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7786-30-3

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7786-30-3 Usage

General Description

Different sources of media describe the General Description of 7786-30-3 differently. You can refer to the following data:
1. Magnesium chloride,MgCI2,also known as chloromagnesite, is a colorless crystalline solid. It is soluble in water and alcohol and is used in the ceramic and textile industries. Magnesium chloride is formed by heating hydrated magnesium chloride crystals in a current of dry hydrogen chloride or by heating magnesium ammonium chloride. Hydrated magnesium chloride, MgCI2·6H20 , also known as bischophite,is a white deliquescent solid formed by the reaction of magnesium carbonate(or hydroxide,oxide or metal)and hydrogen chloride. It is used in disinfectants, fire extinguishers, and paper manufacture. magnesium chloride flakes
2. Magnesium chloride (MgCl2) is an inorganic compound that can be prepared by reacting magnesium oxide and ammonium chloride in the presence of alumina as a covering agent.

Uses

Different sources of media describe the Uses of 7786-30-3 differently. You can refer to the following data:
1. ▼▲ Industry Application Role/benefit Chemical manufacture Manufacturer of? magnesium metal and other magnesium compounds Source of magnesium Road maintenance Dust control Moisture absorbed from the air prevents dust formation Snow and ice control De-icing agent/helps to prevent the ice bond on the road and to remove ice buildup from road Medicine Treating or preventing magnesium deficiency Source of magnesium/helps to raise magnesium levels in the body Food Tofu Coagulant agent/helps liquid forms of soy to solidify into tofu Baby formula milk Ingredient Gas storage Storage of Hydrogen Gas Storage material/effectively absorbs ammonia which is rich in hydrogen atoms Cement Manufacturer of Sorel cement Raw material/Mixed with hydrated magnesium oxide to form hard material Others Fire extinguishers Effective reactant Paper filling Fire retardant Textile filling Keeps the humidity of cotton to make it soft Fertilizer Source of magnesium Mineral supplement for animals Refrigeration brine and artificial seawater Waste water treatment Effective ingredient Anesthesia for cephalopods, crustaceans and bivalve Anaesthetic Polymerase chain reaction Necessary for both in vivo/vitro DNA synthesis
2. An excellent magnesium ion source for synthesis and biology research
3. Magnesium Chloride is a source of magnesium, a color-retention agent, and firming agent. it exists as colorless flakes or crystals and is very soluble in water.
4. Magnesium chloride is used for a variety of other applications besides the production of Mg metal. It is used in the manufacture of textiles, paper, fireproofing agents, cements and refrigeration brine. It has also been used in dust and erosion control. Mixed with hydrated magnesium oxide, magnesium chloride forms a hard material called “Sorel-cement”. The cement is a mixture of MgO (burnt magnesia) with MgCl2 with the approximate chemical formula Mg4Cl2(OH)6(H2O)8, corresponding to a weight ratio of 2.5–3.5 parts MgO to one part MgCl2. This usage of magnesium chloride is unmatched by any other compound. MgCl2 was one of the earlier antiseptics, first used for that purpose by Dr Pierre Delbert in 1915. One veterinary study in 1989 indicated some effectiveness against tumors when used as a feed additive. A commercial form of liquid MgCl2 called DustGard Liquid is used to control dust on unpaved roads, construction sites and similar surfaces. Because it is produced from naturally occurring minerals, it improves air quality and visibility with minimal environmental impact. It also decreases vehicle maintenance costs, prevents soil erosion and reduces the need for blading, watering and gravel replacement. Magnesium chloride is also used in several medical and topical (skin-related) applications. It has been used in pills as supplemental sources of magnesium, where it serves as a soluble compound which is not as laxative as MgSO4, and more bio-available than Mg(OH)2 and MgO, since it does not require stomach acid to produce soluble Mg2+ ion. It can also be used as an effective anesthetic for cephalopods, some species of crustaceans, and several species of bivalves, including oysters. Magnesium chloride is an important coagulant used in the preparation of “tofu” from soy milk. In Japan, it is sold as “Nigari”, (derived from the Japanese word for “bitter"). It is a white powder produced from seawater after the sodium chloride has been removed, and the water evaporated. In China, it is called "Lushui”,Nigari or Lushui and consists mostly of magnesium chloride, with some MgSO4 and other trace elements. It is also an ingredient in baby formula milk. Magnesium chloride has shown promise as a storage material for hydrogen gas. Ammonia can be effectively adsorbed onto solid magnesium chloride, forming Mg(NH3)6Cl2. When the ammonia is released by mild heat, and is then passed through a catalyst, hydrogen gas is retrieved.

Chemical Properties

Magnesium is an essential nutrient for plants and animals and is a natural constituent of fruits, vegetables, grain, meats and sea-foods. It is the fourth most abundant cation in the human body and the second most plentiful intracellularly. The average 60-kg human adult body contains about 24 g magnesium of which about one-half resides in bone. Although plasma levels vary between 1.7 and 3.0 mg per dl, very little is contained in extracellular fluid. Magnesium is essential for the production and transfer of energy, for protein, fat, and nucleic acid synthesis, for contractility in muscle and excitability in nerve, and for the activity of numerous enzyme systems.

Occurrence

MgCl2, is one of the primary constituents of seawater and occurs in most natural brines and salt deposits formed from the evaporation of seawater.

