethylthio)phthalimide acceptor of the EDA complex. Experimental and computational results further suggest that product formation also occurs via SH2 reaction of alkyl radicals with 1,2-bis(trifluoromethyl)disulfane, generated in-situ through combination of thiyl radicals. (Figure presented.).

Trifluoromethylthiolation and trifluoromethanesulfonylation of β,γ-unsaturated hydrazones

Xiao, Hongqing,Meng, Weidong,Xu, Xiu-Hua,Huang, Yangen

, (2020/04/27)

The trifluoromethylthiolation and trifluoromethanesulfonylation of β,γ-unsaturated hydrazones was accomplished with silver(I) trifluoromethanethiolate (AgSCF3) as a CF3S source and sodium trifluoromethylsulfinate (CF3SO2Na) as a CF3SO2 source, respectively. These general methods for the preparation of dihydropyrazoles containing CF3S or CF3SO2 groups were characterized by mild reaction conditions and good functional group tolerance.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 372-64-5