Definition

Different sources of media describe the Definition of 7786-30-3 differently. You can refer to the following data:
1. magnesium chloride: A white solid compound, MgCl2. The anhydrous salt (hexagonal; r.d. 2.32; m.p.714°C; b.p. 1412°C) can be prepared by the direct combination of dry chlorine with magnesium: Mg(s) + Cl2(g) → MgCl2(s) The compound also occurs naturally as a constituent of carnallite(KCl.MgCl2). It is a deliquescent compound that commonly forms the hexahydrate, MgCl2.6H2O (monoclinic;r.d. 1.57). When heated, this hydrolyses to give magnesium oxide and hydrogen chloride gas. The fused chloride is electrolysed to produce magnesium and it is also used for fireproofing wood, in magnesia cements and artificial leather, and as a laxative.
2. ChEBI: Magnesium chloride is a magnesium salt comprising of two chlorine atoms bound to a magnesium atom.

Preparation

In the “Dow Process” (which is the electrolytic method of extracting bromine from brine), magnesium chloride is regenerated from magnesium hydroxide by hydrochloric acid: Mg(OH)2(s)+2HCl→MgCl2(aq)+2H2O It can also be prepared from MgCO3 by a similar reaction. Magnesium chloride is ionic and so will undergo electrolysis when it is molten. Electricity is carried by the movement of the ions within the melt and their discharge at the electrodes. However, solid magnesium chloride is a nonconductor of electricity because the ions are immobile.

Hazard

Toxic by ingestion.

Flammability and Explosibility

Nonflammable

Check Digit Verification of cas no

The CAS Registry Mumber 7786-30-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,7,8 and 6 respectively; the second part has 2 digits, 3 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 7786-30:
(6*7)+(5*7)+(4*8)+(3*6)+(2*3)+(1*0)=133
133 % 10 = 3
So 7786-30-3 is a valid CAS Registry Number.
InChI:InChI=1/2ClH.Mg/h2*1H;/q;;+2/p-2

7786-30-3 Well-known Company Product Price

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  • Alfa Aesar

  • (42850)  Magnesium chloride, ultra dry, 99.99% (metals basis)   

  • 7786-30-3

  • 5g

  • 378.0CNY

  • Detail
  • Alfa Aesar

  • (42850)  Magnesium chloride, ultra dry, 99.99% (metals basis)   

  • 7786-30-3

  • 25g

  • 921.0CNY

  • Detail
  • Alfa Aesar

  • (42850)  Magnesium chloride, ultra dry, 99.99% (metals basis)   

  • 7786-30-3

  • 100g

  • 3394.0CNY

  • Detail
  • Alfa Aesar

  • (35709)  Magnesium chloride, ultra dry, 99.99% (metals basis)   

  • 7786-30-3

  • 10g

  • 939.0CNY

  • Detail
  • Alfa Aesar

  • (35709)  Magnesium chloride, ultra dry, 99.99% (metals basis)   

  • 7786-30-3

  • 50g

  • 3442.0CNY

  • Detail
  • Alfa Aesar

  • (35709)  Magnesium chloride, ultra dry, 99.99% (metals basis)   

  • 7786-30-3

  • 250g

  • 12919.0CNY

  • Detail
  • Alfa Aesar

  • (42843)  Magnesium chloride, ultra dry, 99.9% (metals basis)   

  • 7786-30-3

  • 5g

  • 245.0CNY

  • Detail
  • Alfa Aesar

  • (42843)  Magnesium chloride, ultra dry, 99.9% (metals basis)   

  • 7786-30-3

  • 25g

  • 887.0CNY

  • Detail
  • Alfa Aesar

  • (42843)  Magnesium chloride, ultra dry, 99.9% (metals basis)   

  • 7786-30-3

  • 100g

  • 2628.0CNY

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  • Alfa Aesar

  • (35707)  Magnesium chloride, ultra dry, 99.9% (metals basis)   

  • 7786-30-3

  • 10g

  • 636.0CNY

  • Detail
  • Alfa Aesar

  • (35707)  Magnesium chloride, ultra dry, 99.9% (metals basis)   

  • 7786-30-3

  • 50g

  • 2315.0CNY

  • Detail
  • Alfa Aesar

  • (12315)  Magnesium chloride, anhydrous, 99%   

  • 7786-30-3

  • 1kg

  • 342.0CNY

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7786-30-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name magnesium dichloride

1.2 Other means of identification

Product number -
Other names L-GLUTAMIC ACID HEMIMAGNESIUM SALT TETRAHYDRATE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Processing Aids and Additives
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:7786-30-3 SDS

7786-30-3Synthetic route

Mg(2+)*2Mo(6+)*2Cl(1-)*6O(2-)*4C4H8O=[Mg(ClMoO3)2(C4H8O)4]

Mg(2+)*2Mo(6+)*2Cl(1-)*6O(2-)*4C4H8O=[Mg(ClMoO3)2(C4H8O)4]

A

molybdenum(VI) oxide

molybdenum(VI) oxide

B

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In tetrahydrofuran Ar atm.; hot THF;A 100%
B 100%
magnesium
7439-95-4

magnesium

zinc(II) chloride
7646-85-7

zinc(II) chloride

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In melt melting the starting materials in an evacuated silica ampoule at 900°C for 48 h, cracking the ampoule under Ar;95%
In neat (no solvent) reduction of molten ZnCl2 with Mg forming MgCl2;;
In neat (no solvent) reduction of molten ZnCl2 with Mg forming MgCl2;;
zirconium(IV) chloride
10026-11-6

zirconium(IV) chloride

magnesium
7439-95-4

magnesium

A

zirconium
7440-67-7

zirconium

B

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In melt heating at 800°C under inert gas in a closed vessel, Kroll-process; apparatus described;; separation of Mg and MgCl2 by vacuum destillation;;A 93%
B n/a
In melt heating at 800°C under inert gas in a closed vessel, Kroll-process; apparatus described;; separation of Mg and MgCl2 by vacuum destillation;;A 93%
B n/a
magnesium silicide

magnesium silicide

ammonium chloride

ammonium chloride

silicon nitride

silicon nitride

B

ammonia
7664-41-7

ammonia

C

hydrogen
1333-74-0

hydrogen

D

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In neat (no solvent) High Pressure; mixed, sealed in autoclave under Ar, heated at 450, 500, 550, and 600 °C for 10 h; washed with water, dried in vac. at 70 °C for 12 h; powder XRD;A 93%
B n/a
C n/a
D n/a
dichlorobis(3,5-di-tert-butylpyrazolylato)titanium(IV)
194354-14-8

dichlorobis(3,5-di-tert-butylpyrazolylato)titanium(IV)

methylmagnesium chloride
676-58-4

methylmagnesium chloride

A

dimethylbis(3,5-di-tert-butylpyrazolylato)titanium(IV)
222026-71-3

dimethylbis(3,5-di-tert-butylpyrazolylato)titanium(IV)

B

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In tetrahydrofuran; hexane Ar-atmosphere; MeMgCl soln. (THF) addn. (0°C), stirring (room temp., 20 h), evapn. (reduced pressure); extg. (hexane), filtering, evapn. (reduced pressure); elem. anal.;A 93%
B n/a
(trimethylsilyl)methylmagnesium chloride
13170-43-9

(trimethylsilyl)methylmagnesium chloride

tantalum pentachloride
7721-01-9

tantalum pentachloride

trimethylphosphane
594-09-2

trimethylphosphane

((CH3)3SiCH2)3Ta(P(CH3)3)(CHSi(CH3)3)

((CH3)3SiCH2)3Ta(P(CH3)3)(CHSi(CH3)3)

B

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In diethyl ether; hexane under N2 atm. slurry TaCl5 in hexane at -20°C was treated dropwise with Me3SiCH2MgCl in Et2O, solvent was removed in vacuo, residue was taken up in hexane at 0°C and filtered, PMe3 was added and heated to 50°C for 1 h; soln. was filtered, concd. and cooled to -20°C;A 92%
B n/a
rac-ethanediyl-bis(1-indenyl)zirconium dichloride
154005-14-8, 141724-21-2, 162429-20-1, 100080-82-8, 112243-78-4

rac-ethanediyl-bis(1-indenyl)zirconium dichloride

methylmagnesium bromide
75-16-1

methylmagnesium bromide

A

rac-ethylenebis(1-indenyl)zirconium dimethyl

rac-ethylenebis(1-indenyl)zirconium dimethyl

B

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In 1,4-dioxane; diethyl ether; hexane (N2); dioxane was added to 3 M soln. MeMgBr in hexane and Et2O, stirred for 1 h, filtered, filtrate was added to soln. of zirconium complex in Et2O at -78°C, warmed to room temp. overnight; evapd., dissolved in benzene, filtered, evapd. in vac., crystd. from toluene/hexanes;A 91%
B n/a
ethylmagnesium bromide
925-90-6

ethylmagnesium bromide

palladium dichloride

palladium dichloride

A

ethane
74-84-0

ethane

B

ethene
74-85-1

ethene

C

palladium
7440-05-3

palladium

D

magnesium bromide

magnesium bromide

E

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In tetrahydrofuran To a soln. of anhydrous salt is added C2H5MgBr at 20°C with stirring. The reaction mixture is left for 5 - 6 h at room temp.; decantation, washing with THF, water and ethanol; electron diffraction;A n/a
B n/a
C 90%
D n/a
E n/a
bis(η5-tetramethyl(trimethylsilyl)cyclopentadienyl)titanium dichloride
185154-26-1

bis(η5-tetramethyl(trimethylsilyl)cyclopentadienyl)titanium dichloride

magnesium
7439-95-4

magnesium

Bis(trimethylsilyl)ethyne
14630-40-1

Bis(trimethylsilyl)ethyne

A

(η2-bis(trimethylsilyl)ethyne)bis(η5-tetramethyl(trimethylsilyl)cyclopentadienyl)titanium(II)
195259-28-0

(η2-bis(trimethylsilyl)ethyne)bis(η5-tetramethyl(trimethylsilyl)cyclopentadienyl)titanium(II)

B

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In tetrahydrofuran -18°C (40 h), filtering, evapn. (vac.); extg. (hexane), MgCl2 pptn. (-5°C, overnight), concg., crystn. (-18°C, overnight); elem. anal.;A 80%
B n/a
gallium
7440-55-3

gallium

magnesium
7439-95-4

magnesium

methyl iodide
74-88-4

methyl iodide

A

magnesium chloride
7786-30-3

magnesium chloride

B

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
In neat (no solvent) inert gas atmosphere; mixing, heating in autoclave (100 - 160°C, stirring, 12 h); distillation;A n/a
B 65%
gallium
7440-55-3

gallium

magnesium
7439-95-4

magnesium

ethyl iodide
75-03-6

ethyl iodide

A

triethyl gallium
1115-99-7

triethyl gallium

B

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In hexane inert condition; addn. of hexane to mixt. of Mg and Ga (vac.), addn. of hexane, dropwise addn. of EtI (boiling hexane); distillation;A 65%
B n/a
gallium
7440-55-3

gallium

iodine
7553-56-2

iodine

magnesium
7439-95-4

magnesium

ethyl iodide
75-03-6

ethyl iodide

A

triethyl gallium
1115-99-7

triethyl gallium

B

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In neat (no solvent) inert condition; addn. of I2 to mixt. of Mg and Ga, heating in vac. (150°C), chilling, addn. of EtI (50 - 70°C, 1 h), heating (90 °C, 4 h); distillation;A 61%
B n/a
[ZrCl2(C32H38N4)]
245491-72-9

[ZrCl2(C32H38N4)]

dibenzylmagnesium
6928-77-4

dibenzylmagnesium

A

C39H45N4Zr(C4H8O)(CH2C6H5)
253689-33-7

C39H45N4Zr(C4H8O)(CH2C6H5)

B

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In tetrahydrofuran; toluene stirring (room temp., 1 h); evapn., toluene addn., filtering, evapn., n-pentane addn., filtering, drying (vac.); elem. anal.;A 61%
B n/a
Ga(35),Mg(65) (X%)

Ga(35),Mg(65) (X%)

iodine
7553-56-2

iodine

ethyl iodide
75-03-6

ethyl iodide

A

triethyl gallium
1115-99-7

triethyl gallium

B

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In neat (no solvent) inert condition; addn. of I2 to alloy Mg-Ga, heating in vac. (150 °C), chilling, addn. of EtI), heating (85°C, 4 h); distillation;A 57%
B n/a
dimethylbis(3,5-di-tert-butylpyrazolylato)titanium(IV)
222026-71-3

dimethylbis(3,5-di-tert-butylpyrazolylato)titanium(IV)

tert-butylamine
75-64-9

tert-butylamine

A

chlorotris(3,5-di-tert-butylpyrazolato)titanium(IV)
222027-39-6, 210816-30-1

chlorotris(3,5-di-tert-butylpyrazolato)titanium(IV)

B

(tert-butylimido(chloro)(3,5-di-tert-butylpyrazolato)titanium)2
222027-00-1

(tert-butylimido(chloro)(3,5-di-tert-butylpyrazolato)titanium)2

C

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In hexane byproducts: tert-butylammonium chloride; Ar-atmosphere; stirring (room temp., 16 h); filtering, evapn. (reduced pressure), crystn. (hexane, -15°C, -20°C); elem. anal.;A 56%
B 10%
C n/a
chlorotris(3,5-di-tert-butylpyrazolato)titanium(IV)
222027-39-6, 210816-30-1

chlorotris(3,5-di-tert-butylpyrazolato)titanium(IV)

methylmagnesium chloride
676-58-4

methylmagnesium chloride

A

methyltris(3,5-di-tert-butylpyrazolylato)titanium(IV)
222026-93-9

methyltris(3,5-di-tert-butylpyrazolylato)titanium(IV)

B

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In tetrahydrofuran Ar-atmosphere; MeMgCl soln. (THF) addn. (0°C), stirring (room temp., 20 h), evapn. (reduced pressure); extg. (hexane), filtering, evapn. (reduced pressure); elem. anal.;A 52%
B n/a
magnesium
7439-95-4

magnesium

calcium chloride

calcium chloride

A

hydrogen
1333-74-0

hydrogen

B

magnesium chloride
7786-30-3

magnesium chloride

C

calcium hydroxide

calcium hydroxide

Conditions
ConditionsYield
With water In neat (no solvent) reduction of dry CaCl2 in H2-atmosphere on calcination with Mg; treatment of the reaction-products with H2O under formation of H2;;A 50%
B n/a
C n/a
With water In neat (no solvent) reduction of dry CaCl2 in H2-atmosphere on calcination with Mg; treatment of the reaction-products with H2O under formation of H2;;A 50%
B n/a
C n/a
With water In neat (no solvent) reduction of dry CaCl2 in CO2-atmosphere on calcination with Mg; treatment of the reaction-products with H2O under formation of H2;;A 30%
B n/a
C n/a
With water In neat (no solvent) reduction of dry CaCl2 in CO2-atmosphere on calcination with Mg; treatment of the reaction-products with H2O under formation of H2;;A 30%
B n/a
C n/a
1-chloro-2,3-dimethyl-1,2,3-arsadicarba-closo-dodecaborane(9)

1-chloro-2,3-dimethyl-1,2,3-arsadicarba-closo-dodecaborane(9)

isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

A

1-isopropyl-2,3-dimethyl-1,2,3-arsadicarba-closo-dodecaborane(9)

1-isopropyl-2,3-dimethyl-1,2,3-arsadicarba-closo-dodecaborane(9)

B

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In diethyl ether under Ar, -80°C, molar ratio arsacarbollyl:(CH3)2CHMgCl=4.50:4.44, 1h stirring at room temp.; colorless ppt. is filtered off, solvent removed, extd. with hot hexane, evapd. to dryness, subl. in high vac. at 50°C, elem. anal.;A 50%
B n/a
Vanadium (III) chloride-(tris-tetrahydrofuran)
131063-11-1, 16997-51-6, 19559-06-9

Vanadium (III) chloride-(tris-tetrahydrofuran)

pentafluorophenylmagnesium chloride
879-06-1

pentafluorophenylmagnesium chloride

A

(C6F5)4V*2C4H8O

(C6F5)4V*2C4H8O

B

Tetrakis(pyridin)-dichlorovanadin(II)
25377-37-1, 27790-75-6, 82009-22-1

Tetrakis(pyridin)-dichlorovanadin(II)

C

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In tetrahydrofuran 1 mol of complex was slowly added to an THF soln. of 2 mol RMgCl at -15°C, after 1 h the temp. was raised to room temp. (Ar atm.);; dioxane in Et2O was added, evapd., ppt. was washed with Et2O;;A 43%
B 47%
C n/a
Vanadium (III) chloride-(tris-tetrahydrofuran)
131063-11-1, 16997-51-6, 19559-06-9

Vanadium (III) chloride-(tris-tetrahydrofuran)

(trimethylsilyl)methylmagnesium chloride
13170-43-9

(trimethylsilyl)methylmagnesium chloride

A

Tetrakis(pyridin)-dichlorovanadin(II)
25377-37-1, 27790-75-6, 82009-22-1

Tetrakis(pyridin)-dichlorovanadin(II)

B

tetrakis(trimethylsilylmethyl)vanadium
41572-08-1

tetrakis(trimethylsilylmethyl)vanadium

C

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In diethyl ether 1 mol of complex was slowly added to an ether soln. of 2 mol RMgCl at -15°C, after 1 h the temp. was raised to room temp. (Ar atm.);; dioxane was added, ppt. was extd. with pentane; elem. anal.;;A 43%
B 45%
C n/a
dichlorobis(3,5-di-tert-butylpyrazolylato)titanium(IV)
194354-14-8

dichlorobis(3,5-di-tert-butylpyrazolylato)titanium(IV)

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

A

dibenzylbis(3,5-di-tert-butylpyrazolylato)titanium(IV)
222026-78-0

dibenzylbis(3,5-di-tert-butylpyrazolylato)titanium(IV)

B

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In diethyl ether; toluene Ar-atmosphere; BnMgCl soln. (Et2O) addn. (0°C), stirring (room temp., 16 h), evapn. (reduced pressure); extg. (hexane), filtering, concg. (reduced pressure), crystn. (-20°C, 2 d); elem. anal.;A 43%
B n/a
trichloro-(3,5-di-tert-butylpyrazolylato)titanium(IV)
222027-44-3

trichloro-(3,5-di-tert-butylpyrazolylato)titanium(IV)

methylmagnesium chloride
676-58-4

methylmagnesium chloride

A

dimethylbis(3,5-di-tert-butylpyrazolylato)titanium(IV)
222026-71-3

dimethylbis(3,5-di-tert-butylpyrazolylato)titanium(IV)

B

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In tetrahydrofuran; hexane Ar-atmosphere; pptn. on mixing reagents (-78°C, 0.25 h), stirring(room temp., 3 h), evapn. (reduced pressure); extg. (hexane), filtering, evapn. (reduced pressure);A 35%
B n/a
boron trifluoride
7637-07-2

boron trifluoride

boron trichloride
10294-34-5

boron trichloride

A

boron

boron

B

boron nitride
10043-11-5

boron nitride

C

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
700-1000°C; diluterd with N2; washing with HCl at 1000°C;A n/a
B 34%
C n/a
1-chloro-2,3-dimethyl-1,2,3-phosphadicarba-closo-dodecaborane(9)

1-chloro-2,3-dimethyl-1,2,3-phosphadicarba-closo-dodecaborane(9)

isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

A

1-isopropyl-2,3-dimethyl-1,2,3-phosphadicarba-closo-dodecaborane(9)

1-isopropyl-2,3-dimethyl-1,2,3-phosphadicarba-closo-dodecaborane(9)

B

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In diethyl ether under Ar, -80°C, molar ratio ClP((CH3)2C2B9H9):(CH3)2CHMgCl=1:1, warmed to -20°C; colorless ppt. is filtered off, solvent removed, extd. with hot hexane, evapd. to dryness, subl. in high vac. at room temp., elem. anal.;A 33%
B n/a
brucite

brucite

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
With hydrogenchloride In neat (no solvent) heating of brucite at 383-412 °C in a stream of dry HCl with formation of MgCl2;10.33%
With HCl In neat (no solvent) heating of brucite at 383-412 °C in a stream of dry HCl with formation of MgCl2;10.33%
ethylmagnesium chloride
2386-64-3

ethylmagnesium chloride

methyltrichlorogermane
993-10-2

methyltrichlorogermane

A

C7H17ClGe

C7H17ClGe

B

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In butyldiglyme; ethyldiglym at 40℃; for 3h;
isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

methyltrichlorogermane
993-10-2

methyltrichlorogermane

A

C4H10Cl2Ge

C4H10Cl2Ge

B

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In butyldiglyme; ethyldiglym at 40℃; for 3h;
isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

methyltrichlorogermane
993-10-2

methyltrichlorogermane

A

C7H17ClGe

C7H17ClGe

B

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In butyldiglyme; ethyldiglym at 40℃; for 3h;
C7H17ClGe

C7H17ClGe

isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

A

diethylisopropylmethylgermane

diethylisopropylmethylgermane

B

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In butyldiglyme; ethyldiglym for 1h;
triethylaluminum
97-93-8

triethylaluminum

n-butyl-ethylmagnesium
62202-86-2

n-butyl-ethylmagnesium

A

hydridomagnesium chloride
14989-29-8

hydridomagnesium chloride

B

(AlEt3)2*MgEt2

(AlEt3)2*MgEt2

C

butyl magnesium bromide
693-04-9

butyl magnesium bromide

D

ethylmagnesium chloride
2386-64-3

ethylmagnesium chloride

E

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In 2-Methylpentane for 4383h; Reactivity;
glycerol
56-81-5

glycerol

magnesium chloride
7786-30-3

magnesium chloride

Mg(2+)*H(1+)*C3H5O3(3-)=C3H6O3Mg

Mg(2+)*H(1+)*C3H5O3(3-)=C3H6O3Mg

Conditions
ConditionsYield
With copper In glycerol byproducts: CuCl; Electrolysis; electrolysis of MgCl2 in anhydrous glycerin, copper electrodes, formation of CuCl at the anode and of C3H6O3Mg at the cathode;;100%
With Cu In glycerol byproducts: CuCl; Electrolysis; electrolysis of MgCl2 in anhydrous glycerin, copper electrodes, formation of CuCl at the anode and of C3H6O3Mg at the cathode;;100%
chromium(VI) oxide

chromium(VI) oxide

magnesium chloride
7786-30-3

magnesium chloride

magnesium chlorochromate

magnesium chlorochromate

Conditions
ConditionsYield
In tetrachloromethane stirred vigorously for 3 d under N2; filtd. or evapn. of solvent under reduced pressure;99%
potassium dizirconiumenneaisopropoxide

potassium dizirconiumenneaisopropoxide

zirconium isopropoxide

zirconium isopropoxide

magnesium chloride
7786-30-3

magnesium chloride

MgCl(Zr2(OC3H7)9)
164989-80-4

MgCl(Zr2(OC3H7)9)

Conditions
ConditionsYield
In isopropyl alcohol; benzene byproducts: KCl; reflux (2 h), volatiles removal, stirring (70°C, 10 h), KCl pptn.; filtration, volatiles removal (27°C, red. pressure), pptn., recrystn. (n-hexane/toluene) or volatilization (210°C, 0.01 mmHg); elem. anal.;99%
potassium dizirconiumenneaisopropoxide

potassium dizirconiumenneaisopropoxide

zirconium isopropoxide

zirconium isopropoxide

magnesium chloride
7786-30-3

magnesium chloride

Mg(Zr2(OC3H7)9)2
164989-81-5, 57609-07-1

Mg(Zr2(OC3H7)9)2

Conditions
ConditionsYield
In isopropyl alcohol; benzene byproducts: KCl; reflux (2 h), volatiles removal, stirring (70°C, 10 h), KCl pptn., filtration, volatiles removal, (27°C, red. pressure), pptn.; volatilization (175°C, 0.1 mmHg) (70%); elem. anal.;99%
potassium tetraisopropoxyaluminate

potassium tetraisopropoxyaluminate

aluminum isopropoxide
555-31-7

aluminum isopropoxide

magnesium chloride
7786-30-3

magnesium chloride

Mg(2+)*Cl(1-)*Al(OC3H7)4(1-)=MgCl(Al(OC3H7)4)
164989-79-1

Mg(2+)*Cl(1-)*Al(OC3H7)4(1-)=MgCl(Al(OC3H7)4)

Conditions
ConditionsYield
In isopropyl alcohol; benzene byproducts: KCl; stirring (27°C, 12 h), pptn. (KCl), filtration; volatiles removal (reduced pressure, 27°C), recrystn. (hexane/toluene, -10°C); elem. anal.;99%
sodium tetrahydroborate
16940-66-2

sodium tetrahydroborate

ammonia
7664-41-7

ammonia

magnesium chloride
7786-30-3

magnesium chloride

magnesium borohydride - ammonia (1/6)

magnesium borohydride - ammonia (1/6)

Conditions
ConditionsYield
In diethyl ether under Ar atm. soln. Mg(BH4)2 in Et2O was prepared by react. MgCl2 and NaBH4 (V.N.Konoplev, Zh.Neorg.Khim., 1980, 25 (7), 1737-1740), anhydrous ammonia was passed through soln. at -10°C; react. mixt. was allowed to warm to room temp., volatiles were removed in vacuo; elem. anal.;99%
bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

C42H33FP2Si

C42H33FP2Si

magnesium chloride
7786-30-3

magnesium chloride

C42H33ClNiP2Si

C42H33ClNiP2Si

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 1h; Reagent/catalyst; Inert atmosphere; Schlenk technique;99%
tin(IV) oxide

tin(IV) oxide

magnesium chloride
7786-30-3

magnesium chloride

tin(IV) chloride
7646-78-8

tin(IV) chloride

Conditions
ConditionsYield
With pyrographite In neat (no solvent) byproducts: MgO; heating of a mixture of SnO2 with double excess of MgCl2 forms 98.3 % SnCl4 at 800°C in presence of C;;98.3%
In neat (no solvent) byproducts: MgO; heating of a mixture of SnO2 with double excess of MgCl2 forms 74.60 % SnCl4 at 800°C;;74.6%
In neat (no solvent) byproducts: MgO; heating of a mixture of SnO2 with double excess of MgCl2 forms 58.79 % SnCl4 at 700°C; equilibrium reaction examinated;;58.79%
tin(IV) oxide

tin(IV) oxide

magnesium chloride
7786-30-3

magnesium chloride

tin(ll) chloride

tin(ll) chloride

Conditions
ConditionsYield
With pyrographite In neat (no solvent) byproducts: MgO, CO; formation at reaction of SnO2, MgCl2 and C under exclusion of air for 2 h at 800°C;; collecting of formed SnCl2 at 300-330°C in a condensator at exclusion of air;;98.3%
With C In neat (no solvent) byproducts: MgO, CO; formation at reaction of SnO2, MgCl2 and C under exclusion of air for 2 h at 800°C;; collecting of formed SnCl2 at 300-330°C in a condensator at exclusion of air;;98.3%
With pyrographite In neat (no solvent) byproducts: MgO, CO; heating of a mixture of SnO2 with double excess of MgCl2 in presence of C in 2 h at 523, 548 and 573°C forms liquid SnCl2; examination of the equilibrium reaction;;
hydrogen
1333-74-0

hydrogen

magnesium
7439-95-4

magnesium

magnesium chloride
7786-30-3

magnesium chloride

(HMgCl)2(C4H8O)2
63866-76-2

(HMgCl)2(C4H8O)2

Conditions
ConditionsYield
With tetrahydrofuran In tetrahydrofuran addn. of soln. of MgCl2 in THF to suspn. of Mg powder and catalyst in THF (under Ar), hydrogenation (H2-pressure 40-60 bar, 0°C, 18 h); centrifugation; not isolated;96%
With tetrahydrofuran In tetrahydrofuran addn. of soln. of MgCl2 in THF to suspn. of Mg powder and catalyst in THF (under Ar), hydrogenation (H2-pressure 50-70 bar, 0°C, 8 h); centrifugation; not isolated;59%
With tetrahydrofuran In tetrahydrofuran addn. of soln. of MgCl2 in THF to suspn. of Mg powder and catalyst in THF (under Ar), hydrogenation (H2-pressure 50-70 bar, 25°C, 40 h); centrifugation; not isolated;41%
With catalyst: TiCl4*2THF/ Mg-anthracene In tetrahydrofuran addn. of soln. of MgCl2 in THF to suspn. of Mg powder and catalyst in THF (under Ar), hydrogenation (H2-pressure 50-70 bar, 0°C, 40 h); centrifugation; not isolated;22%
With tetrahydrofuran In tetrahydrofuran addn. of soln. of MgCl2 in THF to suspn. of Mg powder and catalyst in THF (under Ar), hydrogenation (H2-pressure 50-70 bar, 60°C, 48 h); centrifugation; not isolated;15%
Na(1+)*Al(ONC(CH3)2)4(1-)=NaAl(ONC(CH3)2)4

Na(1+)*Al(ONC(CH3)2)4(1-)=NaAl(ONC(CH3)2)4

magnesium chloride
7786-30-3

magnesium chloride

Mg[Al(ONC(CH3)2)4]2
197501-39-6

Mg[Al(ONC(CH3)2)4]2

Conditions
ConditionsYield
In tetrahydrofuran byproducts: NaCl; (moisture free); reflux (4 h), NaCl pptn.; filtration, excess solvent removal (red. pressure), crystn., recrystn. (toluene, -20°C); elem anal.;96%
levodopa
59-92-7

levodopa

magnesium chloride
7786-30-3

magnesium chloride

Mg(L-3,4-dioxyphenylalanine)2

Mg(L-3,4-dioxyphenylalanine)2

Conditions
ConditionsYield
Stage #1: levodopa With potassium tert-butylate In tetrahydrofuran; N,N-dimethyl acetamide for 0.25h;
Stage #2: magnesium chloride In tetrahydrofuran; N,N-dimethyl acetamide
96%
trifluoroacetic acid
76-05-1

trifluoroacetic acid

magnesium chloride
7786-30-3

magnesium chloride

magnesium(II) 2,2,2-trifluoroacetate
38482-84-7, 123333-72-2

magnesium(II) 2,2,2-trifluoroacetate

Conditions
ConditionsYield
at 20 - 100℃; for 1h;95%
magnesium chloride
7786-30-3

magnesium chloride

sodium trispyrazolylborate

sodium trispyrazolylborate

bis{hydrotris(pyrazolyl)borato}magnesium

bis{hydrotris(pyrazolyl)borato}magnesium

Conditions
ConditionsYield
In water byproducts: NaCl; Trofimenko, S., J. Am. Chem. Soc., 89 (1967), 3170; crystd. (toluene/CH2Cl2), sublimed (vac.); elem. anal., TGA;94%
[Rh(1,10-phenanthroline)(NH3)4](CF3SO3)3

[Rh(1,10-phenanthroline)(NH3)4](CF3SO3)3

5,6-chrysenedione
2051-10-7

5,6-chrysenedione

sodium hydroxide
1310-73-2

sodium hydroxide

magnesium chloride
7786-30-3

magnesium chloride

[Rh(5,6-chrysenequinone diimmine)(1,10-phenanthroline)(NH3)2]Cl3

[Rh(5,6-chrysenequinone diimmine)(1,10-phenanthroline)(NH3)2]Cl3

Conditions
ConditionsYield
Stage #1: [Rh(1,10-phenanthroline)(NH3)4](CF3SO3)3; 5,6-chrysenedione; sodium hydroxide In water; acetonitrile
Stage #2: magnesium chloride With sephadex QAE anionexchange column
94%
tetrahydrofuran
109-99-9

tetrahydrofuran

tert-butyl acetoacetate sodium salt
64770-14-5

tert-butyl acetoacetate sodium salt

magnesium chloride
7786-30-3

magnesium chloride

C56H94Mg2Na2O20

C56H94Mg2Na2O20

Conditions
ConditionsYield
at 20℃; for 72h; Inert atmosphere; Schlenk technique; Glovebox;94%
sodium tetrahydroborate
16940-66-2

sodium tetrahydroborate

1,2-dimethoxyethane
110-71-4

1,2-dimethoxyethane

magnesium chloride
7786-30-3

magnesium chloride

Mg(2+)*2BH4(1-)*1.5CH3OCH2CH2OCH3=Mg(BH4)2*1.5CH3OCH2CH2OCH3

Mg(2+)*2BH4(1-)*1.5CH3OCH2CH2OCH3=Mg(BH4)2*1.5CH3OCH2CH2OCH3

Conditions
ConditionsYield
In 1,2-dimethoxyethane mixt. of MgCl2, NaBH4 in DME was stirred for 10 h under inert atm; filtered, washed with DME, solvent was vac. distilled, extd. with CH2Cl2, CH2Cl2 was distilled in vacuo; elem. anal.;93%
for 7 - 22h; Inert atmosphere; Glovebox; Schlenk technique;85%
2,5‐dihydroxyterephthalate
904693-44-3

2,5‐dihydroxyterephthalate

magnesium chloride
7786-30-3

magnesium chloride

iron(II) chloride

iron(II) chloride

C8H4O6(2-)*0.1Fe(2+)*0.9Mg(2+)

C8H4O6(2-)*0.1Fe(2+)*0.9Mg(2+)

Conditions
ConditionsYield
Stage #1: 2,5‐dihydroxyterephthalate; magnesium chloride; iron(II) chloride In methanol; N,N-dimethyl-formamide at 120℃; for 16h;
Stage #2: In N,N-dimethyl-formamide at 120℃; for 9h;
Stage #3: In methanol at 60℃;
93%
2,5-dihydroxy-1,4-benzenedicarboxylic acid
610-92-4

2,5-dihydroxy-1,4-benzenedicarboxylic acid

magnesium chloride
7786-30-3

magnesium chloride

iron(II) chloride

iron(II) chloride

Fe0.1Mg1.9(2,5-dioxido-1,4-benzenedicarboxylate)

Fe0.1Mg1.9(2,5-dioxido-1,4-benzenedicarboxylate)

Conditions
ConditionsYield
In methanol; N,N-dimethyl-formamide at 120℃; for 16h;93%
titanium(IV) isopropylate
546-68-9

titanium(IV) isopropylate

magnesium chloride
7786-30-3

magnesium chloride

Mg2Ti4Cl4(OCH(CH3)2)16
1126433-59-7

Mg2Ti4Cl4(OCH(CH3)2)16

Conditions
ConditionsYield
In benzene soln. of Ti(OPr-i)4 (6.37 mol) in benzene added to slurry of MgCl2 (3.15mol) in benzene; stirred at room temp. until dissolution of MgCl2 (24 h ); reflux for 1 h; evapd. (vac. 0.5 mm, room temp.); crystd. at -20°C (hexane/CH2Cl2= 2:1); elem. anal.;91%
sodium tetrahydroborate
16940-66-2

sodium tetrahydroborate

magnesium chloride
7786-30-3

magnesium chloride

magnesium borohydride

magnesium borohydride

Conditions
ConditionsYield
In diethyl ether ball milled and refluxed in Et2O;90%
In neat (no solvent) (Ar); mechanical action (3 h, room temp.); extn. (Et2O);76%
In not given
potassium heptafluorotantalate

potassium heptafluorotantalate

magnesium chloride
7786-30-3

magnesium chloride

tantalum pentachloride
7721-01-9

tantalum pentachloride

Conditions
ConditionsYield
750 °C for 1 h in inert gas, molar ratio of K2TaF4:chloride = 1:2;90%
700-1000 °C in inert gas, molar ratio of K2TaF7:chloride = 1:2;

7786-30-3Relevant articles and documents

Controlled synthesis of Mg(OH)2 nanorods using basic magnesium chloride as precursor

Chai, Shu-Jing,Luo, Bi-Jun,Wu, Hai-Hong,Wu, Dan,Lu, Shao-Yan,Zhang, Qi

, p. 90 - 101 (2021/07/07)

Mg(OH)2 nanorods were successfully prepared by two-step method. The precursor was obtained by hydrolyzed the MgCl2 in NH3·H2O solution, and then, it transformed into Mg(OH)2 nanorods by a simple solvothermal method without any surfactant or catalyst. The influences of synthesis parameters on the morphological characteristics and sizes of Mg(OH)2 nanoparticles were investigated, such as the proportion of EtOH–H2O solvent, the reaction temperature, and the treatment time. XRD and FESEM were used to characterize the structure, morphology, and composition of the samples. This method is lower costing, simple and environmentally benign, thus, it should be easy to be scaled up for industrial production.

In-situ observation on the magnesiothermic reduction of TiCl4 around 800 °C by microfocus X-ray fluoroscopy

Kishimoto, Akihiro,Uda, Tetsuya

, (2021/05/06)

In the industrial smelting process for titanium metal, liquid TiCl4 is supplied on molten magnesium and reduced to porous titanium in a closed steel or stainless steel container at 800–900 °C. In the present study, in-situ observation on the magnesiothermic reduction of TiCl4 was performed by microfocus X-ray fluoroscopy. We successfully observed that the molten magnesium creeps up on container walls rapidly and that porous titanium is mainly deposited and grows on the walls by reduction of gaseous TiCl4 by the magnesium. This unique behavior of magnesium is attributed to the capillary action of molten magnesium through pores of titanium deposited on the walls.

Ionic liquids as an efficient medium for the mechanochemical synthesis of α-AlH3 nano-composites

Duan,Hu,Ma

, p. 6309 - 6318 (2018/04/23)

Aluminum hydride (AlH3) is one of the most promising hydrogen storage materials that has a high theoretical hydrogen storage capacity (10.08 wt%) and relatively low dehydriding temperature (100-200 °C). In this work, we present a cost-effective route to synthesize the α-AlH3 nano-composite by using cheap metal hydrides and aluminum chloride as starting reagents and to achieve liquid state reactive milling. The LiH/AlCl3 and MgH2/AlCl3 reaction systems were systemically explored. The phase identification of the obtained products was carried out by XRD and the morphology observed by TEM characterization. It was found that the α-AlH3 nano-composite can be successfully synthesized by reactive milling of commercial AlCl3 and LiH in a neutral ionic liquid ([2-Eim] OAc). Based on XRD analysis and TEM observation, an average grain size of 56 nm can be obtained by the proposed mechanochemical process. By setting the isothermal dehydrogenation temperature between 80 and 160 °C, the as-synthesized α-AlH3 nano-composite exhibits an advantage in hydrogen desorption capacity and has fast dehydriding kinetics. The hydrogen desorption content of 9.93 wt% was achieved at 160 °C, which indicates the potential utilization of the prepared nanocomposite in hydrogen storage applications.

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